Scalable synthesis of macroscopic porous carbon sheet anode for potassium-ion capacitor

Carbon materials hold the great promise for application in energy storage devices owing to their low cost, high thermal/chemical stability, and high electrical conductivity. However, it remains challenging to synthesize high-performance carbon electrodes in a simple, scalable and sustainable way. Here, we report a facile method for scalable synthesis of porous carbon anode by using cheap and easily accessible zeolitic imidazolate framework-8 as a template and polyvinylpyrrolidone as an additiona...     

Aggregation-induced emission luminogens and tunable multicolor polymer networks modulated by dynamic covalent chemistry

Aggregation-induced emission(AIE) based luminescent materials are generating intensive interest due to their unique fluorescence in the aggregation state. Herein we report a strategy of dynamic covalent chemistry(DCC) controlled AIE luminogens for the regulation of multicolor emission in reversible covalent polymer networks. Tetraphenylethene derived ring-chain tautomers were prepared, and the emission was readily controlled through multimode, such as changing the solvent, adding the base, and d...     

Efficient removal of tetracycline by H2O2 activated with iron-doped biochar: Performance,mechanism, and degradation pathways

In this study,novel iron-doped biochar（Fe-BC） was produced using a simple method,and it was used as an H₂ O₂ activator for tetracycline（TC） degradation.Generally,iron loading can improve the separation performance and reactivity of biochar（BC）.In the Fe-BC/H₂ O₂ system,92% of the TC was removed within 30 min with the apparent rate constant(k_obs) of 0.155 min^-1,which was 23.85 times that in the case of the BC/H₂ O_2<...     

Water-induced luminescence improvement in a lanthanide β-diketone complex for monitoring water purity

Water-caused luminescence quenching is a well-known and intractable issue for luminescence lanthanide complexes, greatly confining their broad application as sensing and displaying devices in water system.Herein, an anionic and coordination-saturated lanthanide complex with a nanosheet-like structure has been prepared. It exhibits excellent photophysical properties both in solid state and in aqueous suspension. Noteworthily, a 13% improvement for sensitization efficiency from organic ligand to c...     

Achieving higher performances without an external curing agent in natural magnolol-based epoxy resin

Bio-based epoxy thermoset prepared from renewable biomass raw materials can alleviate fossil energy crisis and reduce environmental pollution,which satisfies the needs of sustainable social development.In this study,a bio-based epoxy thermoset precursor（MGOL-EP） was synthesized from a naturally occurring magnolol through a facile and efficient one-step process.And the fully bio-based epoxy thermoset（MGOL-EP-SC） was obtained by self-curing without adding any other hardener.MGOL-EP-SC revealed an ...     

Pincer iridium（Ⅲ）-catalyzed enantioselective C（sp3）-H functionalization via carbenoid C–H insertion of 3-diazooxindoles with 1,4-cyclohexadiene

The asymmetric carbenoid C–H insertion of 3-diazooxindoles into 1,4-cyclohexadiene has been accomplished in the presence of chiral bis(imidazoline) NCN pincer iridium(Ⅲ) complexes as the catalysts. With a catalyst loading of 0.5 mol%, the reactions proceeded smoothly at 0℃ to afford a variety of chiral 3-substituted oxindoles in good yields with moderate to excellent enantioselectivities(up to 99% ee). The protocol exhibits good functional group tolerance with respect to 3-diazooxindoles and is ...     

One-step synthesis of hierarchical Ni3Se2 nanosheet-on-nanorods/Ni foam electrodes for hybrid supercapacitors

Transitional metal selenides have high conductivity, even metal quality, which makes them great for using as electrode materials for fabricating supercapacitors. Here, hierarchical Ni₃Se₂ nanosheet-on-nanorods on Ni foam（NSR-Ni₃Se₂/Ni） was fabricated by a facile three-dimensional（3D） substrate-assisted confinement assembly method, and used as a freestanding electrode material for hybrid supercapacitors（HSCs）. In this design, metallic Ni₃Se     

Recent advances in the application of sulfinic acids for the construction of sulfur-containing compounds

Sulfur-containing organic compounds display wide applications in the field of materials science, synthetic chemistry, and pharmaceutical industry. Thus, numerous synthetic strategies have been developed for the synthesis of sulfur-containing compounds in synthetic chemistry. In recent years, the utilization of sulfinic acids as versatile synthons has emerged as attractive and powerful approach to access various organosulfur compounds through sulfonylation, sulfinylation or sulfenylation reaction...     

Dearomative spirocyclization via visible-light-induced reductive hydroarylation of non-activated arenes

A visible-light-induced spirocyclizative hydroarylation via reductive dearomatization of a series of non activated arenes including 2-phenyl indoles and naphthalene derivatives under mild conditions is de scribed. An intriguing chemoselective dearomative hydroarylation of 2-phenyl indoles is presented. Th dearomative hydroarylation protocol rapidly delivers valuable spirocycles with carbon-carbon doub bonds from readily accessible aromatic precursors in a single step.     

带旋转自由度的拟协调平面元

本文用拟协调方法研究了一类带有旋转自由度的平面膜元,讨论了九参数三角元、十二参数任意四边形元几种可能的各类场变量的选取搭配,得到了几个性能良好的九参数和十二参数带旋转自由度的拟协调平面元。所给出的单元列式简单,数值结果表明单元精度很高,尤其是任意四边形元QR4b性能最好。