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排序方式: 共有1323条查询结果,搜索用时 31 毫秒
101.
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The influence of different variables (stirring, degreasing, oxidant additions, pH, Ce concentration, anion type, time and temperature of immersion) on the optimization of Ce conversion and electrolysis coatings on both A3xx.x alloys and aluminium metal matrix composites A3xx.x/SiCp was evaluated in 3.5 wt% NaCl at 22 °C using potentiodynamic polarization. Ce treated surfaces presented better corrosion behaviour in chloride media than original material surfaces without treatment. Both treatments preferentially covered the intermetallic compounds and SiCp. The electrolysis afforded a higher degree of protection than conversion treatment because the coating was more extensive. Coating microstructure was analysed by scanning electron microscopy (SEM), atomic force microscopy (AFM) and X-ray photoelectron spectroscopy (XPS). 相似文献
104.
Robert Quintana Antxon martínez de Ilarduya Abdelilah Alla Sebastián Muñoz‐Guerra 《Journal of polymer science. Part A, Polymer chemistry》2011,49(10):2252-2260
Three series of terephthalate polyesters (copolyesters and terpolyesters) containing 70, 80, and 90 mol % of ethylene glycol respectively, 1,4‐cyclohexanedimethanol (CHDM) and isosorbide in varying ratios, were synthesized by melt polycondensation. It was found that only ~75 mol % of the feeding isosorbide was incorporated in the resulting polyesters and that their content in diethylene glycol oscillated between 2 and 4 mol %. The polyesters had weight‐average molecular weights in the 25,000–33,000 g mol?1 range and polydispersities between 2 and 2.5. The combined 1H and 13C NMR analysis revealed that the microstructure of all these polyesters was at random. They showed good thermal stability with decomposition temperatures above 400 °C. Their glass‐transition temperatures were observed to increase with the content in cyclic diols, this effect being more pronounced when isosorbide was the replacing comonomer. Only the series containing 90 mol % of ethylene terephthalate units was able to crystallize upon cooling from the melt. Compared isothermal crystallizations revealed that isosorbide was more effective than CHDM in repressing the crystallizability of PET. © 2011 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem, 2011 相似文献
105.
Orietta León Alexandra Muñoz‐Bonilla Vanesa Bordegé Manuel Sánchez‐Chaves Marta Fernández‐García 《Journal of polymer science. Part A, Polymer chemistry》2011,49(12):2627-2635
In this work the synthesis of poly(butyl acrylate)‐b‐poly(2‐{[(D ‐glucosamin‐2‐N‐yl)carbonyl]oxy}ethyl methacrylate) (PBA‐b‐PHEMAGl) diblock glycopolymer and poly(2‐{[(D ‐glucosamin‐2‐N‐yl)carbonyl]oxy}ethyl methacrylate)‐b‐poly(butyl acrylate)‐b‐poly(2‐{[(D ‐glucosamin‐2‐N‐yl)carbonyl]oxy}ethyl methacrylate) (PHEMAGl‐b‐PBA‐b‐PHEMAGl) was performed via atom transfer radical polymerization. Monofunctional and difunctional poly(butyl acrylate) macroinitiators were used to synthesize the well‐defined diblock and triblock glycopolymers by chain extension reaction with the glycomonomer HEMAGl. The self‐assembly of these glycopolymers in aqueous solution was studied by dynamic light scattering and transmission electron microcopy, showing the coexistence of spherical micelles and polymeric vesicles. In addition, the biomolecular recognition capacity of these micelles and vesicles, containing glucose moieties in their coronas, was investigated using the lectin Concanavalin A, Canavalia Ensiformis, which specifically interacts with glucose groups. The binding capacity of Concanavalin A with glycopolymer is influenced by the copolymer composition, increasing with the length of HEMAGl glycopolymer segment in the block copolymer. © 2011 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem, 2011 相似文献
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107.
J. Masiá-Pérez J. Escribano E. Valero E. Arribas M. García-Moreno J. L. Muñoz-Muñoz R. Gómez-Ladrón de Guevara R. Varón 《Journal of mathematical chemistry》2010,48(3):617-634
The kinetic study carried out in paper I of this series (preceding article) on enzyme systems involving zymogen activation
and the simultaneous action of two different, mutually exclusive inhibitors (Scheme 1) allows, new dimensionless kinetic parameters
to be suggested. These parameters furnish quantitative information about the relative weight of the activation and inhibition
routes, i.e. the conditions under which the activation prevails over the inhibition and vice versa, as well as the absolute
and relative contributions to overall inhibition of each of the inhibition routes and their synergistic effect. These results
can be easily and directly applied to any of the thousands of particular cases of the model. Examples are given for different
particular cases. 相似文献
108.
Gilberto Muñoz Moreno Noé Alcalá Ochoa 《Optics and Lasers in Engineering》2011,49(6):663-667
An analysis of phase modifications introduced by laser jitter in frequency-domain optical coherence tomography (OCT) is described. It is shown that a 1D spurious phase function is introduced as a consequence of this phenomenon. This phase function is added to any other introduced by the object under analysis causing a superposition of both. The result may impose some limitations for unambiguous determination of phase changes of objects. Experimental and theoretical results are presented. 相似文献
109.
María Muñoz 《Topology and its Applications》2008,156(2):438-442
In this paper we give some new topological cardinal inequalities in iterated function spaces. Open questions are posed. 相似文献
110.
J. A. H. Coaquira H. R. Rechenberg C. Marquina M. R. Ibarra A. M. Benito W. Maser E. Muñoz M. T. Martínez 《Hyperfine Interactions》2001,134(1):103-108
Iron particles encaged in carbon nanocapsules have been produced by the Krätschmer–Huffmann carbon-arc discharge method. Soot, collarette and cathode samples have been characterized by Mössbauer spectroscopy and magnetic measurements in the temperature range 4.2–300 K. Different iron phases and iron-carbon solid solutions have been detected in our samples. The Einstein model has been used to evaluate the coupling constant between the particles and their environment, yielding values of the order 1–10 N/m. Irreversibilities observed at ZFC and FC curves for soot samples would suggest the presence of superparamagnetism only if the particles presented a blocking temperature above 300 K. 相似文献