利用时间分辨的光电子影像技术研究2,6-二甲基吡啶分子锥形交叉超快动力学

利用时间分辨的飞秒光电子影像技术结合时间分辨的质谱技术,研究了2,6-二甲基吡啶分子锥形交叉超快动力学过程. 2,6-二甲基吡啶分子吸收266 nm泵浦光从基态跃迁至S₂态(π-π^*). 母体离子时间变化曲线包含两个指数函数,一个是时间常数为635 fs的快速组分,另一个是时间常数为4.37 ps的慢速组分. 通过时间分辨光电子影像得到的时间依赖的光电子角度分布和能量分辨的光电子谱分布提供了S₂态演变的动力学信息. 简言之,快速组分反映了通     

MOS-based model of four-transistor CMOS image sensor pixels for photoelectric simulation

By using the MOS-based model established in this paper, the physical process of photoelectron generation, transfer, and storage in the four-transistor active pixel sensor (4T-APS) pixels can be simulated in SPICE environment. The variable capacitance characteristics of double junctions in pinned photodiodes (PPDs) and the threshold voltage difference formed by channel nonuniform doping in transfer gates (TGs) are considered with this model. The charge transfer process of photogenerated electrons from PPDs to the floating diffusion (FD) is analyzed, and the function of nonuniform doping of TGs in suppressing charge injection back to PPDs is represented with the model. The optical and electrical characteristics of all devices in the pixel are effectively combined with the model. Moreover, the charge transfer efficiency and the voltage variation in PPD can be described with the model. Compared with the hybrid simulation in TCAD and the Verilog-A simulation in SPICE, this model has higher simulation efficiency and accuracy, respectively. The effectiveness of the MOS-based model is experimentally verified in a 3 μ m test pixel designed in 0.11 μ m CIS process.     

飞秒时间分辨的光电子影像技术研究2-氯吡啶超快内转换动力学

利用时间分辨的飞秒光电子影像技术结合时间分辨的质谱技术, 研究了2-氯吡啶分子激发态的超快过程. 实时观察到了2-氯吡啶分子第二激发态(S₂)向第一激发态(S₁)高振动能级的的超快内转换过程,该内转换的时间常数为(162±5)fs. 实验结果表明, 通过S₂/S₀的锥形交叉衰减到基态的衰减通道也是退布居的重要通道, 其时间尺度为(5.5±0.3) ps.     

Coherence generation and population transfer in a three-level ladder system

This work explores the effect of spontaneous emission on coherence generation and population transfer in a threelevel ladder atomic system driven by two pulses in counterintuitive order.With adiabatic evolution and the weakdephasing approximation,we find that a large coherence and population transfer can be achieved even with spontaneous decay rate.The maximum coherence and population transfer decrease with the increase of spontaneous decay rate from the highest state to intermediate state.But this effect can be compensated by shortening the pulse width and enlarging the delay time.Results show that the coherence generation and population transfer never depend on the spontaneous decay rate from the intermediate state to ground state.The validity of the analytic solution is examined by numerical calculation.     

L-天冬氨酸在银胶体中吸附状态的表面增强拉曼光谱研究

利用表面增强拉曼光谱 (Surface EnhancedRamanScattering,SERS)研究了L 天冬氨酸在银溶胶体中的吸附状态及其浓度变化对表面增强拉曼散射效应的影响 ,并探讨了L 天冬氨酸在银溶胶表面的吸附作用特点和规律。实验结果表明 ,L 天冬氨酸在银溶胶中有明显的SERS信号 ,经过分析表明 ,该化合物能够吸附在银表面 ,这种吸附是通过羧基和氨基中的氮原子与银结合来实现的 ,L 天冬氨酸分子中带有负电荷的羧基和氨基中带有孤对电子的氮原子都能与银原子配位 ,其中羧基在银表面的增强为电荷转移机制增强 ,具有化学吸附的特征 ;氨基在银表面的增强为电磁场增强机制 ,为物理吸附。而且SERS强度随着L 天冬氨酸浓度的变化而改变 ,当其浓度为 10 - 3mol·L- 1 时增强效果较好 ,当浓度降低 ,增强作用也逐步变弱     

Fluorescence properties in a single driven four-level atomic system

The spontaneous emission decay dynamics of a tripod configuration four-level atom driven by a single laser field is studied.Under different initial conditions,we discuss the effects of quantum interference and detuning of external driving field on atomic spontaneous emission properties.For the larger detuning,the interesting phenomena of the spectral line narrowing are found which stem from the contribution of external driving field.     

车辆噪声烦恼度的音色表达

烦恼度作为评价噪声对人影响的重要指标,受到广泛重视并获得应用。通过主观评价实验和数据统计分析,从音色角度对城市典型车辆噪声烦恼度进行建模并给予物理解释。研究发现:(1)车辆噪声烦恼度音色空间由四个维度构成;(2)利用多元线性回归方法给出的车辆噪声烦恼度模型与声样本烦恼度拟合较好;(3)烦恼度空间维度与特定频谱特性具有较高的相关性。研究结果为车辆噪声烦恼度建模及降噪设计提供了新的思路。      

用共振增强多光子电离方法研究几种含溴化合物的光解

利用飞行时间质谱仪(TOF)和共振增强多光子电离(REMPI)方法, 研究了两种正一溴代烷烃(C₂H₅Br, n-C₃H₇Br)和溴苯(C₆H₅Br)在234及267 nm附近的光解. 测出了这几种含溴化合物在不同波长下光解产物Br^*和Br的分支比N(Br*)/N(Br), 并根据从头计算结果, 解释了这几种含溴化合物光解产物的分支比随光解波长变化的趋势及几个低激发态势能面之间的关系.     

甲胺分子共振增强多光子电离的波长依赖性

使用激光多光子电离质谱技术，研究了甲胺分子在４２５ｎｍ－４９５ｎｍ波长范围内共振增强多光子电离碎裂过程，记录了母体离子和与碎片离子产额与波长的依赖关系。由于共振增强多光子电离母体离子与碎片离子谱的相似性，可用探测总离子信号的方法来替代单独的母离子探测，有效地提高痕量探测的灵敏度。