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61.
The properties of paramagnetic complexes formed by muonium located near acceptor and donor impurities in silicon are calculated using the quantum chemical methods. The calculated data are compared to the experimentally observed characteristics of normal and anomalous muonium centers. 相似文献
62.
Zohar Nir Otto Vogl Amitava Gupta 《Journal of polymer science. Part A, Polymer chemistry》1982,20(10):2735-2754
2(2-Hydroxy-5-isopropenylphenyl)2H-benzotriazole was synthesized in 40% overall yield starting from o-nitroaniline. Diazotization in aqueous hydrochloric acid gave o-nitrophenyl diazonium chloride which was condensed with p-hydroxyacetophenone; the azo compound was reduced to 2(2-hydroxy-5-acetylphenyl) 2H-benzotriazole with zinc powder in sodium hydroxide solution and the 2-hydroxy group of the compound was acetylated. Treatment of the acetyl compound with methyl Grignard reagent resulted in the methylation of the 5-acetyl group to 2[2-acetoxy-5(2-hydroxy-2-propyl)phenyl]2H-benzotriazole which was then dehydrated with potassium hydrogen sulfate to the desired 2(2-hydroxy-5-isopropenylphenyl)2H-benzotriazole. This monomer did not homopolymerize, but was copolymerized readily with styrene, methyl methacrylate, and n-butyl acrylate with azobisisobutyronitrile as the initiator. 2(2-Acetoxy-5-acetylphenyl)2H-benzotriazole was also reduced with sodium borohydride to form 2[2-acetoxy-5-(1-hydroxyethyl)phenyl]2H-benzotriazole which was dehydrated and hydrolyzed to the known 2(2-hydroxy-5-vinylphenyl)-2H-benzotriazole. This route provides a novel and simpler synthesis of 2(2-hydroxy-5-vinylphenyl)2H-benzotriazole. 相似文献
63.
B Frydman S Reil M E Despuy H Rapoport 《Journal of the American Chemical Society》1969,91(9):2338-2342
64.
A triangle‐free graph G is called k‐existentially complete if for every induced k‐vertex subgraph H of G, every extension of H to a ‐vertex triangle‐free graph can be realized by adding another vertex of G to H. Cherlin 11 , 12 asked whether k‐existentially complete triangle‐free graphs exist for every k. Here, we present known and new constructions of 3‐existentially complete triangle‐free graphs. 相似文献
65.
66.
Non-classical negations may fail to be contradictory-forming operators in more than one way, and they often fail also to respect fundamental meta-logical properties such as the replacement property. Such drawbacks are witnessed by intricate semantics and proof systems, whose philosophical interpretations and computational properties are found wanting. In this paper we investigate congruential non-classical negations that live inside very natural systems of normal modal logics over complete distributive lattices; these logics are further enriched by adjustment connectives that may be used for handling reasoning under uncertainty caused by inconsistency or undeterminedness. Using such straightforward semantics, we study the classes of frames characterized by seriality, reflexivity, functionality, symmetry, transitivity, and some combinations thereof, and discuss what they reveal about sub-classical properties of negation. To the logics thereby characterized we apply a general mechanism that allows one to endow them with analytic ordinary sequent systems, most of which are even cut-free. We also investigate the exact circumstances that allow for classical negation to be explicitly defined inside our logics. 相似文献
67.
Chaim Even‐Zohar 《Random Structures and Algorithms》2017,51(1):121-142
We introduce and study the writhe of a permutation, a circular variant of the well‐known inversion number. This simple permutation statistics has several interpretations, which lead to some interesting properties. For a permutation sampled uniformly at random, we study the asymptotics of the writhe, and obtain a non‐Gaussian limit distribution. This work is motivated by the study of random knots. A model for random framed knots is described, which refines the Petaluma model, studied with Hass, Linial, and Nowik (Discrete Comput Geom, 2016). The distribution of the framing in this model is equivalent to the writhe of random permutations. © 2016 Wiley Periodicals, Inc. Random Struct. Alg., 51, 121–142, 2017 相似文献
68.
S. Zohar N. Venugopalan D. Kissick M. Becker S. Xu O. Makarov S. Stepanov C. Ogata R. Sanishvili R. F. Fischetti 《Journal of synchrotron radiation》2016,23(2):443-447
X‐ray beam stability is crucial for acquiring high‐quality data at synchrotron beamline facilities. When the X‐ray beam and defining apertures are of similar dimensions, small misalignments driven by position instabilities give rise to large intensity fluctuations. This problem is solved using extremum seeking feedback control (ESFC) for in situ vertical beam position stabilization. In this setup, the intensity spatial gradient required for ESFC is determined by phase comparison of intensity oscillations downstream from the sample with pre‐existing vertical beam oscillations. This approach compensates for vertical position drift from all sources with position recovery times <6 s and intensity stability through a 5 µm aperture measured at 1.5% FWHM over a period of 8 hours. 相似文献
69.
70.
A design of an ionization calorimeter in which scintillation fibers oriented in three mutually orthogonal directions are used as a detecting system is proposed. Such a device can be employed in satellite-borne experiments aimed at studying high-energy cosmic rays. This scheme makes it possible to reconstruct the primary-particle energy for any track direction, this ensuring a large geometric factor. A high spatial resolution enables one to separate the electromagnetic and hadron components by the shape of the cascade. 相似文献