Mo／2Si混合粉末的摩擦化学效应

利用 ZJM10 T型搅拌机和 X射线衍射仪研究了 Mo/ 2 Si混合粉末在机械球磨过程中的摩擦化学效应 .结果表明 :在球磨初期 ,晶粒尺寸明显减小 ,显微应变和有效温度系数明显增加 ;在球磨 3h后 ,Mo和 Si粉末的晶粒尺寸和显微应变变化幅度减小 ;球磨 10 h后 ,有效温度系数趋于极限值 ,晶粒尺寸和显微应变几乎保持不变 .塑性 Mo颗粒的机械活化以变形或晶格畸变加剧为主 ,而脆性 Si颗粒的机械活化以细化或比表面积增加为主 .球磨过程中未检测到摩擦化学变化     

Effective Synthesis of Polysubstituted Pyrroles from (E)-Dimethyl 2-(Bromomethyl)-3-(diethoxyphosphoryl) Fumarate

Methyl 1-alkyl-4-(diethoxyphosphoryl)-5-oxo-2,5-dihydro-1H-pyrroles-3-carboxylate 4 was synthesized from the reaction of dimethyl 2-(bromomethyl)-3-(diethoxyphosphoryl) fumarate 3- E and primary amines in good yields.     

Highly Reversible Cuprous Mediated Cathode Chemistry for Magnesium Batteries

Sluggish kinetics and poor reversibility of cathode chemistry is the major challenge for magnesium batteries to achieve high volumetric capacity. Introduction of the cuprous ion (Cu⁺) as a charge carrier can decouple the magnesiation related energy storage from the cathode electrochemistry. Cu⁺ is generated from a fast equilibrium between copper selenide electrode and Mg electrolyte during standing time, rather than in the electrochemical process. A reversible chemical magnesiation/de‐magnesiation can be driven by this solid/liquid equilibrium. During a typical discharge process, Cu⁺ is reduced to Cu and drives the equilibrium to promote the magnesiation process. The reversible Cu to Cu⁺ redox promotes the recharge process. This novel Cu⁺ mediated cathode chemistry of Mg battery leads to a high reversible areal capacity of 12.5 mAh cm^?2 with high mass loading (49.1 mg cm^?2) of the electrode. 80 % capacity retention can be achieved for 200 cycles after a conditioning process.     

硒的化学与生物形态分析综述

硒是人体必需的微量元素，其特殊的生理，生化功能不仅取决于硒的总浓度水平，而且同不同化学生物形态下硒的存在密切相关，硒的分析研究在生命科学、环境科学、医药科学等领域日益活跃。本文就近年来在硒分析方面发表的有关文献，从样品的采集条件，储存条件，消解过程，总量测定，特别是应用各种联用技术进行硒化物形态分析等诸方面，作出较系统全面的综述。     

具有离散参数齐次随机场的线性预测(XI)

本文提出和研究了一般的斜半平面和角形区域的具有离散参数齐次随机场的线性预测问题，求出了它们的预测值与预测误差，分别推广了[2],[3],[4]的结果。     

Cyclotomic Z2-extensions of J-fields

Hurwitz-type relations of Iwasawa's λ₂^?-invariants and the 2-ranks of the “narrow” ideal class groups in the 2-extensions of J-fields are given under the assumption of the vanishing of μ₂-invariants.     

李群方法在渗流力学的应用

试图用李群方法来分析流体及渗流的运动规律.对于流形上流体、渗流力学方程的研究,物理空间的流动中的拓扑结构只要具有李群的性质,便可以此来进行流动分析.这是将李群理论直接、直地应用于渗流力学的一种方法.李群方法将众多求解特定类型的渗流微分方程方法统一到共同的概念之下.李群无穷小变换方法为寻找微分方程的闭合形式的解提供的广泛的应用,补充了求解渗流力学方程的数学物理技巧.     

Two‐Step Synthesis of Multifunctional γ‐Lactams from γ‐Lactone

We present herein an efficient and rapid method for the synthesis of N,1‐dialkyl‐4‐(2‐hydroxyethyl)‐5‐oxopyrrolidine‐3‐carboxamides based on the conversion of γ‐lactone to γ‐lactam via the conjugate addition of primary amines to an ethyl α‐functionalized acrylate followed by intramolecular cyclization.     

Bicontinuous nanodisc and nanospherical titania materials prepared by sol-gel process in reverse microemulsion

TiO₂ nanoparticles with different shapes and sizes were synthesised by the sol-gel route in Water/Brij78/Hexane reverse microemulsions. The aqueous cores of these microemulsions were used as nanoreactors to control sol-gel reactions. We studied the effect of water/surfactant mole ratio (W ₀) on the morphology, and textural properties of the final products. The materials thus obtained were characterised by different techniques. Thermogravimetric and differential thermal analysis (TG-DTA) was used to study the thermal behaviour of the products and X-ray diffraction (XRD) to identify the crystalline phases. The morphological and textural properties of the products were determined by scattering electron microscopy (SEM) and the Brunauer-Emmett-Teller (BET) method, respectively. We also studied the influence of thermal treatment on the structure and size of the TiO₂ particles. The effect of W ₀ on the anatase-rutile phase transition temperature was investigated.     

Étude de l’activité catalytique des argiles pontées aluminium,zirconium et cérium dans la synthèse du 2,2-diméthyl-1,3-dioxolane

The purified Tunisian clay G and the commercialized American clay W were pillared with zirconium, aluminum and mixed pillars zirconium–aluminum, cerium–zirconium, cerium–aluminum, and cerium–zirconium–aluminum. These different clays were used in the synthesis of 2,2-dimethyl-1,3-dioxolane 3 by acetalyzation of acetone 2 with ethylene glycol 1 under autogenously pressure and without solvent. Results indicate that the yield of product 3 depends of the nature and the acidity of the clay used and the time of reaction.