弹性介质中圆柱壳动力响应研究的现状和展望

一、引言在地震动情况下,地下结构与地面结构相比较其动力响应是十分不同的。以桥梁和水堤为例,对这类结构的设计,水平惯性力是一个极为重要的因素。可是,对于地下结构,以埋管为例,惯性荷载主要由其周围的土介质所承受。地下管道系统的地震破坏,     

HT-7U超导托卡马克装置极向场线圈的等效弹性常数及其残余刚度

HT－7装置的超导极向场线圈由导管，超导材料和绝缘体组合而成，具有复杂的正交各向异性的性质。本文从微观力学的观点出发，将极向场线圈整体作为一种复合材料来考虑，采用微观力学的复合律和损伤力学的细观损伤模型，求出了极向场线圈的等效弹性常数和残余刚度；并且，残余刚度的计算结果已得到了实验验证。这些材料特性已被用于有限元分析的输入数据。     

Parametric response of a metallic column at elevated temperature

The parametric response of a metallic column at elevated temperature is investigated, taking into account its non-linear viscous characteristics. An asymptotic method for the determination of the region of self-excitation and the amplitudes and phase angles for both stationary and non-stationary responses is outlined briefly. This method is applied to predict the parametric response of a 2618-T61 Al alloy column at 200°C. It is shown that the region of selfexcitation shifts away from the elastic frequency axis, that the amplitude of the stationary response increases sharply as the excitation parameters move from the stability region into the selfexcitation region and that the amplitude of the non-stationary response can be approximated by the stationary response solution for slow varying excitation frequency.     

90°弯管内流动的理论模型及流动特性的数值研究

从三维不可压缩雷诺时均Navier-Stokes方程出发,对90°弯曲管道内湍流流动进行数值模拟。网格划分采用六面体网格,湍流模型为RNGk-ε模型,在近壁区采用两层壁面模型进行修正,流场的计算结果与实验数据吻合较好。在此基础上,本文数值研究了来流方向对流场结构和流动特性的影响。得出在弯管流场中发生了分离现象,且随着来流侧滑角的增大,分离区范围增大。此外,随着来流从同一侧滑角变换至同一攻角时,横截面的二次流图像中也从具有两个对称主涡变成只具有一个主涡的现象。     

Realizing both High Energy and High Power Densities by Twisting Three Carbon‐Nanotube‐Based Hybrid Fibers

Energy storage devices, such as lithium‐ion batteries and supercapacitors, are required for the modern electronics. However, the intrinsic characteristics of low power densities in batteries and low energy densities in supercapacitors have limited their applications. How to simultaneously realize high energy and power densities in one device remains a challenge. Herein a fiber‐shaped hybrid energy‐storage device (FESD) formed by twisting three carbon nanotube hybrid fibers demonstrates both high energy and power densities. For the FESD, the energy density (50 mWh cm^?3 or 90 Wh kg^?1) many times higher than for other forms of supercapacitors and approximately 3 times that of thin‐film batteries; the power density (1 W cm^?3 or 5970 W kg^?1) is approximately 140 times of thin‐film lithium‐ion battery. The FESD is flexible, weaveable and wearable, which offers promising advantages in the modern electronics.     

Two Uranyl Complexes with Pyromellitic Acid. A Heterometallic Complex with U=O–CuII Interaction

Two uranyl complexes based on pyromellitic acid were hydrothermally synthesized, and their X‐ray single‐crystal diffraction structures were determined. Complex [UO₂(Hbtec)]^–(Himd)⁺ · H₂O ( 1 ) (H₄btec = pyromellitic acid, imd = imidazole), is an ionic complex, which shows a typical (4, 4) topological structure in the space. A heterometallic complex, UO₂Cu(btec)(phen) ( 2 ) (phen = 1,10‐phenanthroline) results from the reaction of uranyl nitrate and copper(II) bromide with pyromellitic acid. The structure of complex 2 revealed that the chains of UO₇ and CuO₃N₂ units were connected to each other through the carboxyl groups and U=O–Cu interactions to create a two‐dimensional framework.     

氧化钛负载脱硝催化剂的碱中毒过程：氧化钒的保留和氧化钨的牺牲

V2O5-WO3/TiO2催化剂目前已广泛用于电厂和工业锅炉燃烧废气脱硝,但燃烧原料煤及石油中含有的杂质元素碱金属与碱土金属元素可吸附在催化剂上,不仅会减少催化剂酸性位的数量,还会与催化活性元素结合生成惰性物种,导致催化剂失活。因此,已有许多有关钒钨钛催化剂碱中毒的研究,从催化剂的氧化还原能力、酸性位损失及表面孔结构等方面进行了讨论。但这些研究大多集中在碱中毒对活性组分V2O5的影响及中毒催化剂的活性变化,很少涉及催化剂中WO3的作用,也缺乏有关不同活性元素与钾盐反应的实验证据。本文采用过量浸渍法制备了不同钒和钨含量的钒钨钛催化剂,研究了氯化钾对其氨法选择性催化还原(NH3-SCR)活性的失活效应。利用感应耦合等离子体、N2吸附、拉曼光谱、H2程序升温还原、NH3吸附红外光谱和NH3氧化活性等手段对新鲜和中毒催化剂的性质进行了表征,特别探讨了V2O5和WO3对催化剂抗碱中毒能力的贡献。
　　催化剂活性测试结果表明, V2O5含量越高,活性温度窗口越宽,而且含有WO3的三元催化剂活性高于V2O5/TiO2二元催化剂。催化剂的BET比表面积和孔结构取决于TiO2载体,随活性组分配比变化不大,说明催化剂物理结构性质并非影响活性的主要因素。原位红外光谱及H2程序升温还原测试结果表明,随V2O5含量提高,催化剂表面Br?nsted酸性位数量及氧化还原能力提高。作为反应的主要活性物种, V2O5在碱中毒处理后变成惰性的偏钒酸钾KVO3,使催化剂中Br?nsted酸性位减少,热稳定性下降,并削弱了催化剂的氧化还原能力,因此低钒含量的催化剂容易严重中毒失活。在高钒负载量(3%)时,部分V2O5在碱中毒后得以保留,从而使催化剂保持了一定的脱硝催化活性。
　　另外, WO3能给催化剂表面提供热稳定的酸性位,虽然WO3自身的氧化还原能力差,但其能改善V2O5的分散性,从而提高V2O5-WO3/TiO2催化剂的活性。除此之外, WO3在催化剂碱中毒过程中还能扮演牺牲剂,与钾反应生成钨酸钾(K2WO4),即在V2O5与钾离子结合形成KVO3的同时,部分WO3也会与钾反应形成K2WO4,可以使三元催化剂保留更多的活性V物种。因此,在所研究的催化剂中,高钒负载量的V2O5-WO3/TiO2催化剂表现出最好的抗碱中毒能力。
　　活性影响因素分析表明,对于新鲜催化剂,其表面吸附的NH3量足够多,催化剂活性与表面酸性相关度不大,脱硝效率主要取决于催化剂的氧化还原能力。但是,对于碱中毒处理后的催化剂,其表面吸附NH3的能力大大削弱,这时脱硝效率除了受催化剂氧化还原能力影响,在很大程度上也依赖于催化剂的表面酸性。