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排序方式: 共有279条查询结果,搜索用时 15 毫秒
271.
The large-amplitude motions of a one degree-of-freedom model of orthogonal cutting are analysed. The model takes the form of a delay differential equation which is non-smooth at the instant at which the tool loses contact with the workpiece, and which is coupled to an algebraic equation that stores the profile of the cut surface whilst the tool is not in contact. This system is approximated by a smooth delay differential equation without algebraic effects which is analysed with numerical continuation software. The grazing bifurcation that defines the onset of chattering motion is thus analysed as are secondary (period-doubling, etc.) bifurcations of chattering orbits, and convergence of the bifurcation diagrams is established in the vanishing limit of the smoothing parameters. The bifurcation diagrams of the smoothed system are then compared with initial value simulations of the full non-smooth delay differential algebraic equation. These simulations mostly validate the smoothing technique and show in detail how chaotic chattering dynamics emerge from the non-smooth bifurcations of periodic orbits. 相似文献
272.
A Wittig reaction employing the ylide generated from isopropyl triphenylphosphonium bromide with THP-protected aldol intermediate 8 constitutes the key step in a regiospecific synthesis of olefin 1 in the total synthesis of zoapatanol analogue 2a. 相似文献
273.
Gem-substituted aryl, aralkenyl and 2-furyl ethynyl vinyi carbinols as well as 2,5-disubstituted furans can be obtained by a novel addition and rearrangement reaction of acetylene with the appropriate aldehydes. 相似文献
274.
Zsuzsanna Szabo Eva Juhasz Andrew V. Schally Balazs Dezso Sandor Huga Zoltan Hernadi Gabor Halmos Csongor Kiss 《Molecules (Basel, Switzerland)》2022,27(9)
Antagonists of growth hormone-releasing hormone (GHRH) inhibit the growth of various tumors, including endometrial carcinomas (EC). However, tumoral receptors that mediate the antiproliferative effects of GHRH antagonists in human ECs have not been fully characterized. In this study, we investigated the expression of mRNA for GHRH and splice variants (SVs) of GHRH receptors (GHRH-R) in 39 human ECs and in 7 normal endometrial tissue samples using RT-PCR. Primers designed for the PCR amplification of mRNA for the full length GHRH-R and SVs were utilized. The PCR products were sequenced, and their specificity was confirmed. Nine ECs cancers (23%) expressed mRNA for SV1, three (7.7%) showed SV2 and eight (20.5%) revealed mRNA for SV4. The presence of SVs for GHRH-Rs could not be detected in any of the normal endometrial tissue specimens. The presence of specific, high affinity GHRH-Rs was also demonstrated in EC specimens using radioligand binding studies. Twenty-four of the investigated thirty-nine tumor samples (61.5%) and three of the seven corresponding normal endometrial tissues (42.9%) expressed mRNA for GHRH ligand. Our findings suggest the possible existence of an autocrine loop in EC based on GHRH and its tumoral SV receptors. The antiproliferative effects of GHRH antagonists on EC are likely to be exerted in part by the local SVs and GHRH system. 相似文献
275.
Michal Stransky Zoltan Jurek Robin Santra Adrian P. Mancuso Beata Ziaja 《Molecules (Basel, Switzerland)》2022,27(13)
In this work, we report on incorporating for the first time tree-algorithm based solvers into the molecular dynamics code, XMDYN. XMDYN was developed to describe the interaction of ultrafast X-ray pulses with atomic assemblies. It is also a part of the simulation platform, SIMEX, developed for computational single-particle imaging studies at the SPB/SFX instrument of the European XFEL facility. In order to improve the XMDYN performance, we incorporated the existing tree-algorithm based Coulomb solver, PEPC, into the code, and developed a dedicated tree-algorithm based secondary ionization solver, now also included in the XMDYN code. These extensions enable computationally efficient simulations of X-ray irradiated large atomic assemblies, e.g., large protein systems or viruses that are of strong interest for ultrafast X-ray science. The XMDYN-based preparatory simulations can now guide future single-particle-imaging experiments at the free-electron-laser facility, EuXFEL. 相似文献
276.
DFT and coupled‐cluster calculations show that the B2N2O4 molecule has a triplet ground state and therefore is paramagnetic. 相似文献
277.
ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a “Full Text” option. The original article is trackable via the “References” option. 相似文献
278.
279.