Thermolysis of N-allylic 1,2,4-triazoles

A number of 4-allylic substituted 3,5-diphenyl-4H-1,2,4-triazoles were thermolyzed at 315–320° in evacuated glass ampoules. The main reaction in the melt was rearrangement to the corresponding 1-substituted triazoles, which appeared to proceed via competing S_N2 and S_N2′ mechanisms. The allylic systems were observed to undergo [2,3]-allyl walk reactions between the 1- and 2-ring positions. Allyl to vinyl isomerization also took place. Substitution of the allylic moiety increased the rate of reaction but decreased the rate of isomerization of allylic to the vinylic substituted triazoles. The 4-vinyl substituted triazoles were inert under the reaction conditions. Some triazoles were converted into substituted pyridines. This was proposed to proceed via nitrogen extrusion and formation of a 1,3-dipolar intermediate (nitrile ylide) which added intramolecularly to the allyl moiety and subsequently aromatized to the pyridine.     

[2]Catenane Synthesis via Covalent Templating

After earlier unsuccessful attempts, this work reports the application of covalent templating for the synthesis of mechanically interlocked molecules (MiMs) bearing no supramolecular recognition sites. Two linear strands were covalently connected in a perpendicular fashion by a central ketal linkage. After subsequent attachment of the first strand to a template via temporary benzylic linkages, the second was linked to the template in a backfolding macrocyclization. The resulting pseudo[1]rotaxane structure was successfully converted to a [2]catenane via a second macrocyclization and cleavage of the ketal and temporary linkages.     

Simulations of full multivariate Tweedie with flexible dependence structure

We employ a variables-in-common method for constructing multivariate Tweedie distributions, based on linear combinations of independent univariate Tweedie variables. The method lies on the convolution and scaling properties of the Tweedie laws, using the cumulant generating function for characterization of the distributions and correlation structure. The routine allows the equivalence between independence and zero correlation and gives a parametrization through given values of the mean vector and dispersion matrix, similarly to the Gaussian vector. Our approach leads to a matrix representation of multivariate Tweedie models, which permits the simulations of many known distributions, including Gaussian, Poisson, non-central gamma, gamma, and inverse Gaussian, both positively or negatively correlated.     

Kolmogorov Type Law of the Logarithm for Arrays

In this paper, we establish the analogue of Kolmogorov-type law of the logarithm for an array of independent random variables. The main methods are to develop the classic Bernstein’s and Kolmogorov’s inequality and replace the boundedness condition by conditions on the cumulant transform.     

Semigroups of measures in non-commutative harmonic analysis

We find the invariant convolution semigroups of measures on the Heisenberg group which are analogous to the familiar semigroups in the abelian context from modern potential theory, and we show that the abelian theory may be obtained as the limit of the Heisenberg case as Planck's constant tends to zero. Work supported in part by the NSF.     

Unbounded derivations tangential to compact groups of automorphisms

We consider unbounded derivations in C¹-algebras commuting with compact groups of ¹-automorphisms. A closed ¹-derivation δ in a C¹-algebra $\text{U}$ is said to be a generator if there exists a strongly continuous one-parameter subgroup t∈$\text{R}$→τ(t)? Aut($\text{U}$) such that $\text{δ =}\text{d}\text{dt}\text{τ(t)¦}{}_{\mathrm{t\; =\; 0}}$. If δ is known to commute with a compact abelian action α:G→Aut($\text{U}$), and if δ(a) = 0 for all a in the fixed point algebra $\text{U}$^α of the action G, then we show that δ is necessarily a generator. Moreover, in any faithful G-covariant representation, there is a commutative operator field γ ∈ ? → v(γ) such that $\text{v(γ)}{}^1\text{= ?v(γ), v(γ)}$ is possibly unbounded but affiliated with the center of {$\text{U}$^α}″, and e^tδ(x) = xe^tv(γ) for all x in the Arveson spectral subspace $\text{U}$^α(γ). In particular, if $\text{U}$ is the CAR algebra over an infinite-dimensional Hilbert space and α is the gauge group, then any such derivation δ is a scalar multiple of the generator of the gauge group.     

Cooperative and Non-Cooperative Differential Game Solutions to an Investment and Pricing Problem

A monopoly possesses a finite stock of a resource and wishes to determine an optimal pricing policy. The competitive fringe invests in production capacity and wishes to select an optimal investment rate. Demand towards the monopoly depends on price as well as on the sales rate of the competition. Modelling the situation as a differential game, non-cooperative (Nash and Stackelberg) and cooperative (Pareto) equilibria are determined. Owing to the special structure of the game, these solutions can be found in closed form.     

Cooperative Advertising in a Marketing Channel

This paper examines dynamic advertising and promotion strategies in a marketing channel where the retailer promotes the manufacturer product and the manufacturer spends on advertising to build a stock of goodwill. We assume that sales depend on goodwill and promotion activities and that there are decreasing marginal returns to goodwill. Two scenarios are studied. First, the manufacturer and retailer determine noncooperatively their respective strategies. Second, the game is played à la Stackelberg with the manufacturer as the leader who supports partially the cost of the promotion activities of the retailer. In both cases, stationary Markovian strategies are characterized. These scenarios are examined also in the absence of decreasing marginal effect of goodwill on sales. The results show that, whether or not the goodwill stock has a decreasing marginal effect on sales, the cooperative advertising program is a coordinating mechanism in the marketing channel, i.e., both players receive higher payoffs.     

Asymptotics of periodic subelliptic operators

We establish that heat diffusion with periodic conductivity is governed by two scales. The small time diffusion is described by the geodesic distance but the large time behaviour is dictated by the distance associated with an homogenized system obtained by a suitable averaging process. Our methods are quite general and apply to diffusion on a stratified Lie group.     

Rapidity dependence of charged antihadron to hadron ratios in Au+Au collisions at sqrt[s(NN)]=200 GeV

We present ratios of the numbers of charged antihadrons to hadrons (pions, kaons, and protons) in Au+Au collisions at sqrt[s(NN)]=200 GeV as a function of rapidity in the range y=0-3. While the ratios at midrapidity are approaching unity, the K(-)/K(+) and p;/p ratios decrease significantly at forward rapidities. An interpretation of the results within the statistical model indicates a reduction of the baryon chemical potential from mu(B) approximately 130 MeV at y=3 to mu(B) approximately 25 MeV at y=0.