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241.
Zofia Peimel-Stuglik Stanisaw Kowalak Aldona Jankowska 《Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy》2008,69(5):1395
The aim of the work was to collect information concerning boundary effects which are suspected in α-alanine dosimeters consisted of powdered microcrystalline α-alanine and binders. In our experiments the conventional binders were replaced by molecular sieves (MS). MS are inorganic porous materials (host structures) with well organized and uniform intra-crystalline pore systems of nano-scale size. The guest molecules can be either physically adsorbed on very large inner MS surface, or chemically bound to the active sites. They can be also encapsulated inside the intracrystalline cavities. The EPR spectra of gamma irradiated dl-α-alanine supported on NaY, CeY, SOD, mordenite, ZSM-5 and ALPO4-5 were very similar to that one observed for irradiated microcrystalline dl-α-alanine. In the case of alanine supported on HY an initial EPR spectrum was different and only after some weeks it made resemble to the well known quintet observed in microcrystalline samples. In sodalites synthesized in the presence of dl-α-alanine EPR signal appeared in non-irradiated sample was very low and structureless. The irradiated sample showed a distinct spectrum which was quite different from that one observed for crystalline dl-α-alanine. 相似文献
242.
Zofia Rz?czyńska Anna Danczowska-Burdon 《Journal of Thermal Analysis and Calorimetry》2012,108(3):991-999
Pyridine-2,4-dicarboxylic acid (lutidinic acid) is next one after pyridine-2,5-dicarboxylic acid of the six isomers which lanthanide complexes were studied thermally and spectrally. New complexes synthesized with light lanthanides (III) with general formula Ln2L3·nH2O, where n?=?7.5; 8; 8.5; 9, were obtained. Sodium salt was obtained as hexahydrated compound. Hydrated complexes of La(III), Ce(III), Pr(III), Nd(III), Sm(III), Eu(III), and Gd(III) are thermally stable up to 303?C313?K. Dehydration process run for all compounds in one stage, anhydrous compounds decompose through appropriate light lanthanides (III) oxalates, oxocarbonates, carbonates to metal oxides. Theoretical IR and Raman studies were carried out in order to identify precisely characteristic group bands vibrations present on IR and Raman spectra. 相似文献
243.
Zofia Lendzion-Bieluń 《Central European Journal of Chemistry》2012,10(2):327-331
Based on the active surface model of the iron catalyst for ammonia synthesis, the assumptions which led to obtaining the cobalt
catalyst for ammonia synthesis were described. The incorporation into the system small amounts of manganese, an element which
binds oxygen stronger than cobalt, has influence the development of the catalyst’s specific surface area. The activity of
manganese modified catalysts is higher than that of cobalt catalyst without manganese addition. The obtained catalysts were
characterized with the following methods: ICP-OES, XRD, BET
相似文献
244.
The uncertainty relation for the photons in three dimensions that overcomes the difficulties caused by the nonexistence of the photon position operator is derived in quantum electrodynamics. The photon energy density plays the role of the probability density in configuration space. It is shown that the measure of the spatial extension based on the energy distribution in space leads to an inequality that is a natural counterpart of the standard Heisenberg relation. The equation satisfied by the photon wave function in momentum space which saturates the uncertainty relations has the form of the Schr?dinger equation in coordinate space in the presence of electric and magnetic charges. 相似文献
245.
Lucjan Chmielarz Małgorzata Rutkowska Piotr Kuśtrowski Marek Drozdek Zofia Piwowarska Barbara Dudek Roman Dziembaj Marek Michalik 《Journal of Thermal Analysis and Calorimetry》2011,105(1):161-170
Hydrotalcite-like materials containing apart from magnesium and aluminum also copper, cobalt, nickel, and iron were prepared by a co-precipitation method. Thermal transformations of hydrotalcite-like materials were studied by thermal analysis methods as well as XRD, UV–vis–DRS, and XPS measurements of the samples calcined at various temperatures (600, 700, and 800 °C). Calcined hydrotalcites, especially those containing cobalt and copper, were found to be active and selective catalysts of N2O decomposition. It was shown that an increase in the calcination temperature significantly activated the Co-containing catalysts. Promotion of the samples with potassium resulted in activation of the hydrotalcite-based catalysts. 相似文献
246.
Daniel Taton Agnieszka‐Zofia Wilczewska Mathias Destarac 《Macromolecular rapid communications》2001,22(18):1497-1503
Double hydrophilic statistical, diblock and triblock copolymers comprised of acrylamide and acrylic acid units have been synthesized in aqueous medium using the MADIX process. Starting from an either monofunctional or difunctional xanthate, the resulting AB and ABA‐type double hydrophilic block copolymers (DHBC) exhibited molar masses predetermined by the initial monomer/xanthate precursor molar ratio and polydispersity indices in the range 1.2–1.5. Batch copolymerizations yielded well‐defined statistical copolymers that were chain‐extended for the synthesis of novel poly‐ (acrylic acid‐stat‐acrylamide)‐block‐polyacrylamide DHBC. 相似文献