岩石节理粗糙面的分形几何特性与剪切强度关系的实验研究

自然形成的岩石节理面的表面形状具有分形特性，利用分形理论来描述岩石节理的粗糙特性，并确立与岩石节理面的剪切力学特性间的关系对于指导岩体工程设计，和管理具有重要一研究利用开发设计的三维激光测距仪在精确测定岩石节理面的表面形状４ 基础上，依据变量图法建立了 岩石节理面的     

压电介质二维边界积分方程中的基本解

由于压电介质的变形－电场耦合效应及压电响应的各向异性，使解析求解压电介质问题的工作变量十分复杂，若采用边界元数值方法求解，必须具备积分方程中的基本解，本文根据电磁场方程及连续介质力学的耦合性质论层出了二维无限域中分别在单位力及单位电荷载作用下的位移场，电势场、应力场和电位移场的解，从而确立了边界积分方程中所必需的八个基本解。     

近场波动模拟的一种应力人工边界

采用平面波和远场散射波混合透射，引入无限介质线弹性本构关系建立了一种应力人工 边界条件. 其优点在于边界结点反应与内部有限元结点反应采用相同的积分格式计算，有限 元积分方法稳定时不存在人工边界失稳问题. 数值算例表明：边界精度高于现有黏性边 界、黏弹性人工边界，以及一、二阶透射人工边界.     

快速求解叶栅流动的边界元方法

本文利用边界元方法，通过ｋｒｉｃｈｈｏｆｆ变换将描述叶栅流动的控制方程转换成线性方程。并将广义ｋ－Ｊ条件与边界积分方程联立求解，避免了非线性项和叶片出气角的迭代计算。完成了一种快速求解任意迥转面叶栅流场的计算程序，实用表明与其它数值方法及实验结果符合较好，具有快带、简明、实用的特点。     

静载荷作用下柔韧圆板的大幅度振动

本文首先给出了均布载荷作用下柔韧圆板的大幅度振动方程，按文中给出的时间模态假设导了该问题的非线性耦合的代数和微分特征方程组，利用修正迭代法求出了该方程组的近似解析解，得到了柔韧圆振动的幅频－载荷特征关系，讨论了静载荷对其振动性态的影响。     

Flow through isotropic granular porous media

A generalization of the Navier-Stokes equation is developed to include laminar flow through a rigid isotropic granular porous medium of spatially varying permeability. The model is based on a theory of interspersed continua and the mean geometrical properties of an idealized granular porous microstructure. The derived momentum transport equations are applicable to granular porous media over the entire porosity range from zero through unity. No restriction with respect to flow velocity is imposed, except for the assumption of laminar flow within the pores. The results provide useful and versatile equations and substantiate many of the empirical equations currently in use. One of the major advantages of the generalized momentum equation is its adaptability to numerical simulation.     

Isotope‐Filtered 4D NMR Spectroscopy for Structure Determination of Humic Substances

Humic substances, the main component of soil organic matter, could form an integral part of green and sustainable solutions to the soil fertility problem. However, their global‐scale application is hindered from both scientific and regulatory perspectives by the lack of understanding of the molecular make‐up of these chromatographically inseparable mixtures containing thousands of molecules. Here we show how multidimensional NMR spectroscopy of isotopically tagged molecules enables structure characterization of humic compounds. We illustrate this approach by identifying major substitution patterns of phenolic aromatic moieties of a peat soil fulvic acid, an operational fraction of humic substances. Our methodology represents a paradigm shift in the use of NMR active tags in structure determination of small molecules in complex mixtures. Unlike previous tagging methodologies that focused on the signals of the tags, we utilize tags to directly probe the identity of the molecules they are attached to.     

Enantioselective Synthesis of Quaternary Carbon Stereocenters: Addition of 3‐Substituted Oxindoles to Vinyl Sulfone Catalyzed by Pentanidiums

A pentanidium‐catalyzed highly enantioselective conjugate addition of 3‐alkyloxindoles to phenyl vinyl sulfone has been demonstrated. This approach allows the construction of 3,3‐dialkyl‐substituted oxindole frameworks with high yield and excellent enantioselectivity (up to 99 %) under simple phase‐transfer conditions. A variety of oxindoles bearing all‐carbon quaternary stereogenic centers were obtained in the presence of 0.25 mol % pentanidium. Meanwhile, practicality was illustrated by a gram‐scale asymmetric synthesis of two 3,3‐dialkyl‐substituted oxindoles. The resulting adduct can be smoothly transformed to the natural product analogue in a short synthetic route.     

A Two‐Coordinate Cobalt(II) Imido Complex with NHC Ligation: Synthesis,Structure, and Reactivity

The synthesis, structural characterization, and reactivity of the first two‐coordinate cobalt complex featuring a metal–element multiple bond [(IPr)Co(NDmp)] ( 4 ; IPr=1,3‐bis(2′,6′‐diisopropylphenyl)imidazole‐2‐ylidene; Dmp=2,6‐dimesitylphenyl) is reported. Complex 4 was prepared from the reaction of [(IPr)Co(η²‐vtms)₂] (vtms=vinyltrimethylsilane) with DmpN₃. An X‐ray diffraction study revealed its linear C? Co? N core and a short Co? N distance (1.691(6) Å). Spectroscopic characterization and calculation studies indicated the high‐spin nature of 4 and the multiple‐bond character of the Co? N bond. Complex 4 effected group‐transfer reactions to CO and ethylene to form isocyanide and imine, respectively. It also facilitated E? H (E=C, Si) σ‐bond activation of terminal alkyne and hydrosilanes to produce the corresponding cobalt(II) alkynyl and cobalt(II) hydride complexes as 1,2‐addition products.