New bifurcations of basin boundaries involving Wada and a smooth Wada basin boundary

This paper demonstrates and analyses double heteroclinic tangency in a three-well potential model, which can produce three new types of bifurcations of basin boundaries including from smooth to Wada basin boundaries, from fractal to Wada basin boundaries in which no changes of accessible periodic orbits happen, and from Wada to Wada basin boundaries. In a model of mechanical oscillator, it shows that a Wada basin boundary can be smooth.     

8β-hydroxyeremophil-7(11)-ene-12,8α(4β,6α)-diolide分子的晶体结构

运用层析法、结晶法从狭苞橐吾全草中分离得到艾里莫芬烷型倍半萜8β-hydroxyeremophil-7(11)-ene-12,8α(4β,6α)-diolide化合物,并通过质谱、核磁共振氢谱和碳谱、氢核-氢核相关谱、异核多量子相干谱和异核多键相干谱进行结构鉴定．其单晶经X射线衍射测试表明,其晶体属正交晶系,空间群为P212121,晶胞参数为: a=6．8519(5),b=10．7191(8),c=18．5942(14)A,V=1365．67(18) A3,Z=4,Dc=1．354 mg／m3．F(000)=592,μ=0．101 mm-1     

小口径双通道球幕投影镜头的设计

为提高球幕投影成像质量,提出了双通道球幕投影方案,并基于此方案,为3.05 cm(1.2英寸)3DMD芯片技术投影机设计了双通道球幕投影镜头。根据投影方案确定了设计指标,对初始结构的选型做出了合理的分析,阐述了光学设计过程,给出了像差优化及设计结果的评价。为避免镜头口径过大引起的重心不稳,通过合理控制光线入射高度,将镜头首片透镜的口径进行了大幅度的压缩,最终口径仅为102 mm。设计的成像质量高、像质均匀的球幕双拼投影镜头F#为2.5,反远比为6:1,1.0视场在38 lp/mm的Nyquist频率处MTF值为0.5,0.85以内视场的MTF值达到0.65以上,最大横向色差为4.7 μm,小于0.5 pixel。     

(一)-△~(9(12))-CapneUene类的合成中间体——光学活性5-甲基-8-羟基双环[3,3,0]2一辛酮的不对称合成研究

通过手性硝基烯胺(4)与α-甲基-δ-戊内酯烯醇锌盐发生加成消除反应解决了倍半萜Capnellene类合成中构筑不对称季碳这个难题,对映体过量(e. e. )为94％。由L-脯氨酸经14步实现了(一)-△~(9(12))-Capnellene类的合成中间体——光学活性5-甲基-8-羟基双环[3 3,0]-2-辛酮(13)的对映选择合成。     

关于数列{2~n}

易知等比数列{2~n}前n项的和为S_n=a_(n+1)-2。对于这个关系式,我们有三点联想。 (一)简便求和。若a_5=32,则S_4=30。 (二)判定由关系式a_(n+1)=rS_n+S给出的数列是否为等比数列。事实上a_(n+1)=rS_n+S (1) a~n=rS_(n-1)+S (2) (1)-(2)得a_(n+1)-a_n=r(s_n-S_(n-1))=ra_n a_(n+1)/a_n=r+ 因此,r≠-1,a_1=S,{a_n}为等比数列。 (三)等比数列前n项和公式的新法推导。     

Kinetic model of gas phase polymerization of 1,3-butadiene catalyzed by supported rare earth coordination system

Gas phase polymerization of 1,3-butadiene (Bd) catalyzed by supported rare earth coordination system is studied and a new kinetic model is proposed. Four elementary reactions or processes: the process of exposure and activation of potential active catalytic center, propagation, deactivation and chain transfer reaction to alkyl aluminum, are considered in this model. Some important parameters, such as monomer-consuming rate, are well expressed as the functions of macroscopic polymerization conditions such as pressure, temperature, and duration. The model can simulate the whole polymerization procedure satisfactorily.     

MULTIPLE EQUILIBRIA IN BAROCLINIC ATMOSPHERE BY THERMAL FORCING RELATED TO SUBTROPICAL HIGH

By using Lorenz's moist general circulation model, a nonlinear and dissipative system describing atmospheric motion has been obtained in approximation of Low Order.The multiple equilibria and the transformation between the flow patterns of winter and summer, the latitudinal oscillation of subtropical high by thermal forcing and nonlinear interaction of general circulation are studied in this paper.The results show that the transformation of flow patterns is a discontinuous leaping, and is a process of resetting new flow pattern by rapid exchange inflow field.In the corresponding dry model, we cannot find the latitudinal oscillation of the center of subtropical high.In the moist model, after the thermal effect of water vapor is drawn into the model, nonlinear interaction appears between flow and heating fields.This effect helps to bring about the latitudinal oscillation of subtropical high.     

液相沉淀法制备稀土-锆固溶体及其性能研究

采用液相沉淀法制备了Ce0.6Zr0.3La0.05Y0.05O2固溶体。通过BET,XRD,SEM,程序升温还原和氧脉冲吸附等方法对合成产品性能进行了表征。研究了前驱体的形态、高温水热处理、表面处理以及后期固溶体的还原处理对固溶体性能的影响。其中前驱体的高温水热处理和固溶体的还原处理对固溶体的催化性能有很大的影响。200℃水热处理制得的固溶体经1000℃老化4 h后,比表面积为25.3 m2.g-1,孔容为0.21 cm3.g-1,经800℃还原处理3 h后储氧量为478.3μmol.g-1,显示了较高的比表面积和储氧能力的高温稳定性。     

妙用另类加速度 巧解“匀”变速运动

提出另类加速度及适用条件,得出另类匀变速直线运动的规律,并讨论如何巧妙利用该规律解有关变速问题.