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181.
一种新型有机电致微腔结构的双模发射 总被引:4,自引:4,他引:0
采用结构Glass/DBR/ITO/NPB/NPB:Alq/Alq/Al制作了有机微腔电致发光器件。将空穴传输材料与发光材料以一定比例混合作为发光层,为了便于对比,在不改变有机层的膜厚的情况下同时制作了传统的异质结微腔器件,发现两种器件的发光光谱有很大不同,器件的复合效率与传统的异质结器件相比也得到了很大提高,这是因为将两种有机材料混合能消除界面势垒,提高器件的复合效率,从而提高了器件的发光性能,实现了微腔双模发射,且两个模式的半峰全宽分别为8nm和12nm。通过进一步优化器件结构可以实现微腔白光发射。 相似文献
182.
Renhe Chu Jichang Yan Suoyuan Lian Yuehong Wang Fucheng Yan Dawei Chen 《Solid State Communications》2004,130(12):789-792
The interesting shape (shuttle-like, sphere with needles, uniform particles) rutile titania were prepared by the hydrolysis of TiCl4 in high acidic aqueous solution in the absence or presence of PEG-1000. PEG-1000 acted as dispersant, which could control the shape and size of the precipitate of titania. As a result, shuttle-like nanocrystalline appeared and the aggregation was improved with the increase of the amount of acid and the decrease of the concentration of TiCl4 in the absence of PEG-1000. Uniform nanoparticles were obtained in the presence of PEG-1000 and the diameter of the particles decreased with increasing the amount of PEG-1000. This process simplification will lower production cost and make continuous process possible. The products were analyzed using X-ray diffractometer, transmission electron microscopy. 相似文献
183.
本文将布拉格方程推广应用到高聚物的结构研究中,得到了经不同剂量辐照的聚乙烯单晶的长周期,并辅以示差扫描量热法研究了γ-射线辐照对聚乙烯单晶结构的影响. 相似文献
184.
标题化合物二乙胺合三(5-甲基-2-苯并噻唑基)硼烷(C28H29BN4S3(Mr=527.57)的晶体属于三斜晶系,空间群为P1,晶胞参数a=0.397(8)nm,b=1.1742(6)nm,c=1.3100(2)nm,α=104.29(2)°,β=92.99(3)°,γ=98.58(5)°,V=1.3790nm3,Z=2,Dc=1.270g/cm3,μ(MoKα)=2.804cm-1.结构的偏离因子R=0.0648,Rw=0.0737.结构测定表明,甲基取代基的电子效应导致硼碳键键长的平均化,预示杂环对硼原子的π-电子反馈与胺基氮原子对硼原子的反馈有彼消此长的关系. 相似文献
185.
186.
本文第一部分主要把扭曲的方法运用到模上,从而得到扭曲模.作为特例,我们构造了H M的Smaush模和量子模.当K是有限维Hopf代数,证明K* M是一个右D(K)-Hopf模,因此得到了一个基本同构定理.第二部分主要把斜余配对双代数进行推广,得到了斜余配对Hopf模,并且给出判断斜余配对Hopf模的一个充要条件. 相似文献
187.
This paper presents a variational inequality (VI) approach to the problem of minimizing a sum of p-norms. First the original problem is reformulated as an equivalent linear VI. Then an improved extra-gradient method is presented
to solve the linear VI. Applications to the problem of p-norm Steiner Minimum Trees (SMT) shows that the proposed method is effective. Comparison with the general extra-gradient
method is also provided to show the improvements of the new method. 相似文献
188.
189.
An analytical method involving anion exchange high performance liquid chromatographic determination of vitellogenin (Vtg) in fish plasma after postcolumn fluorescence derivatization with o-phthalaldehyde (OPA) was developed. The retention time of Vtg was about 11 min. The reagent variables for derivatization were optimized. The fluorophore was excited at 335 nm and detected at 435 nm. A calibration curve was established ranging from 0.13 to 11.28 microg. The determination limit of Vtg was found to be as low as 0.13 microg. The spiked recovery was 93.6% and interassay variability was less than 4%. The method developed was used to determine Vtg in fish plasma obtained from red sea bream (Pagrosomus major), black porgy (Sparus macrocephalus) and skew band grunt (Hapalogenys nitens), without complicated sample pretreatment. The results confirmed that the method showed advantages of being simple, rapid, reproducible and sensitive. 相似文献
190.
Yan Zhao Xingbin Yang Ru Jiang Xiaoli Sun Wenmin Liu Shengyong Zhang 《Analytical sciences》2006,22(5):747-751
The investigation on capillary electrophoretic enantioseparation of six synthetic compounds containing vicinal diol groups has been undertaken to acquire the optimum conditions using native beta-cyclodextrin (beta-CD) as chiral selector and borate as a background electrolyte. The separation was carried out in an uncoated capillary (58.5 cm x 75 microm i.d., effective length 48.5 cm) and the effects of several important factors were investigated in detail. The results showed that beta-CD as a chiral selector exhibited good enantioselectivity and that the enantioseparation was greatly influenced by the structure of the diols, the borate concentration and the buffer pH. The optimum performance was obtained for the chiral vicinal diols under the conditions of 200 mM borate buffer of pH 9.8 containing 1.7% beta-CD at an applied voltage of 15 kV and a capillary temperature of 20 degrees C. Under the conditions, four diols were baseline separated with fast analysis time and the good theoretical plate numbers (above 10 x 10(4)) and favorable migration-time reproducibilities (RSDs below 3.0%) were obtained. The separation results were satisfactory. 相似文献