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1.
We describe a general method that enables us to obtain all the singular terms of helicity amplitudes of n-parton processes at one loop. The algorithm uses helicity amplitudes at tree level and simple color algebra. We illustrate the method by calculating the singular part of the one-loop helicity amplitudes of all 2 → 3 parton subprocesses. The results are used to derive the soft gluon limit of the cross sections of all 2 → 4 parton scattering subprocesses which provide a useful initial condition for the angular ordering approximation to coherent multiple soft gluon emission, incorporated in existing Monte Carlo simulation programs. 相似文献
2.
Marshall M. Siegel Keiko Tabei Frank Lambert Leonard Candela Bart Zoltan 《Journal of the American Society for Mass Spectrometry》1998,9(11):1196-1203
The atmospheric pressure ionization (API) source for a commercial mass spectrometer was modified to operate as a dual source in both the electrospray ionization (ESI) and atmospheric pressure chemical ionization (APCI) techniques by simultaneously utilizing the electrospray probe and the corona discharge needle. A switching box was designed to operate in either manual or programmable modes to permit rapid switching between ionization techniques without changing sources, probes, or breaking vacuum. The source can be operated using the following ionization techniques: ESI only, APCI only, ESI/APCI simultaneously, and ESI/APCI alternatingly. The optimum operating conditions for these ionization techniques were similar to the manufacturer’s original specifications except that the APCI flow rate was lower (~50 µL/min versus 1000 µL/min) and externally heated nebulizing gas was found to be desirable. A four-component mixture, introduced by flow injection, was used to demonstrate the versatility of the dual ESI/APCI source. 相似文献
3.
Mohammed Ahmed Shehab Nikita Sharma Andrea Valsesia Gbor Karacs Ferenc Kristly Tams Kos Anett Katalin Lesk Lilla Nnai Klara Hernadi Zoltn Nmeth 《Molecules (Basel, Switzerland)》2022,27(9)
Nowadays, the use of hybrid structures and multi-component materials is gaining ground in the fields of environmental protection, water treatment and removal of organic pollutants. This study describes promising, cheap and photoactive self-supported hybrid membranes as a possible solution for wastewater treatment applications. In the course of this research work, the photocatalytic performance of titania nanowire (TiO2 NW)-based hybrid membranes in the adsorption and degradation of methylene blue (MB) under UV irradiation was investigated. Characterization techniques such as scanning electron microscopy (SEM), transmission electron microscopy (TEM), energy-dispersive X-ray spectroscopy (EDS), X-ray powder diffractometry (XRD) were used to study the morphology and surface of the as-prepared hybrid membranes. We tested the photocatalytic efficiency of the as-prepared membranes in decomposing methylene blue (MB) under UV light irradiation. The hybrid membranes achieved the removal of MB with a degradation efficiency of 90% in 60 min. The high efficiency can be attributed to the presence of binary components in the membrane that enhanced both the adsorption capability and the photocatalytic ability of the membranes. The results obtained suggest that multicomponent hybrid membranes could be promising candidates for future photocatalysis-based water treatment technologies that also take into account the principles of circular economy. 相似文献
4.
Laszlo Papp Zoltan Major Laszlo Rinyu Istvan Tóth 《Isotopes in environmental and health studies》2013,49(4):494-511
This paper describes the procedure followed for noble gas measurements for litres, millilitres and microlitres of water samples in our laboratory, including sample preparation, mass spectrometric measurement procedure, and the complete calibrations. The preparation line extracts dissolved gases from water samples of volumes of 0.2 μ l to 3 l and it separates them as noble and other chemically active gases. Our compact system handles the following measurements: (i) determination of tritium concentration of environmental water samples by the 3He ingrowth method; (ii) noble gas measurements from surface water and groundwater; and (iii) noble gas measurements from fluid inclusions of solid geological archives (e.g. speleothems). As a result, the tritium measurements have a detection limit of 0.012 TU, and the expectation value (between 1 and 20 TU) is within 0.2 % of the real concentrations with a standard deviation of 2.4 %. The reproducibility of noble gas measurements for water samples of 20–40 ml allows us to determine solubility temperatures by an uncertainty better than 0.5 °C. Moreover, noble gas measurements for tiny water amounts (in the microlitre range) show that the results of the performed calibration measurements for most noble gas isotopes occur with a deviation of less than 2 %. Theoretically, these precisions for noble gas concentrations obtained from measurements of waters samples of a few microlitres allow us to determine noble gas temperatures by an uncertainty of less than 1 °C. Here, we present the first noble gas measurements of tiny amounts of artificial water samples prepared under laboratory conditions. 相似文献
5.
In higher dimensional field theories with compactified dimensions there are three standard ways to do perturbative calculations: (i) by the summation over Kaluza-Klein towers; (ii) by the summation over winding numbers making use of the Poisson-resummation formula; and (iii) by using mixed propagators, where the coordinates of the four infinite dimensions are Fourier-transformed to momentum space while those of the compactified dimension are kept in configuration space. The third method is broadly used in finite temperature field theory calculations. One of its advantages is that one can easily separate the ultraviolet divergent terms of the uncompactified theory from the non-local finite corrections arising from windings around the compact dimensions. In this note we demonstrate the use of this formalism by calculating one-loop self-energy corrections in a 5D theory formulated on the manifold and on the orbifold . 相似文献
6.
Junjun Wu Lu Gem Gao Zoltan Varga Xuefei Xu Wei Ren Donald G. Truhlar 《Angewandte Chemie (International ed. in English)》2020,59(27):10826-10830
Faced with the contradictory results of two recent experimental studies [Jara‐Toro et al., Angew. Chem. Int. Ed. 2017 , 56, 2166 and Chao et al., Angew. Chem. Int. Ed. 2019 , 58, 5013] of the possible catalytic effect of water vapor on CH3OH + OH reaction, we report calculations that corroborate the conclusion made by Chao et al. and extend the rate constant evaluation down to 200 K. The rate constants of the CH3OH + OH reaction catalyzed by a water molecule are computed as functions of temperature and relative humidity using high‐level electronic structure and kinetics calculations. The Wuhan–Minnesota Scaling (WMS) method is used to provide accurate energetics to benchmark a density functional for direct dynamics. Both high‐frequency and low‐frequency anharmonicities are included. Variational and tunneling effects are treated by canonical variational transition state theory with multidimensional small‐curvature tunneling. And, most significantly, we include multistructural effects in the rate constant calculations. Our calculations show that the catalytic effect of water vapor is not observable at 200–400 K. 相似文献
7.
Balazs Kobzi Erno Kuzmann Zoltan Homonnay Stjepko Krehula Mira Ristic Shiro Kubuki 《Journal of Radioanalytical and Nuclear Chemistry》2018,316(2):579-586
Tin silicate glass without SnOx nanoparticles (SiO2·SnOx), a silica glass containing only SnOx nanoparticles (SiO2·SnOxNP) and the improved product, which combines the tin silicate glass with SnOx nanoparticles (SiO2·SnOx·SnOxNP) was prepared. For the structural analysis 119Sn Mössbauer spectroscopy and X-ray diffraction were applied. The 119Sn Mössbauer spectra showed that the SiO2·SnOx·SnOxNP sample had the largest SnII content (12.0%). It also had an outstanding methylene blue degradation with the first-order rate value with (18?±?2) × 10?3 min?1 with visible light irradiation. 相似文献
8.
Keszthelyi T Paszti Z Rigó T Hakkel O Telegdi J Guczi L 《The journal of physical chemistry. B》2006,110(17):8701-8714
Langmuir-Blodgett (LB) monomolecular layers of alkylhydroxamic acids and alkylphosphonic acids on copper and iron substrates have been studied by X-ray photoelectron spectroscopy (XPS) and sum-frequency vibrational spectroscopy. According to the XPS results, the structures of the hydroxamic acid and phosphonic acid Langmuir-Blodgett films are very similar: the thickness of the layer of the hydrocarbon tails is typically 1.9-2.1 nm, while the layer of headgroups is about 0.3-0.35 nm thick. The tilt angle of the carbon chains is estimated to be 20-30 degrees with respect to the sample surface normal, and the molecules are connected to the substrate via their headgroups. Analysis of the P 2p and N 1s lines indicates the presence of deprotonated headgroups. The substrate Cu 2p line includes a component which can be assigned to Cu(2+) ions in a thin Cu(OH)(2) layer. The deposition of LB layers led to significant decrease of the hydroxide-related signal, which indicates that binding of the headgroups to the surface is accompanied by the elimination of water molecules. The sum-frequency spectra also clearly indicate that well-ordered monolayers can be formed by the Langmuir-Blodgett technique. Since the non-resonant background from the metal substrates renders the analysis of the spectra more difficult, model system samples on glass were prepared. It was found that the alkyl chains of the adsorbed acids predominantly adopt the all-trans conformation and form an ordered structure. Upper limits for the mean tilt angle of the terminal methyl groups are approximately 10-20 degrees. 相似文献
9.
Mohd Rushdi Abu Bakar Zoltan Kalman Nagy Christopher David Rielly 《Journal of Thermal Analysis and Calorimetry》2010,99(2):609-619
A combination of differential scanning calorimetry and hot-stage microscopy with image analysis has been used to investigate the polymorphism of sulfathiazole. The use of light intensity profiles obtained from the HSM images, as an alternative way to present results of the HSM analysis, was found to be useful in describing and verifying thermal events. The approach provides a unique insight into the polymorphic transformations and thermal behaviour exhibited by this compound. The results of the experiments show that sulfathiazole tends to crystallise as mixtures of polymorphs, even though the literature methods for producing pure polymorph were followed. 相似文献
10.