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101.
Yanying Lu Tianyu Zhu Wessel van den Bergh Morgan Stefik Kevin Huang 《Angewandte Chemie (International ed. in English)》2020,59(39):17004-17011
Developing high capacity and stable cathodes is a key to successful commercialization of aqueous Zn‐ion batteries (ZIBs). Pure layered V2O5 has a high theoretical capacity (585 mAh g?1), but it suffers severe capacity decay. Pre‐inserting cations into V2O5 can substantially stabilize the performance, but at an expense of lowered capacity. Here we show that an atomic layer deposition derived V2O5 can be an excellent ZIB cathode with high capacity and exceptional cycle stability at once. We report a rapid in situ on‐site transformation of V2O5 atomic layers into Zn3V2O7(OH)2?2 H2O (ZVO) nanoflake clusters, also a known Zn‐ion and proton intercalatable material. High concentration of reactive sites, strong bonding to the conductive substrate, nanosized thickness and binder‐free composition facilitate ionic transport and promote the best utilization of the active material. We also provide new insights into the V2O5‐dissolution mechanisms for different Zn‐salt aqueous electrolytes and their implications to the cycle stability. 相似文献
102.
103.
104.
A. Mavinkurve S. Visser W. van den Broek A. J. Pennings 《Journal of polymer science. Part A, Polymer chemistry》1996,34(6):985-990
A polymer consisting of a saturated carbon backbone with pendent acetylenic groups was prepared from monovinylacetylene. A titration was performed between the monomer and tertiary butyllithium, its lithiating agent. The charge transfer complex formed between the solvent THF and the tertiary butyllithium was used as an indicator of the unreacted butyllithium. Hence, a stoichiometric quantity of tertiary butyllithium was added dropwise to a solution of monovinylacetylene in THF to form lithiovinylacetylene. The addition of a slight excess of butyllithium led to the polymerization of the lithiated monomer. The obtained polymer was reprotonated and characterized. This polymerization was evaluated as a possible route to synthesize poly(vinylacetylene) with processable molecular weights, for its application as a potential carbon fiber precursor. © 1996 John Wiley & Sons, Inc. 相似文献
105.
E A Hogendoorn K Westhuis E Dijkman H A Heusinkveld A C den Boer E A Evers R A Baumann 《Journal of chromatography. A》1999,858(1):45-54
The coupled-column (LC-LC) configuration consisting of a 3 microm C18 column (50 x 4.6 mm I.D.) as the first column and a 5 microm C18 semi-permeable-surface (SPS) column (150 x 4.6 mm I.D.) as the second column appeared to be successful for the screening of acidic pesticides in surface water samples. In comparison to LC-LC employing two C18 columns, the combination of C18/SPS-C18 significantly decreased the baseline deviation caused by the hump of the co-extracted humic substances when using UV detection (217 nm). The developed LC-LC procedure allowed the simultaneous determination of the target analytes bentazone and bromoxynil in uncleaned extracts of surface water samples to a level of 0.05 microg/l in less than 15 min. In combination with a simple solid-phase extraction step (200 ml of water on a 500 mg C18-bonded silica) the analytical procedure provides a high sample throughput. During a period of about five months more than 200 ditch-water samples originating from agricultural locations were analyzed with the developed procedure. Validation of the method was performed by randomly analyzing recoveries of water samples spiked at levels of 0.1 microg/l (n=10), 0.5 microg/l (n=7) and 2.5 microg/l (n=4). Weighted regression of the recovery data showed that the method provides overall recoveries of 95 and 100% for bentazone and bromoxynil, respectively, with corresponding intra-laboratory reproducibilities of 10 and 11%, respectively. Confirmation of the analytes in part of the samples extracts was carried out with GC-negative ion chemical ionization MS involving a derivatization step with bis(trifluoromethyl)benzyl bromide. No false negatives or positives were observed. 相似文献
106.
Verheyen S. Blaton N. Kinget R. Van den Mooter G. 《Journal of Thermal Analysis and Calorimetry》2003,73(2):563-576
The effect of grinding on the physical properties and pharmaceutical performance of solid dispersions made of poly(ethylene)
glycol 6000 (PEG6000) and temazepam or diazepam was studied using differential scanning calorimetry (DSC), X-ray powder diffraction
and dissolution experiments. DSC-analysis of flash-cooled dispersions revealed that amorphous PEG present immediately after
grinding crystallised upon aging mainly into the twice folded modification and to a small extent into the extended form. DSC-analysis
of dispersions kept in the slab form for 1 month and subsequently ground, revealed that in the abscence of the grinding impulse
crystallisation of PEG6000 takes place in the same way as in dispersions ground immediately after preparation and then aged
for 1 month. Grinding solid dispersions immediately after preparation resulted in superior dissolution properties compared
with solid dispersions kept in the monolith-slab form and subsequently ground. This difference in dissolution properties was
found to be attributed to the drug and not to the polymer, more precisely, it was suggested that the drug particle size in
ground dispersions was smaller than in dispersions kept in the slab form and subsequently ground. These findings suggest that
grinding of solid dispersions immediately after preparation is the preparation method of choice instead of liquid filling
of hard gelatin capsules resulting in monoliths.
This revised version was published online in July 2006 with corrections to the Cover Date. 相似文献
107.
Svetlana Ignatova David HawesRemco van den Heuvel Peter HewitsonIan A. Sutherland 《Journal of chromatography. A》2010,1217(1):34-39
A new and significantly more robust design of non-synchronous coil planet centrifuge is introduced where the degree of mixing between two immiscible phases can be changed independently from the “g” field required to separate out the phases. A hypothesis that an optimum ratio between the speed of the bobbin and the speed of the rotor can be found to optimise the efficiency of the separation for a given force field is upheld for an intermediate polarity phase system. This paves the way for extensive further research to find the optimum non-synchronous conditions for a range of different phase systems that are desirable for the separation of large molecules, proteins and biologics but can tend to emulsify in the standard “J” type centrifuge systems currently available and routinely in use for aqueous organic phase systems. A step change of up to 30% in resolution and 90% in plate efficiency is demonstrated. 相似文献
108.
R. Malhotra M. R. H. Mandjes W. R. W. Scheinhardt J. L. van den Berg 《Mathematical Methods of Operations Research》2009,70(1):149-169
Feedback fluid queues play an important role in modeling congestion control mechanisms for packet networks. In this paper
we present and analyze a fluid queue with a feedback-based traffic rate adaptation scheme which uses two thresholds. The higher
threshold B
1 is used to signal the beginning of congestion while the lower threshold B
2 signals the end of congestion. These two parameters together allow to make the trade-off between maximizing throughput performance
and minimizing delay. The difference between the two thresholds helps to control the amount of feedback signals sent to the
traffic source. In our model the input source can behave like either of two Markov fluid processes. The first applies as long
as the upper threshold B
1 has not been hit from below. As soon as that happens, the traffic source adapts and switches to the second process, until
B
2 (smaller than B
1) is hit from above. We analyze the model by setting up the Kolmogorov forward equations, then solving the corresponding balance
equations using a spectral expansion, and finally identifying sufficient constraints to solve for the unknowns in the solution.
In particular, our analysis yields expressions for the stationary distribution of the buffer occupancy, the buffer delay distribution,
and the throughput. 相似文献
109.
Virginie Aumond Matthieu Waeles Pascal Salaün Kristoff Gibbon-Walsh Constant M.G. van den Berg Pierre-Marie Sarradin Ricardo D. Riso 《Analytica chimica acta》2012
A rapid electrochemical stripping chronopotentiometric procedure to determined sulfide in unaltered hydrothermal seawater samples is presented. Sulfide is deposited at −0.25 V (vs Ag/AgCl, KCl 3 M) at a vibrating gold microwire and then stripped through the application of a reductive constant current (typically −2 μA). The hydrodynamic conditions are modulated by vibration allowing a short deposition step, which is shown here to be necessary to minimize H2S volatilization. The limit of detection (LOD) is 30 nM after a deposition step of 7 s. This LOD is in the same range as the most sensitive cathodic voltammetric technique using a mercury drop electrode and is well below those reported previously for other electrodes capable of being implemented in situ. 相似文献
110.
Vizing established an upper bound on the size of a graph of given order and radius. We find a sharp upper bound on the size of a bipartite graph of given order and radius. 相似文献