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131.
The open electron resonator, described by Duncan et al. [D.S. Duncan, M.A. Topinka, R.M. Westervelt, K.D. Maranowski, A.C. Gossard, Phys. Rev. B 64 (2001) 033310. [1]], is a mesoscopic device that has attracted considerable attention due to its remarkable behaviour (conductance oscillations), which has been explained by detailed theories based on the behaviour of electrons at the top of the Fermi sea. In this work, we study the resonator using the simple quantum quantum electrical circuit approach, developed recently by Li and Chen [Y.Q. Li, B. Chen, Phys. Rev. B 53 (1996) 4027. [2]]. With this approach, and considering a very simple capacitor-like model of the system, we are able to theoretically reproduce the observed conductance oscillations. A very remarkable feature of the simple theory developed here is the fact that the predictions depend mostly on very general facts, namely, the discrete nature of electric charge and quantum mechanics; other detailed features of the systems described enter as parameters of the system, such as capacities and inductances. 相似文献
132.
The interpretation of the Mössbauer spectra of iron bearing chromites is still a matter of discussion. After a preliminary characterization by X-ray diffraction, electron microscopy and chemical analysis of Cuban natural chromites, a Mössbauer study and a detailed computation analysis were carried out. The studied samples show both types of iron cations (Fe3+ and Fe2+) in the octahedral and tetradral sites of the spinel structure. No ordered distribution, or charge transfer effects were detected. All the spectra were fitted using the same model, with consistent hyperfine parameters. 相似文献
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135.
Jesús Díaz 《Tetrahedron》2010,66(40):8021-13437
Proline-catalysed aldol reactions are central to the development of organocatalysis, and have been the subjects of many studies. List’s results on the effect of fluorine substitution on proline catalysts for an intramolecular aldol condensation provide a perfect test set for computational analysis, as subtle changes in the catalyst structure lead to clear changes in the product ratios. The results show that the carbon-carbon bond forming transition states for the Hajos-Parrish-Wiechart reaction do not account for the observed selectivity in all cases. However, if an analysis of post transition-state epimerization pathways is also included, together with the effect of water, it is possible to account for all of the experimental data. 相似文献
136.
Elena Chekmeneva José Manuel Díaz‐Cruz Cristina Ariño Miquel Esteban 《Electroanalysis》2010,22(2):177-184
The complexation of the natural antioxidants α‐lipoic acid (ALA) and its reduced form dihydrolipoic acid (DHLA) with Hg2+ was investigated by a recently proposed differential pulse voltammetric (DPV) method using the rotating Au‐disk electrode. Complexation processes are proposed from the multivariate curve resolution by alternating least squares (MCR‐ALS) analysis of DPV titration data. Main complexes were both 1 : 1 Hg : ALA and Hg : DHLA, although the formation of 1 : 2 complexes can be also deduced. ALA and DHLA show different Hg2+‐binding patterns at different pH. Voltammetric findings are completed with the data obtained by electrospray ionization mass‐spectrometry (ESI‐MS), especially in negative mode. 相似文献
137.
Francisco J. Salgado Sara Vázquez Amparo Pérez-Díaz Pilar Arias 《Analytica chimica acta》2010,658(1):18-3648
Serum is a typical sample for non-invasive studies in clinical research. Its proteome characterization is challenging, since requires extensive protein depletion. Methods used nowadays for removal of high-abundance proteins are expensive or show quite often a low loading capacity, which has strong repercussions on the number of samples and replicates per analysis.In order to deplete immunoglobulins (Igs) and albumin (HSA) from 1 mL serum samples, we have developed a protocol based on a combination of thiophilic chromatography, not previously used in clinical proteomics, and a HSA-specific resin. Ig/HSA-depleted samples, immunoglobulinome and albuminone were analyzed by 2-DE. Thiophilic chromatography, coupled with HSA-depletion, allows a good 2-DE resolution as well as the visualization of new spots. Moreover, it yields enough protein to evaluate technical variability and facilitate subsequent protein identification. To validate the protocol, we carried out a preliminary comparative study between triplicate Igs/HSA-depleted serum samples from healthy control individuals and recently diagnosed/untreated rheumatoid arthritis (RA) patients. RA patients showed several acute phase proteins, as well as additional serum proteins, differentially and significantly regulated.Therefore, thiophilic chromatography can be used as an efficient and economical method in 2-DE to deplete immunoglobulins from large human serum samples before a more extensive fractioning. 相似文献
138.
Yurina Díaz Jairo Quiroga Justo Cobo Christopher Glidewell 《Acta Crystallographica. Section C, Structural Chemistry》2010,66(6):o305-o309
The molecules of 8‐methyl‐7,10‐diphenyl‐5H‐benzo[h]pyrazolo[3,4‐b]quinoline‐5,6(10H)‐dione, C27H17N3O2, (I), are weakly linked into chains by a single C—H...O hydrogen bond, and these chains are linked into sheets by a π–π stacking interaction involving pyridyl and aryl rings. In 8‐methyl‐7‐(4‐methylphenyl)‐10‐phenyl‐5H‐benzo[h]pyrazolo[3,4‐b]quinoline‐5,6(10H)‐dione, C28H19N3O2, (II), the molecules are linked into a three‐dimensional framework structure by a combination of C—H...N, C—H...O and C—H...π(arene) hydrogen bonds, together with a π–π stacking interaction analogous to that in (I). 相似文献
139.
We study slow-light performance of molecular aggregates arranged in nanofilms by means of coherent population oscillations. The molecular cooperative behavior inside the aggregate enhances the delay of input signals in the gigahertz range in comparison with other coherent population oscillation-based devices. Moreover, the problem of residual absorption present in coherent population oscillation processes is removed. We also propose an optical switch between different delays by exploiting the optical bistability of these aggregates. 相似文献
140.