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991.
Farrington EJ Martinez Viviente E Williams BS van Koten G Brown JM 《Chemical communications (Cambridge, England)》2002,(4):308-309
The 1,3-bis(diphosphinomethyl)ferrocene 3 readily reacts with [(C2H4)2RhCl]2 to form an equilibrating pair of diastereomers 8a and 8b by C-H insertion into the ferrocene. 相似文献
992.
993.
Linington RG Robertson M Gauthier A Finlay BB van Soest R Andersen RJ 《Organic letters》2002,4(23):4089-4092
Extracts of the marine sponge Caminus sphaeroconia showed potent activity in a screen for bacterial type III secretion inhibitors. Bioassay guided fractionation of the extract led to the isolation of the novel antimicrobial glycolipid caminoside A (1). The structure of caminoside A was elucidated by analysis of spectroscopic data and chemical degradation.[structure: see text] 相似文献
994.
The need to measure several quantities rapidly in the same sample has prompted the development of automated methods of analysis that in both the continuous and discontinuous modes offer the possibility of simultaneous determinations. The application of pH gradients and differential kinetic determinations dominate the simultaneous determination of two or more closely related species in mixtures without prior separation. Various options enable use of kinetic-based measurements for the simultaneous determination of different analytes in flow systems. Some possible general reactions are given and discussed. The scope of sequential injection kinetic analysis is illustrated with examples. 相似文献
995.
Kemerink M Offermans P van Duren JK Koenraad PM Janssen RA Salemink HW Wolter JH 《Physical review letters》2002,88(9):096803
We demonstrate that the soft nature of organic semiconductors can be exploited to directly measure the potential distribution inside such an organic layer by scanning-tunneling microscope (STM) based spectroscopy. Keeping the STM feedback system active while reducing the tip-sample bias forces the tip to penetrate the organic layer. From an analysis of the injection and bulk transport processes it follows that the tip height versus bias trace obtained in this way directly reflects the potential distribution in the organic layer. 相似文献
996.
Affolder T Akimoto H Akopian A Albrow MG Amaral P Amidei D Anikeev K Antos J Apollinari G Arisawa T Artikov A Asakawa T Ashmanskas W Azfar F Azzi-Bacchetta P Bacchetta N Bachacou H Bailey S de Barbaro P Barbaro-Galtieri A Barnes VE Barnett BA Baroiant S Barone M Battle C Bauer G Bedeschi F Belforte S Bell WH Bellettini G Bellinger J Benjamin D Bensinger J Beretvas A Berge JP Berryhill J Bhatti A Binkley M Bisello D Bishai M Blair RE Blocker C Bloom K Blumenfeld B Blusk SR Bocci A Bodek A 《Physical review letters》2002,88(7):071806
We present the first general search for new heavy particles, X, which decay via X --> WZ0 --> e(nu)+jj as a function of M(X) and Gamma(X) in pp collisions at square root[s] = 1.8 TeV. No evidence is found for production of X in 110 pb(-1) of data collected by the Collider Detector at Fermilab. General cross section limits are set at the 95% C.L. as a function of mass and width of the new particle. The results are further interpreted as mass limits on the production of new heavy charged vector bosons which decay via W' --> WZ0 in an extended gauge model as a function of the width, Gamma(W'), and mixing factor between the W' and the standard model W bosons. 相似文献
997.
Niobium and tantalum carbide clusters have been isolated in the gas phase and irradiated with intense tunable infrared (IR) light. Stable neutral clusters are selectively ionized and subsequently detected in a mass spectrometer. By tuning the IR frequency, infrared multiphoton absorption spectra are obtained for a whole range of clusters. These mass-selective IR spectra lead to insights into the structures of small niobium and tantalum carbide clusters and nanocrystals. 相似文献
998.
Diffuse-reflectance spectroscopy for measurement of the absorption and scattering coefficients of biological tissue produces reliable results for wavelengths from 650 to 1050 nm. Implicitly, this approach assumes homogeneously distributed absorbers. A correction factor is introduced for inhomogeneous distribution of blood concentrated in discrete cylindrical vessels. This factor extends the applicability of diffusion theory to lower wavelengths. We present measurements of in vivo optical properties in the wavelength range 500-1060 nm. 相似文献
999.
Slejkovec Z Salma I van Elteren JT Zemplén-Papp E 《Fresenius' Journal of Analytical Chemistry》2000,366(8):830-834
An analytical procedure for speciation of As in urban aerosol samples was developed. The aerosols were collected by sequential filtration through membrane filters. Part of each filter was investigated by INAA for the total amount of As. Another part of the filters was treated by a sequential extraction procedure to differentiate between water-extractable, phosphate-extractable and refractory chemical forms. Water-extractable forms were further differentiated into anionic As species by HPLC-HGAFS. Extractability of As into water exhibited a clear dependency on the aerosol size fraction (12% in coarse fraction and 50% in fine fraction). Dependency of the phosphate extractable As on the aerosol size fraction seems not to be significant (10-15% in both size fractions). The remaining amount, i.e., about 78% of the coarse As and about 40% of the fine As was considered to be refractory or environmentally immobile As. Water-extractable As forms could only be attributed to arsenate. 相似文献
1000.
van Staden JF Stefan RI Aboul-Enein HY 《Fresenius' Journal of Analytical Chemistry》2000,367(2):178-180
A new amperometric biosensor based on D-aminoacid oxidase is described for the assay of R-perindopril. R-perindopril can be determined in the 400-20 nmol/L concentration range; the detection limit is 10 nmol/L. The selectivity was checked with S-perindopril, D- and L-proline, and polyvinylpyrrolidone. The main interfering species was D-proline. An automated system for the assay of R-perindopril based on the concept of flow injection with an amperometric biosensor (based on D-aminoacid oxidase) as detector is also described. The system is suitable for the on-line monitoring of R-perindopril at a sampling rate of 72 samples/h, in the linear range: 100 nmol/L -20 nmol/L with an RSD better than 0.09% (n = 10). 相似文献