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11.
The reaction of enynals 1, including o-alkynylbenzaldehydes, and carbonyl compounds 2 in the presence of a catalytic amount of AuBr3 in 1,4-dioxane at 100 degrees C gave the functionalized aromatic compounds 3 in high yields. The AuBr3-catalyzed formal [4 + 2] benzannulation proceeds most probably through the coordination of the triple bond of 1 to AuBr3, the formation of a pyrylium auric ate complex via the nucleophilic addition of the carbonyl oxygen atom, the reverse electron demand-type Diels-Alder addition of the enols, derived from 2, to the auric ate complex, and subsequent dehydration and bond rearrangement. Similarly, the AuBr3-catalyzed reactions of 1 with acetal compounds afforded the corresponding aromatic compounds in good yields. 相似文献
12.
If u is a superharmonic function on R2, then [formula] for all (x, y) R2. This follows from the fact that a line segmentin R2 is non-thin at each of its constituent points. (See Doob[1, 1.XI] or Helms [7, Chapter 10] for an account of thin setsand the fine topology.) The situation is different in higherdimensions. For example, if u is the Newtonian potential onR3 defined by [formula] then [formula] Corollary 2 below will show that, nevertheless, for nearly everyvertical line L, the value of a superharmonic function at anypoint X of L is determined by its lower limit along L at X. Throughout this paper, we let n 3. A typical point of Rn willbe denoted by X or (X', x), where X'Rn1 and xR. Givenany function f:Rn [,+] and any point X, we define thevertical cluster set of f at X by [formula] and the fine cluster set of f at X by [formula] 1991 Mathematics Subject Classification 31B05. 相似文献
13.
Hiroaki Aikawa 《Proceedings of the American Mathematical Society》2000,128(1):195-201
The integrability of positive superharmonic functions on a bounded fat John domain is established. No exterior conditions are assumed. For a general bounded John domain the -integrability is proved with the estimate of in terms of the John constant.
14.
Hiroaki Aikawa Tero Kilpeläinen Nageswari Shanmugalingam Xiao Zhong 《Potential Analysis》2007,26(3):281-301
We establish a scale-invariant version of the boundary Harnack principle for p-harmonic functions in Euclidean C
1,1-domains and obtain estimates for the decay rates of positive p-harmonic functions vanishing on a segment of the boundary in terms of the distance to the boundary. We use these estimates
to study the behavior of conformal Martin kernel functions and positive p-superharmonic functions near the boundary of the domain.
H. A. was partially supported by Grant-in-Aid for (B) (2) (No. 15340046) Japan Society for the Promotion of Science. N. S.
was partially supported by NSF grant DMS-0355027. X. Z. was partially supported by the Taft foundation. 相似文献
15.
Hydrogen Production from a Methanol–Water Solution Catalyzed by an Anionic Iridium Complex Bearing a Functional Bipyridonate Ligand under Weakly Basic Conditions
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Prof. Dr. Ken‐ichi Fujita Dr. Ryoko Kawahara Takuya Aikawa Prof. Dr. Ryohei Yamaguchi 《Angewandte Chemie (International ed. in English)》2015,54(31):9057-9060
An efficient catalytic system for the production of hydrogen from a methanol–water solution has been developed using a new anionic iridium complex bearing a functional bipyridonate ligand as a catalyst. This system can be operated under mild conditions [weakly basic solution (0.046 mol L?1 NaOH) below 100 °C] without the use of an additional organic solvent. Long‐term continuous hydrogen production from a methanol–water solution catalyzed by the anionic iridium complex was also achieved. 相似文献
16.
Hiroshi Kimura Koichiro Aikawa Yuichi Masubuchi Jun-ichi Takimoto K. Koyama Keiji Minagawa 《Rheologica Acta》1998,37(1):54-60
The mechanism of the electrorheological (ER) effect in two types of liquid crystalline polymer (LCP)/dimethylsiloxane (DMS)
blends was investigated by rheological measurements and by structure observation under electric field and shear flow. The
results show that the phase structures of these immiscible blends can be categorized into slipping (low viscosity) and non-slipping
(high viscosity) states. In the non-slipping state, higher viscosity LCP domains connect the electrodes. In the slipping state,
on the other hand, LCP domains do not connect the electrodes and the shear is mainly confined in the lower viscosity DMS domains.
The ER effect (electrically induced viscosity increase) originates from the electrically induced slipping to non-slipping
transition. In one of the blends, the ER effect occurs only at high shear rate, since this blend is in non-slipping state
even under no field if the shear rate is low.
Received: 29 April 1997 Accepted: 3 November 1997 相似文献
17.
Koji YamamotoHiroki Sugiura Ryo AmemiyaHaruo Aikawa Zengjian AnMasahiko Yamaguchi Masashi Mizukami Kazue Kurihara 《Tetrahedron》2011,67(33):5972-5978
Optically active ethynylhelicene pentamers and hexamers linked by disulfide bonds were synthesized. They formed self-assembled monolayers (SAMs) with double helix structure on gold surfaces, which were analyzed by infrared reflection-absorption spectroscopy (IR-RAS), quartz crystal microbalance (QCM), surface plasmon resonance (SPR), and circular dichroism (CD). Double helix SAMs could be formed on gold surfaces either from double helices or random coils in solution. The double helices on the surface were more stable than in solution. This result suggested the presence of strong intercomplex interactions between double helix complexes on the surface. 相似文献
18.
Inoue K Kitahara K Aikawa Y Arai S Masuda-Hanada T 《Molecules (Basel, Switzerland)》2011,16(7):5905-5915
To investigate the separations of all aldopentoses (ribose, arabinose, xylose and lyxose) and aldohexoses (glucose, galactose, allose, altrose, mannose, gulose, idose and talose) on the D? stationary phase prepared by the reaction of chloromethylated styrene-divinylbenzene copolymer and N,N,N',N'-tetramethyl-1,6-diaminohexane, we examined the effect of varying the concentration of the NaOH eluent on the elution orders. Separations of these aldoses were achieved using a 20 mM NaOH eluent. The elution behaviors of the aldoses were probably due to not only the individual pK(a) values, but also the chemical structures of the cyclic aldoses. 相似文献
19.
Shigeki Habaue Ryo Muraoka Akiko Aikawa Soichiro Murakami Hideyuki Higashimura 《Journal of polymer science. Part A, Polymer chemistry》2005,43(8):1635-1640
The oxidative coupling polymerization of 2,3‐dihydroxynaphthalene with the novel dinuclear‐type copper(II) catalysts successfully produced poly(2,3‐dihydroxy‐1,4‐naphthylene). For example, the MeOH‐insoluble polymer with a number average molecular weight of 4.4 × 103 from the polymerization using the complex of CuCl2 and N,N′‐bis(2‐morpholinoethyl)‐p‐xylylenediamine ( p ‐ 1 ) at room temperature under an O2 atmosphere followed by acetylation of the hydroxyl groups was obtained in 63% yield. The structures of the tetraamine ligands and the counter anion of the copper(II) salts significantly influenced the catalyst activity. The polymerization of 2,2′‐dimethoxy‐1,1′‐binaphthalene‐3,3′‐diol with the 2CuCl2‐ p ‐ 1 catalyst, however, resulted in a lower yield. © 2005 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 43: 1635–1640, 2005 相似文献
20.
S. Katsumoto K. Kobayashi H. Aikawa A. Sano Y. Iye 《Superlattices and Microstructures》2003,34(3-6):151
We investigate coherent transport through hybrid systems of quantum dots and Aharonov–Bohm (AB) rings. Strong coherence over the entire system leads to the Fano effect, which originates from the interference and the phase shift caused by the discrete states in the dots. The high controllability of the system parameters reveals that the Fano effect in mesoscopic transport can be a powerful tool for detecting the phase shift of electrons. We apply it to detect electrostatic phase modulation and the phase shift in a quantum wire with a side-coupled dot. Finally, we provide an experimental answer to the problem of “neighboring in-phase Coulomb peaks”. 相似文献