Synthesis and Properties of Functionally Substituted Ammonium Salts of 3-<Emphasis Type="Italic">tert</Emphasis>-Butylperoxy-3-methylbutanoic Acid

An effective synthesis of novel functionally substituted nitrogen- and phosphorus-containing salts of 3-tert-butylperoxy-3-methylbutanoic acid, potential sources of free radicals, have been developed.     

Effect of elastic stress on the magnetostriction of ferromagnets

An experimental study has been made of the effect of elastic tensile stresses on the magnetostriction curves of polycrystalline nickel, transformer steel, an equiatomic cobalt-platinum alloy, and an Invar iron alloy with 30–40 wt. % nickel. The sign of the magnetostriction changes during the rotation process under the effect of sufficiently high stress. The effect is explained on the basis of the concept of a magnetic rotation texture, developed earlier by one of the authors. A change in the magnetostrictive susceptibility for the paraprocess of the Invar alloy is found to be caused by the stress; the signs of the magnetostrictive constants are determined for the hardened cobalt-platinum alloy.Translated from Izvestiya Vysshikh Uchebnykh Zavedenii, Fizika, Vol. 12, No. 2, pp. 89–94, February, 1969.     

A Theoretical Description of the Photodissociation Spectrum of the H2O...HCl Complex

The effect of association of the water molecule and hydrogen chloride on the UV absorption bands is studied. Complete ab initio calculations for the H₂O...HCl complex in the S ₁ and S ₂ states are performed. A mathematical model using Airy functions is developed to describe the absorption cross-sections in a continuous spectrum. The form of the potential is determined by accurate ab initio calculations. The cross-sections of potential surfaces of lower electron states are found from ab initio calculations using the Hartree–Fock, configurational interaction, and multi-configurational interaction techniques. A complete vibrational analysis and an analysis of the change in the electron density for the S ₀ S ₁ transition on moving along the reaction coordinate allow a conclusion to be made on the feasibility of applying the model proposed to the H₂O...HCl complex. The results obtained in the framework of the model using Airy functions show reasonably good agreement with the experiment. For the H₂O...HCl heterodimer, the absorption band has the same structureless form as for the water monomer. The absorption band (peaking at 161 nm) is seen to shift towards short wavelengths as compared with the water monomer H₂O ( 167 nm).     

Possible application of a volume avalanche discharge initiated by an electron beam for designing a krypton dimer laser

The emissive and amplifying properties of volume nanosecond discharge plasma formed at high pressures in krypton have been investigated theoretically and experimentally. It is theoretically shown that lasing can be obtained in this type of discharge at krypton pressures exceeding 6–7 atm. In the discharge gap with a cathode of small curvature radius, volume discharge without preliminary ionization is obtained at a high pressure and intense krypton dimer emission that peaks at a wavelength of 146 nm is detected. It is shown that, upon excitation by a volume avalanche discharge initiated by an electron beam, no less than 90% of the energy in the range 120–540 nm is emitted by krypton dimers. At a krypton pressure of 1.5 atm, an energy of ～30 mJ of spontaneous emission into the total solid angle and a radiation pulse width at half maximum of ～240 ns are obtained.     

Synthesis and structure of 9-hydroxy-1,2-dicarba-closo-dodecaborane(11)

The oxidation of 1,2-C₂B₁₀H₁₂ (1) with 100% nitric acid was studied in two solvents (CH₂C1₂ and CCl₄). Under the action of superacid (CF3SO3H), the compound 9-HO-1,2-C₂B₁₀H₁₁ (2) gives the onium cation 9-H₂O⁺-1,2-C₂B₁₀H₁₁ involved in the salt [9-H₂O⁺-1,2-C₂B₁₀H_n]-CF₃SO₃^?, as demonstrated by ^uB NMR spectroscopy. The experimental and simulated ^uB NMR spectra of the cation 9-H₂O⁺-1,2-C₂B₁₀H₁₁ are in satisfactory agreement with each other. In the presence of a base, compound 2 is transferred from an ethereal solution to an aqueous alkaline solution giving the anion 9-O^?- 1,2-C₂B₁₀H₁₁. The structure of compound 2 was confirmed by ¹H, ¹¹B, ¹¹B¹H, ¹¹B-¹¹B COSY NMR spectroscopy, IR spectroscopy, and gas chromatography mass spectrometry and was additionally established by X-ray diffraction.

     

Kinetics and Mechanism of the Kabachnic-Fields Reaction

Abstract

The Kabachnic-Fields reaction is one of the most important methods of synthesis of functionally substituted derivatives of tetracoordinated phosphorus with P-C bond. At the same time mechanism of this important and interesting reaction practically has not been investigated.