三硼酸锂(LBO)单晶的位错研究

本文叙述新型无机非线性单晶三硼酸锂(LBO)中位错的X射线衍射形貌观测和鉴定结果,探讨了位错形成的结构影响因素。 关键词：     

三硼酸锂晶体中负晶的观察

采用光学显微镜、X射线形貌术以及激光散射层析等方法,对新型非线性光学材料三硼酸锂晶体中的一种特殊的包裹体——负晶进行观测和研究,揭示了它的本质和组成,探讨了它的形成机理。 关键词：     

Nonlinear Optical BBO Crystals: Growth, Properties and Applications

1　 INTRODUCTIONLow temperature phase barium metaborateβ- Ba B2 O4 ( BBO) as a new nonlinearoptical material was firstdiscovered in 1 979by Chen's group of the Fujian Instituteof Research on the Structure of Matter,People's Republic of China〔1〕.BBO has anumber ofexcellentpropertiessuch aslarge effective SHG coefficients,large birefrin-gence,wide transparent spectral range,high damage threshold and good machnicaland chemical properties.Particularly attractive feature is its UV t…     

β′-相掺钕钼酸钆晶体生长和性质研究

采用提拉法生长β′-相掺钕钼酸钆晶体.在1000℃温度下烧结72h合成钼酸钆粉末样品.研究了生长工艺,拉速0.3～3mm/h,转速10～40r/min.沿[001]方向生长出35mm的掺钕钼酸钆单晶,晶体为紫色,透明.钕离子分凝系数略大于1.     

分子动力学模拟研究β-BAB2O4熔体的结构

The local structure of β-BaB2O4 melt at 1400 K has been studied by using the method of molecular dynamics simulation. The radial functions simulated show agreement with the recent experimental results of X-ray diffraction. The calculation of bond order parameters indicates that the local structure of the melt can be described by the model of linear combination of 0.11 tetrahedrons BO4 and 0.89 planar triangles BO3. In the process of crystal growth the existing of many planar triangles BO3 in the melt maybe favorable for the forming of planar boroxol rings B3O6 near the crystal interface. The statistics of rings and chains have been done and some isolated BO3, pyroborate B2O5,chain（－B－O－）n and isolated B3O6 rings are found in the melt which is in agreement with HTRS experimental results. A large (－B－O－)n network is also found and it is suggested that the planar BO3 units are mainly existed in the network but isolated.     

P(S)21m相掺钕钼酸钆晶体的结构

标题的晶体是采用提拉法得到的,单晶X射线结构分析表明:化合物分子式(Nd0.023Gd0.977)2(MoO4)3晶体属于四方晶系,空间群为P(S)21m, a=b=7.3556(10) , c=10.685(2)( ), Z=2,Dc=4.563g/cm3,Mr= 1585.64, F(000)=700.00, μ(MoKα)=14.527cm-1,R=0.0463, wR=0.0953,衍射点数为645.Gd(Nd)原子为七配位,Mo原子为四配位.