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971.
Microstructure characterization of titanium dioxide nanodispersions and thin films for dye-sensitized solar cell devices 总被引:1,自引:0,他引:1
P.?de AlmeidaEmail author J.?van Deelen C.?Catry H.?Sneyers T.?Pataki R.?Andriessen C.?Van Roost J.M.?Kroon 《Applied Physics A: Materials Science & Processing》2004,79(7):1819-1828
This article reports on the microstructure characterization of titanium dioxide nanodispersions and thin films made thereof for dye-sensitized solar cell devices. Structure–property relationships have been investigated mainly using electron microscopy to assess how microstructure (crystalline structure, defects) and morphological (e.g. heterogeneities, inclusions, voids) features in the electron transport element of the solar cell device correlate with electrical performance, namely, short-circuit photocurrent density (Jsc). This work shows that for a nanodispersion synthesized in the laboratory different electrical performances are measurable depending on the thin film forming process, more specifically, heat-sintering at 450 °C or pressure-sintering at 500 bar. For the heat-sintered device Jsc is about 7.3 mA/cm2 whereas for the pressure-sintered one this value is much lower, this difference being attributed to the existence of inclusions in the titanium dioxide matrix, which are spatially isolated from the rest of the electron transport element thereby limiting the charge transport process by promoting their premature recombination. PACS 68.37.Lp; 73.61.Le; 81.40.-z; 84.60.Jt 相似文献
972.
Mutual mass diffusion and thermal diffusion has been investigated in poly(dimethylsiloxane)/ poly(ethylmethylsiloxane) (PDMS/PEMS) polymer blends of equal weight fractions. Molar masses ranged from below 1 to over 20 kg/mol. Both the mutual mass (D) and the thermal diffusion (DT) coefficient contain a thermally activated factor with an activation temperature of 1415 K. The molar mass dependence of DT is due to an end-group effect of the local friction coefficient. The thermal diffusion coefficient in the limit of long chains and infinite temperature is DT0, = - 1.69×10-7cm2(sK)-1. The Soret coefficient ST of blends far enough away from a critical point is proportional to the static structure factor S(q = 0). 相似文献
973.
974.
S.?Cheedket V.?E.?LyubovitskijEmail author Th.?Gutsche Amand?Faessler K.?Pumsa-ard Y.?Yan 《The European Physical Journal A - Hadrons and Nuclei》2004,20(2):317-327
We apply the perturbative chiral quark model at one loop to analyze the electromagnetic form factors of the baryon octet. The analytic expressions for baryon form factors, which are given in terms of fundamental parameters of low-energy pion-nucleon physics (weak pion decay constant, axial nucleon coupling, strong pion-nucleon form factor), and the numerical results for baryon magnetic moments, charge and magnetic radii are presented. Our results are in good agreement with experimental data.Received: 7 January 2003, Revised: 4 November 2003, Published online: 15 April 2004PACS:
12.39.Ki Relativistic quark model - 13.40.Gp Electromagnetic form factors - 14.20.Dh Protons and neutrons - 14.20.Jn Hyperons 相似文献
975.
R.H.?BirknerEmail author J.?Kaiser W.?Els?sser C.?Jung 《Applied physics. B, Lasers and optics》2004,79(8):963-967
We demonstrate the interplay between the intensity noise and the spatial emission characteristics of resonant-cavity light-emitting diodes. First, we find that the total aperture intensity noise exhibits a sub-shot noise behavior in a quite large pumping regime. Second, we investigate the angular, spectral, and spatial emission characteristics of the devices by controlling the shape and width of the angular intensity distribution via temperature detuning of the quantum well wavelength and the cavity resonance wavelength. Finally, the angular and aperture resolved intensity noise exhibit a super-shot noise behavior in contrast to that of the total emission. We explain this difference with anticorrelations between various radial components which increase with the temperature-tuned extension of the spatial emission. PACS 85.60.Jb; 42.50.L; 23.20.En 相似文献
976.
We present X-ray reflectivity investigations of the concentration distribution in binary liquid thin films on silicon substrates. The liquid-vapor coexistence of the binary mixture investigated, hexane and perfluorohexane, is far from criticality. Therefore, a sharp interface separates the liquid film from the vapor. The data reveal a separation of the film in layers parallel to the substrate. A phase diagram is constructed as a projection to the (composition difference, temperature) space, covering a temperature range corresponding to the one-phase and the two-phase regime of the bulk liquid. Although the composition data indicate a mixing gap similar to that of the bulk system, there are two major differences: i) only the near-surface phase changes its composition significantly, and ii) a composition gradient in the film exists also at higher temperatures where in the bulk system the one-phase regime exists.Received: 28 April 2004, Published online: 21 September 2004PACS:
61.10.Kw X-ray reflectometry (surfaces, interfaces, films) - 64.75. + g Solubility, segregation, and mixing; phase separation - 68.15. + e Liquid thin films 相似文献
977.
A.?Thon M.?Merschdorf W.?PfeifferEmail author T.?Klamroth P.?Saalfrank D.?Diesing 《Applied Physics A: Materials Science & Processing》2004,78(2):189-199
Photocurrent measurements in Ag–Al2O3–Al metal–insulator–metal junctions under illumination with ultra-short laser pulses reveal that tunneling and internal photoemission of excited electrons are the dominating transport mechanisms. Photon-assisted tunneling is observed under rare conditions that depend critically on the preparation of the interface. The comparison of time-resolved two-pulse correlation measurements with model calculations shows that the photon-induced transport of excited electrons is well described using a one-dimensional many-particle model for two coupled metallic leads, whereas a single-particle model for nonresonant excitation in a rectangular double-minimum potential reveals the signature of photon-assisted tunneling. PACS 73.40.-c; 72.10.-d; 73.40.Gk; 73.50.Pz 相似文献
978.
A.?VoigtEmail author W.?Wenzel J.?Richter P.?Tomczak 《The European Physical Journal B - Condensed Matter and Complex Systems》2004,38(1):49-58
We investigate an antiferromagnetic s = 1/2 quantum spin system with anisotropic spin exchange on a fractal lattice, the Sierpiski gasket. We introduce a novel approximative numerical method, the configuration selective diagonalization (CSD) and apply this method to a the Sierpiski gasket with N = 42. Using this and other methods we calculate ground state energies, spin gap, spin-spin correlations and specific heat data and conclude that the s = 1/2 quantum antiferromagnet on the Sierpinski gasket shows a disordered magnetic ground state with on the Sierpinski gasket shows a disordered magnetic ground state with a very short correlation length of
and an, albeit very small, spin gap. This conclusion holds for Heisenberg as well a for XY exchange.Received: 18 February 2004, Published online: 20 April 2004PACS:
75.10.-b General theory and models of magnetic ordering - 05.45.Df Fractals - 75.40.Mg Numerical simulation studies 相似文献
979.
de Oliveira Cristina Soltovski Bet Camila Delinski Bisinella Radla Zabian Bassetto Waiga Lucas Henrique Colman Tiago André Denck Schnitzler Egon 《Journal of Thermal Analysis and Calorimetry》2018,133(3):1491-1498
Journal of Thermal Analysis and Calorimetry - Samples of potato starch (PS), sweet potato starch (SPS) and their binary mixtures, with moisture levels of 10, 15 and 20% (db), were submitted to... 相似文献
980.