氨基酸辅助增强Cs3Cu2I5钙钛矿荧光粉及其蓝光LED的性能研究

本文采用简单的室温球磨法制备了一系列L-组氨酸(L-His)和5-氨基戊酸(5-Ava)修饰的Cs₃Cu₂I₅钙钛矿荧光粉，并对Cs₃Cu₂I₅∶x%L-His和Cs₃Cu₂I₅∶x%5-Ava(x=0、0.5、1、1.5、2)样品的物相、形貌、光学和稳定性进行了分析。氨基酸添加未对Cs₃Cu₂I₅钙钛矿的晶体结构造成影响，Cs₃Cu₂I₅仍属于Pnma空间群，但氨基酸的加入对钙钛矿的晶粒尺寸有一定的限制作用，并有效改善了其光电性能。当x=1时，经L-His和5-Ava修饰的Cs₃Cu₂I₅钙钛矿较纯Cs₃Cu₂I₅钙钛矿的荧光强度...     

几种因素对磷化钼催化剂重整性能的影响

考察了采用不同溶解方式对活性的影响,磷源对催化剂性能的影响以及不同含量的磷对催化剂的影响。结果表明,磷源对催化剂的结构影响较小,但是对活性有比较大的影响,其中以磷酸氢二铵作为磷源时重整活性最好。并考察了催化剂失活再还原后测定其活性和催化剂的稳定性,钝化后还原和新鲜态的催化剂评价其重整活性时,差别很小。并用H2-TPR和CO2-TPD技术表征了所制磷化钼催化剂的表面性质。     

中心相似分布的参数估计

本文提出了中心相似多元分布统计分析模型,多元正态分布是其特例.研究了该模型中未知参数的矩估计问题,并证明了这些估计的大样本性质.     

BaTiO3-BaAl2O4-Al2O3复合载体的制备、表征及其Ni基催化剂催化CH4/CO2重整反应性能

以十六烷基三甲基溴化胺为结构导向剂,采用溶胶-凝胶法制备了BaTiO3-BaAl2O4-Al2O3复合载体,采用X射线衍射、红外光谱、N2吸附-脱附、透射电子显微镜和H2程序升温还原等技术对复合载体进行了表征,并以CH4/CO2重整制合成气为探针反应,考察了不同Ni/BaTiO3-BaAl2O4-Al2O3催化剂的性能.结果表明,BaTiO3-BaAl2O4-Al2O3复合载体具有多孔织构特性和较高的比表面积,BaTiO3和BaAl2O4以晶粒状态分布在复合载体的内外表面,晶粒尺寸在20～50nm的范围,复合载体孔径为10～20nm.复合载体上BaTiO3和BaAl2O4的引入,适度削弱了Ni/BaTiO3-BaAl2O4-Al2O3催化剂中Ni物种与γ-Al2O3间的强相互作用,抑止了NiAl2O4尖晶石的生成;当载体中Ba(Ti)含量为17.33%时,其负载的Ni催化剂上CH4/CO2重整制合成气反应的活性和稳定性最高.     

Broadband tunable optical amplification based on modulation instability characteristic of high-birefringence photonic crystal fibers

A novel high-birefringence photonic crystal fiber (HB-PCF) with two zero-dispersion wavelengths (ZDWs) is designed, and an extraordinarily high modal birefringence of 1.56×10-2 is obtained at pump wavelength λp=1850nm. With the designed HB-PCF, the effect of the pump parameters on the modulation instability (MI) in the anomalous dispersion region close to the second ZDWs of the HB-PCF is comprehensively studied in this work. A broadband and tunable optical amplification is achieved by controlling the pump power and the pump wavelength based on the combined operation of Raman effect and cross phase modulation. By optimizing the pump parameters, the amplification bandwidth along the fiber slow axis reaches 152 nm for the pump power Pp=280W and the pump wavelength λp=1675nm, while the gain bandwidth along the fiber fast axis is 165 nm for the pump power Pp=600W and the pump wavelength λp=1818nm.     

Pressure dependent modulation instability in photonic crystal fiber filled with argon gas

By using the designed photonic crystal fiber filled with argon gas, the effect of gas pressure on modulation instability(MI) gain is analyzed in detail. The MI gain bandwidth increases gradually as the argon gas pressure rises from 1 P_0 to 400 P_0(P_0 is one standard atmosphere), while its gain amplitude slightly decreases. Moreover, the increase of the incident light power also results in the increase of MI gain bandwidth in the Stokes or anti-Stokes region when the incident power increases from 1 W to 200 W. Making use of the optimal parameters including the higher argon gas pressure(400 P_0) and the incident light power(200 W), we finally obtain a 100 nm broadband MI gain. These results indicate that controlling the MI gain characteristic by changing the argon gas pressure in PCF is an effective way when the incident light source is not easy to satisfy the requirement of practical application. This method of controlling MI gain can be used in optical communication and laser shaping.     

改进卡方检验

In goodness-of-fit tests, Pearson＇s chi-squared test is one of most widely used tools of formal statistical analysis. However, Pearson＇s chi-squared test depends on the partition of the sample space. Different constructions of the partition of the sample space may lead to different conclusions. Based on an equiprobable partition of sample space, a modified chi~quared test is proposed. A method for constructing the modified chi-squared test is proposed. As an application, the proposed test is used to test whether vectorial data come from an uniformity distribution defined on the hypersphere. Some simulation studies show that the modified chisquared test against different alternative is robust.     

具有AR(1)误差的非线性随机效应模型中自相关系数的扰动诊断

随机效应模型广泛应用于刻画重复测量数据的特征,Banerjee和Frees[1]用Cook距离,Lesaffre和Verbeke[2]用影响曲率分别对线性随机效应模型进行了分析.本文利用影响曲率对具有AR(1)误差的非线性随机效应模型中的自相关系数扰动进行了分析,得到了影响曲率的表达式,并且利用血浆药物渗透数据(Davidian和Gillinan[3])来说明分析方法的应用.     

基于EGB2分布族的GAS-EGARCH模型与VaR预测

GARCH族模型是刻画资产收益率的常用工具,在风险度量领域具有广泛应用。为了更有效地描述收益率的偏斜厚尾等特征,越来越多学者对GARCH族模型的条件分布形式进行了研究。但是仅对GARCH模型条件分布进行修正是不够的,还需要对模型本身的函数形式进行修正。基于得分函数的时变参数建模思想近年来受到广泛关注,本文借助这一思想对EGARCH模型中对数标准差进行时变波动建模,并利用EGB2分布族作为模型的条件分布,进而建立GAS-EGARCH-EGB2模型。以我国10只中证行业指数为研究对象考察GAS-EGARCH-EGB2模型的风险预测效果,GAS-EGARCH-EGB2模型样本外VaR预测表现普遍优于ACM-EGARCH-EGB2模型。