Optical Parameters and Absorption of Azo Dye and Its Metal-Substituted Compound Thin Films

We determine the complex refractive indices N(N= n-ik), dielectric constants ε(ε=ε1 - iε2), and absorption coefficients a of a new azo dye [2-(6-methyl-2-benzothlazolyazo)-5-diethylaminophenol(MBADP)]-doped polymer and its nickel- and zinc-substituted compounds(Ni-MBADP and Zn-MBADP) spin-coated thin films from a scan-ning ellipsometer in the wavelength 400-700 nm region. Metal chelation strongly (about one times) enhances the optical and dielectric parameters at the peaks and results in a large bathochromic shift (50-60nm) of absorption band. Bathochromic shift of Ni-MBADP is about 1Ohm larger than that of Zn-MBADP due to different spatialconfigurations formed in the metal-azo complexes.     

超分辨相变光盘的膜层计算与分析

利用多层膜反射率的矩阵法计算了GeSbTe超分辨相变光盘的光学参数与各膜层厚度之间的关系，最后得到了较为理想的膜层厚度匹配。     

导致光聚物全息存储布喇格偏移因素的研究

研究了光聚物高密度全息存储材料在全息记录过程中曝光量、曝光时间、厚度收缩比例、折射率调制度及记录角度等因素对布喇格偏移的影响规律,结果表明:曝光量一定时,布喇格偏移与曝光时间的关系不大,当曝光量不一定时布喇格偏移随曝光时间增加缓慢增加最后达到饱和;而布喇格偏移随厚度收缩比例和折射率调制度的增加以接近正比例的关系增加;记录光栅的倾斜度越大则布喇格偏移也越大.这些结论对光聚物高密度全息存储研究具有重要的意义.     

碘化亚铜微晶掺杂硅酸盐玻璃的制备及其光学性质

采用可分相的Na2O－Al2O3－B2O3－SiO2系为基础玻璃，以CuO／SnO、NaI为原料分别引入Cu＋、I－，成功地制备出CuI激晶掺杂硅酸盐玻璃．通过X射线粉末衍射（XRD）和高分辨透射电镜（HRTEM）分析观察到玻璃中的晶相和微晶的分布情况；由玻璃的室温透射光谱研究了玻璃的热处理条件与光吸收性的关系．实验发现，该玻璃对Nd：YAG激光器腔内自由振荡具有脉定压缩效应．     

Novel material for nonvolatile ovonic unified memory (OUM)－Ag11In12Te26Sb51 phase change semiconductor

In this paper, Ag_{11}In_{12}Te_{26}Sb_{51} phase change semiconductor films have been prepared by dc sputtering. The crystallization behaviour of amorphous Ag_{11}In_{12}Te_{26}Sb_{51} thin films was investigated by using differential scanning calorimetry and x-ray diffraction. It was found that the crystallization temperature is about 483K and the melting temperature is 754.8K and the activation energy for crystallization, E_a, is 2.07eV. The crystalline Ag_{11}In_{12}Te_{26}Sb_{51} films were obtained using initializer. The initialization conditions have a great effect on the sheet resistance of Ag_{11}In_{12}Te_{26}Sb_{51} films. We found that the effect of the initialization condition on the sheet resistance can be ascribed to the crystallinity of Ag_{11}In_{12}Te_{26}Sb_{51} films. The sheet resistance of the amorphous (R_{amo}) film is found to be larger than 1×10^6Ω and that of the crystalline (R_{cry}) film lies in the range from about 10^3 to 10^4Ω. So we have the ratio R_{amo}/R_{cry}=10^2～10^3, which is sufficiently large for application in memory devices.     

Sb掺和对TeOx薄膜光学和静态记录特性的影响

以真空蒸镀法在K9玻璃基底上制备了TeO_x:Sb单层薄膜,对薄膜的结构、光学和静态记录特性进行了研究.结果表明,Sb掺和后TeO_x薄膜的结构、反射光谱和光学常量均发生了明显变化.TeO_x:Sb薄膜具有良好的写入灵敏性并具有了一定的可擦除性能,该类薄膜有望作为可擦除光存储介质.     

酞菁掺杂有机改性溶胶凝胶材料的自衍射及限幅特性

实验测得八异戊氧基钯酞菁掺杂有机改性溶胶－凝胶固体材料在Ar^ 激光作用下形成的大的与光强相关的多环衍射图案。研究了不同波长下的光学限幅特性,由于其大的光学限幅效应及其固体的可加工性,这种材料在制备光学限幅器件方面具有潜在的应用前景。     

TCNQ脂类衍生物及其铜复合物的合成与红外光谱研究

首次合成了7,7,8,8-四氰基对苯醌二甲烷的脂类衍生物: TCNQ(C₂H₄COOR)₂(R=CH₃, C₂H₅, C₃H₇)及其铜电子转移复合物。通过元素分析确定这些化合物的组成, 对这些化合成物在4 000～400 cm-1范围内的主要红外光谱吸收峰进行了归属,并讨论了取代基对TCNQ类衍生物红外光谱的影响及其规律。     

高质量Yb3+∶CS-FAP激光晶体的生长

本文进行了Yb3+∶FAP与Yb3+∶YAG的对比分析,指出了在激光核聚变领域中Yb3+∶FAP是很有希望的增益介质,针对Yb3+∶FAP吸收光谱宽度很小(4nm)对泵浦源要求苛刻,采用Yb3+∶CS-FAP即以部分Sr2+代替Ca2+造成Yb3+周围环境多样性增加、增加谱宽.参考分析了Ca3(PO4)2-CaF2体系的相图,推测出生长CS-FAP晶体的配料区间,给出了生长晶体的原料制备方法,采用氮气流动、白宝石片封闭保温罩的观察孔和观察窗上贴石英片相结合有效地缓解了在晶体生长过程中组分挥发、开裂、以及氟化物腐蚀窗口等一系列问题.生长工艺参数为:提拉速度1～3mm/h,旋转速度10～20r/min,在流量为20ml/min的流动N2中生长,采用尺寸为60×40mm的Ir坩埚进行生长,线圈尺寸为内径130mm×130mm×8圈,外径155mm×95mm×6圈.得到了尺寸为10mm×20mm的高质量晶体.用X射线粉末衍射分析证明所生长的晶体结构正确.     

In2O3纳米微粒非线性光学特性

用Z扫描技术研究了In₂O₃纳米微粒有机溶胶和水溶胶的三阶非线性光学特性,发现表面修饰能明显提高In₂O₃纳米微粒的非线性响应.讨论了表面偶极效应对In₂O₃纳米微粒非线性的影响. 关键词：