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31.
The influence of nucleus density on optical properties in nucleated isotactic polypropylene 总被引:1,自引:0,他引:1
Alfrd Menyhrd Markus Gahleitner Jzsef Varga Klaus Bernreitner Pirjo Jskelinen Harry
ysd Bla Puknszky 《European Polymer Journal》2009,45(11):3138-3148
The effect and efficiency of three nucleating agents, a sorbitol based clarifier, a traditional heterogeneous nucleating agent and poly(vinylcyclohexane) (PVCH) was studied in polypropylene (iPP) homopolymer. The nucleating agents were added to iPP in different amounts; PVCH in 0–200 ppm, while the other two in 0–2000 ppm. Optical and mechanical properties were determined on injection molded plates or bars, respectively. Nucleation efficiency was studied by thermal analysis, while structure was characterized by polarized light (PLM), scanning electron (SEM) and atomic force microscopy (AFM). Nucleus density was calculated using the method of Lamberti, which is based on the kinetic theory of the crystallization developed by Lauritzen and Hoffmann. The results proved that the nucleating agents modify properties in different ways and extent. PVCH is very efficient already at small concentrations and increases the stiffness of iPP considerably more than the other two compounds. On the other hand, the clarifier and the traditional nucleating agent induce better optical properties even at smaller efficiency. The structure developing in the presence of the three nucleating agents is also different. The clarifier forms a network in iPP and induces the formation of a microcrystalline structure according to the former literature data. Microspherulitic structure develops in the presence of the heterogeneous nucleating agent studied, while relatively large supermolecular units form in iPP nucleated by PVCH even under the conditions of injection molding. The calculation of nucleus density by existing models and the comparison of the results to optical properties proved that haze is determined by the size of the supermolecular units of the polymer and this latter depends on nucleus density. 相似文献
32.
We apply time-dependent density functional theory to study the valence electron excitations of molecules and generalize the typically used time-propagation scheme and Casida's method to calculate the full wavevector dependent response function. This allows the computational study of dipole-forbidden valence electron transitions and the dispersion of spectral weight as a function of the wavevector. The method provides a novel analysis tool for spectroscopic methods such as inelastic x-ray scattering and electron energy loss spectroscopy. We present results for benzene and CF(3)Cl and make a comparison with experimental results. 相似文献
33.
Róbert Berkecz Anna R. M. Hyyryläinen Ferenc Fülöp Antal Péter Tamás Janáky Pirjo Vainiotalo Jaana M. H. Pakarinen 《Journal of mass spectrometry : JMS》2010,45(11):1312-1319
Chiral discrimination of seven enantiomeric pairs of β‐3‐homo‐amino acids was studied by using the kinetic method and trimeric metal‐bound complexes, with natural and unnatural α‐amino acids as chiral reference compounds and divalent metal ions (Cu2+ and Ni2+) as the center ions. The β‐3‐homo‐amino acids were selected for this study because, first of all, chiral discrimination of β‐amino acids has not been extensively studied by mass spectrometry. Moreover, these β‐3‐homo‐amino acids studied have different aromatic side chains. Thus, the emphasis was to study the effect of the side chain (electron density of the phenyl ring, as well as the difference between phenyl and benzyl side chains) for the chiral discrimination. The results showed that by the proper choice of a metal ion and a chiral reference compound, all seven enantiomeric pairs of β‐3‐homo‐amino acids could be differentiated. Moreover, it was noted that the β‐3‐homo‐amino acids with benzyl side chains provided higher enantioselectivity than the corresponding phenyl ones. However, increasing or decreasing the electron density of the aromatic ring by different substituents in both the phenyl and benzyl side chains had practically no role for chiral discrimination of β‐3‐homo‐amino acids studied. When copper was used as the central metal, the phenyl side chain containing reference molecules (S)‐2‐amino‐2‐phenylacetic acid (L ‐Phg) and (S)‐2‐amino‐2‐(4‐hydroxyphenyl)‐acetic acid (L ‐4′‐OHPhg) gave rise to an additional copper‐reduced dimeric fragment ion, [CuI(ref)(A)]+. The inclusion of this ion improved noticeably the enantioselectivity values obtained. Copyright © 2010 John Wiley & Sons, Ltd. 相似文献
34.
Teija Koivula Jaana Laine Tiina Lipponen Outi Perhola Eeva-Liisa K?m?r?inen Kim Bergstr?m Olof Solin 《Journal of Radioanalytical and Nuclear Chemistry》2010,286(3):841-846
The serotonin receptor 5-HT1A ligand 4-[18F]fluoro-N-[2-[1-(2-methoxyphenyl)-1-piperazinyl]ethyl-N-2-pyridinyl-benzamide (p-[18F]MPPF) was produced by a simplified method of Le Bars et al. Traditional oil bath heating was compared to microwave heating.
Various radioanalytical methods, radio-Thin Layer Chromatography (TLC), High Pressure Liquid Chromatography (HPLC) and Mass
Spectrometry (MS), were compared in the evaluation of the labelled product(s). The crude reaction mixture consisted of p-[18F]MPPF and 2–4 radioactive by-products eluting after the product fraction, and the reverse-phase HPLC method failed occasionally
to separate p-[18F]MPPF from the radioactive by-product with close retention time. The heating method had no significant effect on the composition
of labelled by-products. In LC-(ESI)-MS analysis of p-[18F]MPPF the labelled product was identified with m/z ratio of 435 ([M + H+]). The other HPLC fractions were measured to have following m/z ratios: (1) 327; 349; (675) (2) 402; 407/408; (791) and (3) 436, suggesting different kind of decomposition of the labelled
product and/or the inactive precursor. The ion trap mass spectrometer was sufficient for the qualitative analysis of p-[18F]MPPF. However, differentiation of by-products arising from the decomposition of p-[18F]MPPF or from its precursor p-MPPNO2 proved to be challenging. 相似文献
35.
Totti Laitinen Sara Herrero Martín Jevgeni Parshintsev Tuulia Hyötyläinen Kari Hartonen Marja-Liisa Riekkola Markku Kulmala José Luis Pérez Pavón 《Journal of chromatography. A》2010,1217(1):151-159
Organic compounds in atmospheric nanoparticles have an effect on human health and the climate. The determination of these particles is challenged by the difficulty of sampling, the complexity of sample composition, and the trace-level concentrations of the compounds. Meeting the challenge requires the development of sophisticated sampling systems for size-resolved particles and the optimization of sensitive, accurate and simple analytical techniques and methods. A new sampling system is proposed where particles are charged with a bipolar charger and size-segregated with a differential mobility analyzer. This system was successfully used to sample particles from wood pyrolysis with particle sizes 30–100 nm. Particles were analyzed by four techniques: comprehensive two-dimensional gas chromatography–time-of-flight mass spectrometry, gas chromatography–time-of-flight mass spectrometry, gas chromatography–quadrupole mass spectrometry, and aerosol mass spectrometry (aerosol MS). In the chromatographic techniques, particles were collected on a filter and analyzed off-line after sample preparation, whereas in the aerosol MS, particle analysis was performed directly from the particle source. Target compounds of the samples were polyaromatic hydrocarbons and n-alkanes. The analytical techniques were compared and their advantages and disadvantages were evaluated. The sampling system operated well and target compounds were identified in low concentrations. 相似文献
36.
Hämäläinen SK Sun Z Boneschanscher MP Uppstu A Ijäs M Harju A Vanmaekelbergh D Liljeroth P 《Physical review letters》2011,107(23):236803
Despite the enormous interest in the properties of graphene and the potential of graphene nanostructures in electronic applications, the study of quantum-confined states in atomically well-defined graphene nanostructures remains an experimental challenge. Here, we study graphene quantum dots (GQDs) with well-defined edges in the zigzag direction, grown by chemical vapor deposition on an Ir(111) substrate by low-temperature scanning tunneling microscopy and spectroscopy. We measure the atomic structure and local density of states of individual GQDs as a function of their size and shape in the range from a couple of nanometers up to ca. 20 nm. The results can be quantitatively modeled by a relativistic wave equation and atomistic tight-binding calculations. The observed states are analogous to the solutions of the textbook "particle-in-a-box" problem applied to relativistic massless fermions. 相似文献
37.
P Permi S Heikkinen I Kilpel?inen A Annila 《Journal of magnetic resonance (San Diego, Calif. : 1997)》1999,139(2):273-280
(1)H-detected two-dimensional double-/zero-quantum experiments are described for measurement of homonuclear (2)J(HH)-couplings of NH(2) or CH(2) groups in proteins. These experiments utilize multiple-quantum coherence for determination of the size and the absolute sign of the geminal scalar and dipolar couplings in the presence of broad lines. Spectra are simplified by gradient selection and spin-state selective filters. 相似文献
38.
Summary The Onsager and Lorentz local fields ofF colour centres are compared and their change as a function of angular frequency and temperature is also considered. The change
of these fields is proportional to the change of the refractive index produced byF centres. Some approximations about the explicit temperature dependence of the refractive-index change are also presented.
Riassunto I campi locali di Onsager e Lorentz diF centri di colore sono confrontati e si considera il loro cambiamento in funzione della frequenza angolare e della temperatura. Il cambiamento di questi campi è proporzionale al cambiamento dell'indice di rifrazione prodotto daF centri. Si presentano anche alcune approssimazioni riguardo alla esplicita dipendenza dalla temperatura del cambiamento dell'indice di rifrazione.相似文献
39.
Hiroaki Aikawa Tero Kilpeläinen Nageswari Shanmugalingam Xiao Zhong 《Potential Analysis》2007,26(3):281-301
We establish a scale-invariant version of the boundary Harnack principle for p-harmonic functions in Euclidean C
1,1-domains and obtain estimates for the decay rates of positive p-harmonic functions vanishing on a segment of the boundary in terms of the distance to the boundary. We use these estimates
to study the behavior of conformal Martin kernel functions and positive p-superharmonic functions near the boundary of the domain.
H. A. was partially supported by Grant-in-Aid for (B) (2) (No. 15340046) Japan Society for the Promotion of Science. N. S.
was partially supported by NSF grant DMS-0355027. X. Z. was partially supported by the Taft foundation. 相似文献
40.