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The creep processes of hereditary media on a small initial interval are described, using as influence functions the resolvent functions for the generators of the Dirac function, which are employed as relaxation kernels. Equations are constructed for determining the instantaneous modulus and the parameters of these functions from experimental stress-strain diagrams obtained at three different constant loading rates.Moscow Institute of Electronic Machine Building. Translated from Mekhanika Polimerov, No. 5, pp. 945–950, September–October, 1970. 相似文献
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Crystals of a new rare-earth chain diborate TmH[B2O5], space group C2/c, are obtained under hydrothermal conditions. The structure is determined without preliminary knowledge of the chemical formula. It is close to that of the GdH[B2O5] diborate studied earlier, but has a different orientation of the monoclinicity axis. In both structures the arrangement of atoms follows the pattern of the orthorhombic pseudosupergroup Cmca, which is most distinctly violated by the displacements of the rare-earth atoms. Their common anionic chain radical consists of diborate groups, namely, BO3 triangles and BO4 tetrahedra, 2[1T + 1Δ]. It is shown that the existence of two varieties that are based on the hypothetical orthorhombic prototype is determined by the pseudosymmetry and the difference between the ionic radii of the elements located at the middle and the end of the rare-earth series. The twinning and poor quality of the crystals are related to the effect of the m pseudoplane of the supergroup and cleavage. The structures of natural megaborates that contain diborate chains in complex boron-oxygen radicals are discussed. 相似文献
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L. V. Zorina S. S. Khasanov R. P. Shibaeva I. Yu. Shevyakova A. I. Kotov É. B. Yagubskii 《Crystallography Reports》2004,49(6):1010-1017
A new radical cation salt based on 4,5-(1,4-dioxanediyl-2,3-dithio)-4′,5′-ethylenedithiotetrathiafulvalene (DOET) with the photochromic anion [Fe(CN)5NO]2?, namely, (DOET)4[Fe(CN)5 NO]1.25(C6H5Cl)0.75, is synthesized. Single crystals of this salt are studied using X-ray diffraction [a = 10.398(2) Å, b = 11.168(2) Å, c = 18.499(4) Å, α = 103.14(3)°, β = 92.80(3)°, γ = 106.02(3)°, V = 1996.3(7) Å3, space group \(P\bar 1\), and Z = 1]. In the structure, radical cation layers alternate with anion layers along the c axis. The centrosymmetric dimers are formed by DOET radical cations in the donor layer with packing of the β type. Like the vast majority of DOET-based salts, the new salt possesses semiconductor properties. 相似文献