用13CNMR研究聚甲基丙烯酸锡酯的立构序列分布

本文测定了自由基型溶液聚合的聚甲基丙烯酸三甲基锡酯(PTMTM),聚甲基丙烯酸三乙基锡酯(PTETM)和聚甲基丙烯酸三丁基锡酯(PTBTM)的¹³C-NMR谱,对其C-2谱扩展分峰,计算立构序列,从定量数据表明,聚合物样品的空间立构富于或稍富于间规立构,随取代基的体积增大而趋于无规分布,作者认为受空间位阻效应和分子内或分子间形成配位键的影响。     

Augmented Spinor Space

In this paper, based on the Pauli matrices, a notion of augmented spinor space is introduced, and a uniqueness of such augmented spinor space of rank n is proved. It may be expected that this new notion of spaces can be used in mathematical physics and geometry.     

闪烁体荧光传输特性对ETOF探测器性能的影响

为了对BESⅢ端盖飞行时间探测器(ETOF)的测试结果给出合理的解释, 采用Monte Carlo模拟软件包Geant4, 对该探测器测量高能带电粒子的性能进行模拟研究. 详细探讨了当粒子击中ETOF模块不同位置时, 其闪烁体荧光传输特性与探测器模块输出信号之间的关联, 以及PMT输出信号甄别阈值的选取对闪烁探测器本征时间分辨的影响, 并寻找可能的改善时间分辨的方法. 为进一步提高ETOF的性能提供参考.     

Pattern时延差编码四信道水声通信技术研究

本文所研究的是基于Pattern时延差编码（PDS）体制下的水声通信技术.PDS水声编码体制利用Pattern码片出现在码元窗的时延差值进行时延编码,通过码元分割,有效的降低了水声信道的多途干扰;通过频率分割划分四个通信信道,增加通信速率至1000bit/s.在接收端利用带通滤波器来实现通信信道分割,每个信道再应用拷贝相关器实现码元分割并估计出时延差值,完成译码.仿真实验表明,该系统适合于大量不同水声信道高可靠性工作,为水声通信网络化打下坚实基础.     

Compact Single-Stage Femtosecond Multipass Ti：Sapphire Amplifier at 1 kHz with High Beam Quality

A compact femtosecond Ti：sapphire amplifier system is reported using single-stage multipass configuration with high beam quality. A high dispersion glass stretcher and a pair of double prisms for compression are introduced based on broadband femtosecond seed pulses. The non-grating-based pulse stretcher and compressor are advantageous to increase high beam quality and to reduce the high-order dispersion. A Gaussian filter is used to reduce the gain narrowing effect in amplification. The compact femtosecond Ti：sapphire nine-pass amplifier delivers pulses with a duration of 26 fs and an energy of 800μJ at 7mJ pumping pulses energy at I kHz. The 1-kHz femtosecond amplifier with high beam quality and high stability is very suitable for ultrafast physics research applications, such as attosecond science, ultra-precision micromachining, and THz wave generation.     

Generalized Born scattering in anisotropic media

The Born scattering approximation has been widely used in seismology to study scattered waves, and to linearize the propagation problem for inversion. The standard Born theory requires the model be separated into a smooth, reference model and a perturbation. Scattering occurs from the pertubation. In the distorted Born approximation, when the reference model is inhomogeneous, the reference Green's functions are normally not known exactly, but the error in these Green's functions is rarely quantified. In this paper, we generalize Born scattering theory to include the errors in the Green's functions explicitly, and obtain scattering integrals from these errors. For forward modelling, there is no need to separate the model into a reference and perturbation part - approximate Green's functions in the true model can be used to calculate the scattered signals.

The theory is developed for inhomogeneous, anisotropic media. Asymptotic ray theory results are suitable approximate Green's functions for the generalized Born scattering theory. The error terms are simple, easily calculated and included in the scattering integrals. Various applications of generalized Born scattering theory have already appeared in the literature, e.g. quasi-shear ray coupling, and this paper is restricted to an improved and more complete theoretical development. Further applications will appear elsewhere.     

Use of the Apparent Content Curves for the spectrophotometric identification of substances: identification of amphetamines

The possibility of identification of substances which have similar spectral behaviour by means of Apparent Content Curves has been studied. This study is carried out with absorption, excitation and emission spectra of several amphetamines of widespread pharmaceutical use. Results obtained show that amphetamine, phenylpropanolamine, pseudoephedrine, phenylephrine, epinephrine, dopamine and methoxyamphetamine can be identified with a probability of >95%.     

Determination of glycols by HPLC with refractive index detection

A simple and fast HPLC method for the determination of glycols is described. It is characterized by a reversed-phase separation using water as eluent and a refractive index detection. The method was applied to investigate the biodegradation of glycols in a laboratory activated sludge plant and to determine the content of glycols or alcohols in detergents. The detection limit is 4 mg/l ethylene glycol or propylene glycol in an aqueous sample.     

Raman spectroscopy of carbon fibres

Investigations of coated carbon fibres are reported using Raman spectroscopy. Relationships between different process parameters (for example precursor concentration, reactor temperature and various precursors) and the resulting types of carbon fibres are discussed.     

Comparison of four quantification methods for the determination of PCB in transformer oils

The analysis of PCB in transformer oils has been achieved with three HRGC/ECD based methods, proposed by the International Electrotechnical Commission (IEC/TC 10), by the Comité Européen de Normalisation (CEN/TC 19/WG 22) and by the Deutsches Institut für Normung (DIN 51 527). The same clean-up, described in the CEN/TC 19/WG 22, has been used for all the samples, allowing a comparison of the quantification procedure only. The total chlorine content has also been determined with X-ray fluorescence. These different methods of quantification are compared and their application for legislative purposes is discussed.Dedicated to Professor Dr Dieter Klockow on the occasion of his 60th birthday