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151.
In situ variable temperature XRD (VT-XRD) measurements on the transformation of nano-precursors to LaNiO phases are presented. Experimental results showed that LaNiO3 and La2NiO4 phases were formed at ca. 700 °C via the reaction of La2O3 and NiO (from the initial nano-precursors), where a relatively low temperature of 700 °C was found for the synthesis of La2NiO4. The formation of La3Ni2O7 at higher temperature (up to 1150 °C) appeared to proceed through a further reaction of La2NiO4 with unreacted NiO, whilst the formation of La4Ni3O10 (at 1075 °C) proceeded via a further decomposition of LaNiO3. Although phase pure La3Ni2O7 and La4Ni3O10 were not directly obtained under the processing conditions herein, the results of this study allow for a better understanding of formation pathways, particularly for the higher order La-Ni-O phases. 相似文献
152.
153.
In this note, we revisit the single-index model with heteroscedastic error, and recommend an estimating equation method in terms of transferring restricted least squares to unrestricted least squares: the estimator of the index parameter is asymptotically more efficient than existing estimators in the literature in the sense that it is of a smaller limiting variance. 相似文献
154.
Chemical constituents from Schisandra sphenanthera 总被引:1,自引:0,他引:1
The chemical constituents of the stems of Schisandra sphenanthera are described for the first time. This investigation has resulted in the isolation of a new phenolic glycoside (1), along with seven known compounds. The structure of 1 was assigned by using spectroscopic techniques, including 2D NMR spectra. 相似文献
155.
J. Weng R. H. Olley D. C. Bassett P. Jskelinen 《Journal of Polymer Science.Polymer Physics》2004,42(18):3318-3332
Of the three melting peaks typical of a propylene–ethylene random copolymer (with 5.1 wt % ethylene) crystallized between 110 and 140 °C, the two higher peaks result from primary and secondary isothermal crystallization, whereas the material crystallized on cooling gives the lowest peak. In contrast to polypropylene homopolymers, which show strong morphological changes developing from the center of a spherulite, copolymer specimens are uniformly crosshatched. The highest melting peak is related to an open crosshatched framework of primary lamellae, and the next lower peak is related to later forming subsidiary lamellae filling the intervening space. The origin and nature of these double peaks are discussed in terms of the fractional crystallization and the ensuing constraints placed on isothermal lamellar thickening as a result of the exclusion of the comonomer from the polypropylene lattice. © 2004 Wiley Periodicals, Inc. J Polym Sci Part B: Polym Phys 42: 3318–3332, 2004 相似文献
156.
Single‐source organometallic precursors based on a number of homometallic clusters as well as heterometallic cluster RuOs3(CO)13(µ‐H)2 have been used for the chemical vapor deposition of osmium films and osmium–ruthenium alloy films, respectively. Copyright © 2009 John Wiley & Sons, Ltd. 相似文献
157.
We have developed a novel alkaline anion exchange membrane derived from poly(ether‐imide) for improved ionic conductivity. The effects of several important parameters on the chloromethylation of the membrane were investigated. These parameters included reaction temperature, reaction time, concentration of chloromethylation agent, concentration of polymer, and the amount of catalyst. The quaternization of the synthesized chloromethylated polymer was studied as well. The results show that all the studied parameters exhibited significant impacts on chloromethylation. Among them, the concentration of the chloromethylation agent played a key role in increasing the chloromethyl functional group attachment onto the polymer. It was found that the gelation could be avoided if these reaction parameters were controlled. It was also found that using an appropriate quaternization approach could significantly improve the ionic conductivity and optimize the conductivity of the membrane even though the functional chloromethyl groups attached to the polymer are limited. Copyright © 2009 John Wiley & Sons, Ltd. 相似文献
158.
Xinghong Zhang Lin Xu Wenbo Han Ling Weng Jiecai Han Shanyi Du 《Solid State Sciences》2009,11(1):156-161
Hot-pressed zirconium diboride (ZrB2) matrix composites containing 0–30 vol% silicon carbide (SiC) whiskers have been investigated to determine the effect of composition (i.e. amount of SiC whiskers) on the microstructure, mechanical properties and thermal properties. With increasing SiC whisker volume contents, the flexural strength and fracture toughness of the composites were improved compared to those of monolithic ZrB2. Flexural strength increased from 629 MPa for pure ZrB2 to 767 MPa for ZrB2–30 vol%SiCw. Likewise, fracture toughness ranged from 5.4 to 7.1 MPa m1/2 over the same composition range. Specific heat capacity increased with SiC whisker addition, while thermal diffusivity and thermal conductivity decreased slightly with the increase of SiC whisker content. 相似文献
159.
We study Deligne products for forgetful maps between moduli spaces of marked curves by offering a closed formula for tautological
line bundles associated to marked points. In particular, we show that the Deligne products for line bundles on the total spaces
corresponding to “forgotten” marked points are positive integral multiples of the Weil-Petersson bundles on the base moduli
spaces.
Partially supported by the Japan Society for the Promotion of Science. 相似文献
160.
Alexeff I. Weng Lock Kang 《IEEE transactions on plasma science. IEEE Nuclear and Plasma Sciences Society》1999,27(1):32-33
Corona discharges in the air are intensified if a small amount of nonelectronegative gas is fed into the limited region around each corona point. The ions produced in the active region then migrate into the air, to produce an intensified negative and positive ion plasma 相似文献