全文获取类型
收费全文 | 19649篇 |
免费 | 1372篇 |
国内免费 | 2466篇 |
专业分类
化学 | 15409篇 |
晶体学 | 274篇 |
力学 | 497篇 |
综合类 | 169篇 |
数学 | 2658篇 |
物理学 | 4480篇 |
出版年
2023年 | 146篇 |
2022年 | 452篇 |
2021年 | 496篇 |
2020年 | 371篇 |
2019年 | 411篇 |
2018年 | 346篇 |
2017年 | 406篇 |
2016年 | 696篇 |
2015年 | 616篇 |
2014年 | 729篇 |
2013年 | 1434篇 |
2012年 | 1552篇 |
2011年 | 1663篇 |
2010年 | 1020篇 |
2009年 | 1282篇 |
2008年 | 1285篇 |
2007年 | 1237篇 |
2006年 | 1107篇 |
2005年 | 1144篇 |
2004年 | 1292篇 |
2003年 | 941篇 |
2002年 | 861篇 |
2001年 | 505篇 |
2000年 | 448篇 |
1999年 | 314篇 |
1998年 | 253篇 |
1997年 | 226篇 |
1996年 | 225篇 |
1995年 | 188篇 |
1994年 | 145篇 |
1993年 | 181篇 |
1992年 | 156篇 |
1991年 | 106篇 |
1990年 | 118篇 |
1989年 | 100篇 |
1988年 | 96篇 |
1987年 | 74篇 |
1986年 | 84篇 |
1985年 | 98篇 |
1984年 | 102篇 |
1983年 | 74篇 |
1982年 | 62篇 |
1981年 | 62篇 |
1980年 | 55篇 |
1979年 | 35篇 |
1978年 | 28篇 |
1977年 | 35篇 |
1976年 | 27篇 |
1975年 | 25篇 |
1974年 | 28篇 |
排序方式: 共有10000条查询结果,搜索用时 15 毫秒
21.
D. Barrios Rolanía G. Lpez Lagomasino E. B. Saff 《Journal of Approximation Theory》2003,124(2):263-281
Using a convergence theorem for Fourier–Padé approximants constructed from orthogonal polynomials on the unit circle, we prove an analogue of Hadamard's theorem for determining the radius of m-meromorphy of a function analytic on the unit disk and apply this to the location of poles of the reciprocal of Szeg
functions. 相似文献
22.
Parameters of Gaussian multivariate models are often estimated using the maximum likelihood approach. In spite of its merits, this methodology is not practical when the sample size is very large, as, for example, in the case of massive georeferenced data sets. In this paper, we study the asymptotic properties of the estimators that minimize three alternatives to the likelihood function, designed to increase the computational efficiency. This is achieved by applying the information sandwich technique to expansions of the pseudo-likelihood functions as quadratic forms of independent normal random variables. Theoretical calculations are given for a first-order autoregressive time series and then extended to a two-dimensional autoregressive process on a lattice. We compare the efficiency of the three estimators to that of the maximum likelihood estimator as well as among themselves, using numerical calculations of the theoretical results and simulations. 相似文献
23.
Pedro lvarez‐Boo Jos Sergio Casas Alfonso Castieiras María Delfina Couce Eduardo Freijanes Eva Novoa Jos Sordo 《应用有机金属化学》2003,17(9):725-729
Reaction of dichloro‐ and dibromodimethyltin(IV) with 2‐(pyrazol‐1‐ylmethyl)pyridine (PMP) afforded [SnMe2Cl2(PMP)] and [SnMe2Br2(PMP)] respectively. The new complexes were characterized by elemental analysis and mass spectrometry and by IR, Raman and NMR (1H, 13C) spectroscopies. Structural studies by X‐ray diffraction techniques show that the compounds consist of discrete units with the tin atom octahedrally coordinated to the carbon atoms of the two methyl groups in a trans disposition (Sn? C = 2.097(5), 2.120(5) Å and 2.110(6), 2.121(6) Å in the chloro and in the bromo compounds respectively), two cis halogen atoms (Sn? Cl = 2.4908(16), 2.5447(17) Å; Sn? Br = 2.6875(11), 2.7464(9) Å) and the two donor atoms of the ligand (Sn? N = 2.407(4), 2.471(4) Å and 2.360(5), 2.455(5) Å). In both cases, the Sn? N(pyridine) bond length is markedly longer than the Sn? N(pyrazole) distance. Copyright © 2003 John Wiley & Sons, Ltd. 相似文献
24.
CHAO Shu-Jun QIU Zao-Zao HUI Xin-Ping XU Peng-Fei ZHENG Rong-Liang 《有机化学》2003,23(Z1):420-421
Since the discovery of losartan[1](DUP 753), the leading non-peptide AT1 antagonist, several highly potent AT1 selective antagonists bearing heterocycles have been reported. [2] The tetrazole group is a common acidic functionpresent in many these antagonists. 相似文献
25.
26.
It is shown that the presence of mixed-culture growth in batch fermentation processes can be very accurately inferred from total biomass data by means of the wavelet analysis for singularity detection. This is accomplished by considering simple phenomenological models for the mixed growth and the more complicated case of mixed growth on a mixture of substrates. The main quantity provided by the wavelet analysis is the Hölder exponent of the singularity that we determine for our illustrative examples. The numerical results point to the possibility that Hölder exponents can be used to characterize the nature of the mixed-culture growth in batch fermentation processes with potential industrial applications. Moreover, the analysis of the same data affected by the common additive Gaussian noise still lead to the wavelet detection of the singularities although the Hölder exponent is no longer a useful parameter. 相似文献
27.
We continue the studies on the so–called genuine Bernstein–Durrmeyer operators U
n
by establishing a recurrence formula for the moments and by investigating the semigroup T(t) approximated by U
n
. Moreover, for sufficiently smooth functions the degree of this convergence is estimated. We also determine the eigenstructure
of U
n
, compute the moments of T(t) and establish asymptotic formulas.
Received: January 26, 2007. 相似文献
28.
M.A. Domínguez-Crespo L. Díaz-García A.M. Torres-Huerta 《Applied Surface Science》2006,253(3):1205-1214
Four NiMo catalyst supported on Al2O3 with different textural properties have been studied in the hydrodesulfurization (HDS), hydrodenitrogenation (HDN) and hydrodearomatization (HDA) of a Mexican straight run gasoil (SRGO). All reactions were carried out at three different temperatures 613, 633, and 653 K. Alumina supports were analysed by pyridine FTIR-TPD and nitrogen physisorption in order to determine their surface acidity and textural properties, respectively. TPR studies of the NiMo catalysts were analysed to correlate their hydrogenating properties. Metallic particles were characterized (after sulfidation) using transmission electron microscopy (TEM). Catalytic activities are discussed in relation to the physicochemical properties of NiMo catalysts. The importance of textural properties on coke deposition has been emphasized. The results of catalytic activity of these materials varied depending on dispersed MoS particles and pore distribution in final catalysts. The optimum pore diameter was found around 80 Å for HDS and HDN. 相似文献
29.
F. García 《Topology and its Applications》2006,153(15):2886-2892
In this paper we characterize the class of uniform Eberlein compact spaces through a network condition and also in terms of covering properties for the square of the space. 相似文献
30.
Parking Capacity and Pricing in Park'n Ride Trips: A Continuous Equilibrium Network Design Problem 总被引:2,自引:0,他引:2
In this paper we consider the problem of designing parking facilities for park'n ride trips. We present a new continuous equilibrium network design problem to decide the capacity and fare of these parking lots at a tactical level. We assume that the parking facilities have already been located and other topological decisions have already been taken.The modeling approach proposed is mathematical programming with equilibrium constraints. In the outer optimization problem, a central Authority evaluates the performance of the transport network for each network design decision. In the inner problem a multimodal traffic assignment with combined modes, formulated as a variational inequality problem, generates the share demand for modes of transportation, and for parking facilities as a function of the design variables of the parking lots. The objective is to make optimal parking investment and pricing decisions in order to minimize the total travel cost in a subnetwork of the multimodal transportation system.We present a new development in model formulation based on the use of generalized parking link cost as a design variable.The bilevel model is solved by a simulated annealing algorithm applied to the continuous and non-negative design decision variables. Numerical tests are reported in order to illustrate the use of the model, and the ability of the approach to solve applications of moderate size. 相似文献