红外光谱结合X射线荧光光谱分析多种塑料袋组份的研究

为建立一种简便快捷、准确可靠的检验塑料袋样品的分析方法,利用傅立叶红外光谱仪(FTIR)结合能量色散型X射线荧光光谱仪(XRF),对43个不同品牌、不同规格的塑料袋样品进行测定。结果表明,依据样品的有机成分和样品中所含元素的种类及含量的不同,可以对样品进行区分,同时,利用SPSS聚类分析Ward法作为类间距离,对塑料袋样品进行分类,效果较好。并且该方法操作简便快速、结果准确可靠、样品无需特殊的前处理,且属于无损检验,该方法可以用于公安机关实际办案。     

氨基聚硅氧烷对改性环氧树脂的形态与性能的影响

将带有Ｎ－（β－氨乙基）－γ－氨丙基侧基的聚二甲基硅氧烷与环氧树脂共混,制备了聚硅氧烷改性环氧树脂固化物。研究了氨基聚硅氧烷的氨基含量对改性环氧树脂的形态和性能的影响。结果表明,改性环氧树脂固化物的形态与性能主要依赖于氨基聚硅氧烷的氨基含量,在环氧树脂中引入适宜氨基含量的氨基聚硅氧烷,可在一定程度上降低其模量,提高其柔性,并可明显改善环氧树脂的表面性能。     

离子速度影像法研究n-C7H15Br分子光解反应动力学

利用离子速度成像方法, 研究n-C7H15Br分子在231～239 nm范围内几个波长处的光解离动力学. 通过同一束激光经(2+1)共振多光子电离(REMPI)过程探测光解碎片Br(2P3/2)和Br*(2P1/2), 得到了不同激光波长处的离子速度分布图像, 从而获得C7H15Br光解产物的能量分配和角度分布. 结合各向异性参数和量子产率, 计算了n-C7H15Br分子在234 nm波长下不同解离通道的比例. 实验表明光解产物的能量分配可以用冲击模型中的软碰撞模型来解释. 实验还发现, 各向异性参数β(Br*)的值对光波长变化很敏感, 这是由电子激发态的绝热和非绝热过程决定的.     

利用飞秒泵浦探测技术研究碘甲烷B态预解离动力学

应用飞秒双光泵浦-探测技术结合飞行时间质谱研究了碘甲烷分子的B态预解离动力学，其中泵浦光波长为400 nm，探测光为800 nm，碘甲烷主要的产物通道为生成CH3I+和CH3+．改变泵浦与探测光之间的延时，得到了这两种离子的时间演化曲线，每个曲线都可以用两个指数函数来拟合，拟合常数为?1和?2，?1反映了碘甲烷分子吸收三个泵浦激光所到达的高里德堡态的动力学，?2反映了吸收两个泵浦激光所到达的B里德堡态的动力学，得到的B态的带源寿命为1.57 ps，这个值和以前的文献非常符合，试验结果被解释为多光子的电离解     

可移动激光质谱仪及在机动车尾气监测中的应用

激光质谱法是探测环境污染的新方法,它具有高灵敏度、高选择性、多组分和快速实时的特点.文中介绍了可移动激光质谱仪的系统结构、各部分功能以及主要技术指标,报道了该仪器研制设计过程中的某些关键技术问题,并给出了该仪器在机动车尾气监测中的一些实时在线探测结果.     

Quantum interference effects on the probe amplification without and with inversion in a four-level system

A four-level system driven by two coherent fields is considered. It is shown that in the presence of an incoherent pump, the probe gain at a short wavelength can be achieved due to the quantum interference. Our density matrix calculation provides the conditions for probe amplification from different origins, including gain without population inversion on any state basis, gain with population inversion on the dressed-state basis, and gain with population inversion on the bare-state basis. Also, by controlling the Rabi frequency of the coupling field a total change from non-inversion to inversion can be achieved which does not depend on the intensity of the incoherent pump.     

A quantum efficiency analytical model for complementary metal–oxide–semiconductor image pixels with a pinned photodiode structure

A quantum efficiency analytical model for complementary metal–oxide–semiconductor（CMOS） image pixels with a pinned photodiode structure is developed. The proposed model takes account of the non-uniform doping distribution in the N-type region due to the impurity compensation formed by the actual fabricating process. The characteristics of two boundary PN junctions located in the N-type region for the particular spectral response of a pinned photodiode, are quantitatively analyzed. By solving the minority carrier steady-state diffusion equations and the barrier region photocurrent density equations successively, the analytical relationship between the quantum efficiency and the corresponding parameters such as incident wavelength, N-type width, peak doping concentration, and impurity density gradient of the N-type region is established. The validity of the model is verified by the measurement results with a test chip of 160×160 pixels array,which provides the accurate process with a theoretical guidance for quantum efficiency design in pinned photodiode pixels.     

Effect of concentration of Er3+ ions on ultra-large index of refraction via atomic coherence in Er3+: YAG crystal

A four-level system is proposed to produce large index of refraction accompanied by vanishing absorption in the Er^{3+}-doped yttrium aluminium garnet (YAG) crystal. It is found that the high index of refraction with zero absorption can be provided by adjusting the incoherent pumping, the coherent field, as well as the concentration of Er^{3+} ions in the crystal. Furthermore, the value of the incoherent pump to achieve the high index of refraction with zero absorption is greatly changed with increasing the concentration of Er^{3+} ions in the crystal. This indicates that the effect of concentration on the high index of refraction with zero absorption cannot be neglected.     

VUV超短脉冲的产生及其在超快动力学中的应用

真空紫外超短脉冲激光具有波长短、单光子能量高、脉宽小等特点,在飞秒化学以及超快动力学等方面具有相当广泛的应用前景.由于直接利用受激辐射获得真空紫外超短脉冲是相当困难,因此利用非线性频率转换技术,超短脉冲与惰性气体相互作用,将红外、可见或紫外光波段的超短脉冲转换到真空紫外波段是目前获得紫外超短脉冲最快捷有效的方式.围绕真空紫外超短脉冲的产生及其在超短动力学中应用展开,介绍了产生真空紫外超短脉冲的高斯谐波、空心光纤四波混频和光丝四波混频的方法,对其优缺点作了评述,并对真空紫外超短脉冲激光在超快动力学过程中的应用进行了简单的总结.