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121.
We study in this paper the thin multilayered film of the system Fe
x
Zr1-x
using conversion electron Mössbauer spectroscopy (CEMS) as well as Rutherford backscattering spectroscopy (RBS). The solid state reaction (SSR) at 500°C for thex=0.33 andx=0.67 concentrations produces crystalline and amorphous phases. For the concentrationx=0.50 only an amorphous phase is obtained. For reactions at 700°C, besides Fe-Zr phases, another one is observed in the CEMS spectrum. This phase may be associated with some FeSi compound since the RBS profile shows the presence of Si at the surface.This work was supported by CNPq, FINEP and FAPERGS. 相似文献
122.
Maria do Rosário de Pinho 《Journal of Mathematical Analysis and Applications》2003,278(2):293-307
Necessary optimality conditions are derived in the form of a weak maximum principle for optimal control problems with mixed state-control equality and inequality constraints. In contrast to previous work these conditions hold when the Jacobian of the active constraints, with respect to the unconstrained control variable, has full rank. A feature of these conditions is that they are stated in terms of a joint Clarke subdifferential. Furthermore the use of the joint subdifferential gives sufficiency for nonsmooth, normal, linear convex problems. The main point of interest is not only the full rank condition assumption but also the nature of the analysis employed in this paper. A key element is the removal of the constraints and application of Ekeland's variational principle. 相似文献
123.
Manfredo Hörner Gelson Manzoni de Oliveira Eduardo Giuliani Koehler Lorenzo do CantoVisentin 《Journal of organometallic chemistry》2006,691(6):1311-1314
Deprotonated 1,3-bis(3-acetylphenyl)triazene reacts with Hg(CH3COO)2 and pyridine to give light-yellow crystals of {[HgII(RC6H4NNNC6H4R)2Py]}n (R = acetyl). The tectons [HgII(RC6H4NNNC6H4R)2Py] [R = CH3C(O)] are linked to pairs as centrosymmetric dimers through reciprocal metal-η2-arene π-interactions. The dimeric units are operated by a screw axis 21 parallel to the crystallographic direction [0 1 0], also through a reflection-translation plane parallel to the c-axis, resulting a supramolecular bidimensional (2D) assembling of the dimeric tectons through non classical C-H?(O)CCH3 bonding. 相似文献
124.
Elvio A. Campos Yoshitaka Gushikem Maria do Carmo Gonçalves Sandra C. de Castro 《Journal of colloid and interface science》1996,180(2):453
The Nb2O5/cellulose composite was prepared by reacting α-cellulose with NbCl5-n(OC2H5)n, in nonaqueous solvent, under nitrogen atmosphere and submitting the obtained material to hydrolysis. An increase in the crystallinity degree is observed in the composite material because the precursor reagent reacts with the amorphous phase of the cellulose fibers. Loadings between 4.5 and 16.0% of the oxide were achieved and in every case the oxide particles uniformly cover the fiber surface. Lewis and Brønsted acid sites were determined by using pyridine as the basic molecular probe. 相似文献
125.
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128.
CaCu3Ti4O12 (CCTO) has challenged for the last few years the scientific community due to its large dielectric constant, which is almost temperature and frequency independent, from 100 K to 400 K and from 1 kHz to 1 MHz, respectively. This makes the material desirable for many electronic applications. However, the dissipation factor is very large, with tan δ values, at room temperature and 1 kHz, higher than 0.1.In our work we report how the addition of TeO2 lowers the dielectric loss and, although there is a decrease of dielectric constant of doped samples relatively to the undoped one, high dielectric constant values are still being reached. The sample of doped CCTO with 1.5% of TeO2 by weight, presents, at room temperature and 60 kHz, a large dielectric constant, over 3000, and a dissipation factor around 0.09, which represents a decrease on tan δ over 30% relatively to the CCTO undoped sample. Two relaxation processes were identified for all the samples, one at MHz region and the other one at low frequency region (< 1 kHz). DC bias voltage was applied up to 40 V and a strong dc bias influence on the low frequency region was observed both at dielectric and impedance responses of the undoped sample, which was much weaker than the dc bias effects on the 4% Te doped sample.Dielectric measurements will be discussed and correlated with the samples' microstructure, supported on internal barrier layer capacitance (IBLC) and surface barrier layer capacitance (SBLC) models. 相似文献
129.
Radium equivalent and annual effective dose from geological samples from Pedra – Pernambuco – Brazil
The natural radioactivity of an uranium-anomalous area utilized for agricultural activities in Pedra, Brazil, was monitored. For this, samples from the granite and calcium-silicate amphibole rocks underlying this area and also from samples of the soil derived from these rocks were collected and analyzed by high-resolution gamma spectrometry. The equivalent radium (Raeq) was used as a reference for estimating the rate of the effective equivalent dose. The average, minimum and maximum values for the samples were of 319.2 Bq kg?1 (91.1–758.5 Bq kg?1) for soil; 327.5 Bq kg?1 (36.3–1624.0 Bq kg?1) for granitic rocks and 70,124.5 Bq kg?1 (16,979.6–147,159.0 Bq kg?1) for the calcium-silicate amphibole rocks. An estimation of the external exposition was carried out based on the calculation of the parameters obtained. 相似文献
130.
Given an Ext-injective stratifying system of Λ-modules satisfying that the projective dimension of Y is finite, we prove that the finitistic dimension of the algebra Λ is equal to the finitistic dimension of the category . Moreover, using the theory of stratifying systems we obtain bounds for the finitistic dimension of Λ. In particular, we get the optimal bound 2n-2 for the finitistic dimension of a standardly stratified algebra with n simples. 相似文献