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21.
Iványi T Vander Heyden Y Visky D Baten P De Beer J Lázár I Massart DL Roets E Hoogmartens J 《Journal of chromatography. A》2002,954(1-2):99-114
This paper focuses on the classification or differentiation of RP-HPLC columns based on measured chromatographic properties. A chemometric study has been conducted on a published data set consisting of 85 RP-HPLC columns and on a data set consisting of 47 self-tested columns. Principal component analysis enables determination of the number of parameters necessary for a rational differentiation. The results show that reducing the number of parameters for such differentiation still allows classification of the columns just as a higher number did. It is shown that three test parameters produce a classification similar to that obtained with five parameters. 相似文献
22.
Nucleophilic addition of the peroxynitrite anion, ONOO(-), to the two prototypical carbonyl compounds, acetaldehyde and acetone, was investigated in the pH interval 7.4-14. The process is initiated by fast equilibration between the reactants and the corresponding tetrahedral adduct anion, the equilibrium being strongly shifted to the reactant side. The adduct anion also undergoes fast protonation by water and added buffers. Consequently, the rate of the bimolecular reaction between ONOO(-) and the carbonyl is strongly dependent on the pH and on the concentration of the buffer. The pK(a) of the carbonyl-ONOO adduct was estimated to be approximately 11.8 and approximately 12.3 for acetone and acetaldehyde, respectively. It is shown that both the anionic and the neutral adducts suffer fast homolysis along the weak O-O bond to yield free alkoxyl and nitrogen dioxide radicals. The yield of free radicals was determined to be about 15% with both carbonyl compounds at low and high pH, while the remainder collapses to molecular products in the solvent cage. The rate constants for the homolysis of the adducts vary from ca. 3 x 10(5) to ca. 5 x 10(6) s(-1), suggesting that they cannot act as oxidants in biological systems. This small variation around a mean value of about 10(6) s(-1) suggests that the O-O bond in the adduct is rather insensitive to its protonation state and to the nature of its carbonyl precursor. An overall reaction scheme was proposed, and all the corresponding rate constants were evaluated. Finally, thermokinetic considerations were employed to argue that the formation of dioxirane as an intermediate in the reaction of ONOO(-) with acetone is an unlikely process. 相似文献
23.
The crystal structure of 1-[N-(2-aminoethyl)aminopropyl]silatrane has been determined by x-ray diffraction at room temperature. The Si←N bond distance (2.165(2) Å) is in the range observed for other 1-X-propylsilatranes (X = CN, OH, SH, Cl and SCN). The structure is partially disordered: the silatrane moiety displays a disorder that is typical for silatranes and the aminoethyl group terminating the planar chain linked to silicon is rotationally disordered. 相似文献
24.
Summary The photodegradation behaviour of 12 nitrogen-containing herbicides (atrazine, cyanazine, terbuthylazine, terbutryn, EPTC,
buthylate, molinate, cycloate, vernolate, fenuron, chloroxuron, and methabenzthiazuron) has been examined. The compounds were
degraded completely when exposed to a mercury-vapour lamp; the degradation process was followed by consecutive GC measurements.
All the compounds studied had measurable photochemical activity, although actual and average degradation rates varied significantly.
All the compounds except terbutryn furnished more than one major degradation product, in different ratios.
Presented at Balaton Symposium '01 on High-Performance Separation Methods, Siófok, Hungary, September 2–4, 2001 相似文献
25.
L. Harsnyi P. Csszr A. Csszr J. E. Boggs 《International journal of quantum chemistry》1986,29(4):799-815
The vibrational spectrum of uracil trapped in an argon matrix has been interpreted based on ab initio Hartree–Fock SCF calculations with a split-valence 4?21 basis set. The directly computed theoretical general valence force field was scaled with empirical scale factors in order to correct for the systematic errors originating in the limitation of the theoretical model. Scale factors transferred from related molecules provided a priori prediction of fundamental frequencies and intensities, permitting several corrections to be proposed for earlier assignments. Using the observed spectrum with the few altered assignments, a new set of scale factors was optimized to give the best force field available from combined consideration of the experimental and the theoretical data. For unknown reasons, the out-of-plane force field predicted a spectrum agreeing slightly less well with experiment than did the in-plane force field. However, the overall agreement between theory and experiment provided additional support for the assumptions involved in the method. The computed force fields were compared with others available from previous work. The comparison demonstrated the importance of expanding the energy surface around the true energy minimum and of using a proper scaling procedure. Previous scaled CNDO /2 calculations were found to be surprisingly good despite the large corrections required and the fact that they were made at an incorrect geometry. 相似文献
26.
Heinz Günter Viehe Robert Mernyi Lucien Stella Zdenek Janousek 《Angewandte Chemie (International ed. in English)》1979,18(12):917-932
The 100 yers old Wurster's salts have long been recognized as compounds with redical cations. Their unusual stabilization derives partly form capto-dative (cd) substitution. This principle is now discussed as one factor of radical stabilization and it is applied to simple methine derivatives. cd-Substitution has synthetically useful applications: cd-substituents on a carbon atom allow its selective dehydrodimerization. Olefines with geminal and thus cross-conjugated cd-substituents are “radicophilic” and permit twofold carbon radical addition. cd-Substituted olefines are useful antioxidants, polymerization inhibitors and are promising agents in the control of biological radical reactions. Generally, many reactions of cd-substituted molecules appear to involve radicals. 相似文献
27.
E. Czárán O. V. Bragin M. Dobrovolszky Z. Karpinskii Z. Paál P. Tétényi 《Reaction Kinetics and Catalysis Letters》1977,7(2):211-218
Electron microscopic studies reveal that repeated air/hydrogen regeneration cycles cause irreversible structural changes of a Pt/C catalyst involving sintering and migration of the platinum over the support. This is reflected by a serious decrease of the catalytic activity. With hydrogen treatment only, these effects are less significant.
, / Pt/C, . . .相似文献
28.
We studied the reactions of some N-methylpyrrole derivatives with isopropenyl acetate and different acetic anhydrides. We have found that the reaction with isopropenyl acetate afforded 5-acetylpyrrole derivatives while with acetic anhydrides acetylation occurred on the α-carbon atom of the side-chain of pyrrole-2-acetic acid derivatives. 相似文献
29.
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