Nanofibers of Semiconductor Oxides as Sensitive Materials for Detection of Gaseous Products Formed in Low-Temperature Pyrolysis of Polyvinyl Chloride

Nanofibers of semiconducting oxides SnO₂, ZnO, WO₃, produced by the electrospinning method, were tested as sensitive materials for detection of products formed in pyrolysis of polyvinyl chloride in conditions simulating the smoldering of electrically insulating materials upon occurrence of a short-circuit failure in electrical circuits. The method of thermal analysis with mass-spectroscopic determination of gaseous products demonstrated that, in pyrolysis of polyvinyl chloride in the temperature range 200–400°C corresponding to the invisible-smoke stage, the main component of the gas mixture being formed is HCl. It was shown that the materials synthesized can be used to develop gas sensors for early fire warning.     

Electronic structure and lattice dynamics of domeykite Cu<Subscript>3</Subscript>As according to nuclear quadrupolar resonance of<Superscript>75</Superscript>As and<Superscript>63,65</Superscript>Cu

The temperature dependences of nuclear quadrupole resonance (NQR) frequencies, the line width and nuclear relaxation of⁷⁵As and^63,65Cu, as well as the electrical resistivity in domeykite Cu₃As are studied in the temperature range of 4.2-300 K. The comparison of the calculated with the measured lattice contribution to the NQR frequencies points at a substantial role played by the conduction electrons in creating the electric field gradient at the nuclei sites. The temperature dependence of the copper and arsenic nuclear spin-lattice relaxation linear at 4.2<T<200 K and that of the electric resistivity (30<T<200 K) prove the metallic character of the conductivity of domeykite. The enhancement of nuclear relaxation, the narrowing of copper and arsenic NQR line widths are considered as arising due to the ionic movement starting beyond 200 K. This movement influences the electric resistivity, most likely due to the inreasing density of states at the Fermi surface.     

Anisotropic<Emphasis Type="Italic">s</Emphasis>-wave or<Emphasis Type="Italic">d</Emphasis>-wave pairing? Analysis of experiments on ion irradiation of YBa<Subscript>2</Subscript>Cu<Subscript>3</Subscript>O<Subscript>7-x</Subscript> films

The effect of ion irradiation on the superconducting transition temperatureT _c and resistivityρ _ab (T) of YBa₂Cu₃O_7-x films with different oxygen content (initial temperatureT _c0≈90 K and 60 K) is studied experimentally. The dependenciesT _c /T _c0 on residual resistivityρ _o are obtained in very wide range 0.2<T _c /T _c0 <1 andρ _o μΩ·cm. The critical values ofρ _o , corresponding to the vanishing of superconductivity, are found to be an order of magnitude larger then those predicted by theory ford-wave pairing. At 0.5÷0.6<T _c /T _c0<1 the experimental data are in close agreement with theoretical dependencies, obtained for the anisotropics-wave superconductor within the BCS-framework.     

Investigation of the turbulent mixing of thin layers of materials of different density during the laser acceleration of flat multilayer targets in the Iskra-4 facility

The results of the first experiments devised to investigate the mixing of thin layers of Al and Au during the laser acceleration of flat three-layer targets of Si (5 μm), Al (2 μm), and Au (0.05–0.26 μm) by radiation converted to the second harmonic from the Iskra-4 iodine laser with an intensity of 4×10¹³−7×10¹³ W/cm² (τ _0.5∼1 ns), which acts on the Si side of the target. A method for detecting the occurrence of mixing is developed. It is established that under the experimental conditions the thickness of the mixing region is at least ∼0.15 μm. The results of a theoretical analysis of the evolution of the disturbances leading to mixing are presented. Zh. éksp. Teor. Fiz. 111, 882–888 (March 1997) Deceased.     

An Ideal-Fluid Flow through a Stationary Granular Layer in the Presence of a Flat Wall

Doklady Physics - The problem of the flow of an ideal incompressible fluid is considered along a flat surface, perpendicular to which a stationary granular layer is located. The granular-layer...     

Synchronized oscillations in a system of two coupled van-der-pol-duffing oscillators

The results of analysis of the periodic solutions obtained within the framework of complete and truncated equations for a system of identical Van-der-Pol-Duffing oscillators with nonlinear coupling are compared. This work was presented at the Summer Workshop “Dynamic Days” (Nizhny Novgorod, June 30–July 2, 1998). Institute of Applied Physics of the Russian Academy of Sciences, Nizhny Novgorod, Russia. Translated from Izvestiya Vysshikh Uchebnykh Zavedenii, Radiofizika, Vol. 41, No. 12, pp. 1531–1536, December, 1998.     

Study of the pd reaction at ultralow energies using hydrogen liner plasma

The pd reaction (pd → He + γ (5.5 MeV)) is studied in the astrophysical energy collision range of protons with deuterons using the hydrogen liner in the inverse Z-pinch configuration at the pulsed power generator MIG (HCEI, Tomsk). Fundamental characteristics of this and other light-nucleus reactions at ultralow energies are important for problems of basic physics and astrophysics. The knowledge of the energy distribution of the nuclei participating in these reactions is important due to their exponential type of dependence on the collision energy. Two experimental techniques were designed and tested for recovering the energy distribution of liner protons incident on the CD₂ target by using optical detectors and ion collectors. It is shown that the combined use of these two techniques could provide relevant information on the energy distribution of the accelerated protons in the liner. The estimates of the upper limits for the astrophysical S factor and effective cross section of the pd reaction in the proton-deuteron collision energy range of 2.7–16.7 keV are obtained: $\bar S_{pd} (E_{pd} = 10.2 keV) \leqslant 2.5 \times 10^{ - 7} MeV b;\overline \sigma _{pd} (2.7 \leqslant E_{pd} \leqslant 16.7 keV) \leqslant 4 \times 10^{ - 33} cm^2 $ .