全文获取类型
收费全文 | 222篇 |
免费 | 10篇 |
专业分类
化学 | 105篇 |
晶体学 | 2篇 |
力学 | 4篇 |
数学 | 29篇 |
物理学 | 92篇 |
出版年
2023年 | 2篇 |
2022年 | 2篇 |
2021年 | 8篇 |
2020年 | 3篇 |
2019年 | 5篇 |
2018年 | 6篇 |
2017年 | 7篇 |
2016年 | 6篇 |
2015年 | 6篇 |
2014年 | 14篇 |
2013年 | 11篇 |
2012年 | 3篇 |
2011年 | 15篇 |
2010年 | 9篇 |
2009年 | 4篇 |
2008年 | 7篇 |
2007年 | 7篇 |
2006年 | 5篇 |
2005年 | 4篇 |
2004年 | 5篇 |
2003年 | 2篇 |
2002年 | 7篇 |
2001年 | 3篇 |
2000年 | 2篇 |
1999年 | 5篇 |
1998年 | 2篇 |
1997年 | 5篇 |
1996年 | 5篇 |
1995年 | 3篇 |
1994年 | 4篇 |
1993年 | 6篇 |
1992年 | 8篇 |
1991年 | 5篇 |
1990年 | 8篇 |
1989年 | 7篇 |
1988年 | 4篇 |
1987年 | 3篇 |
1986年 | 2篇 |
1984年 | 4篇 |
1983年 | 3篇 |
1982年 | 5篇 |
1981年 | 4篇 |
1979年 | 2篇 |
1978年 | 1篇 |
1977年 | 1篇 |
1976年 | 1篇 |
1975年 | 1篇 |
排序方式: 共有232条查询结果,搜索用时 46 毫秒
61.
Oscar Donoso‐Tauda Carlos A. Escobar Ramiro Araya‐Maturana Andrs Vega 《Acta Crystallographica. Section C, Structural Chemistry》2006,62(10):o631-o632
The molecule of the title compound, C19H20O2S, corresponds to a chiral sulfinyldienol with two stereogenic centres, viz. the C atom susbtituted by the hydroxy group and the sulfinyl S atom. The molecule displays a V‐shape in the solid state. The dihedral angle defined by the least‐squares planes of the aromatic rings is 72.9 (1)°. The packing pattern exhibits the following intermolecular hydrogen bonds: one O—H⋯O [H⋯O = 1.98 Å, O⋯O = 2.785 (4) Å and O—H⋯O = 166°] and two C—H⋯O [H⋯O = 2.58 and 2.60 Å, C⋯O = 3.527 (5) and 3.347 (5) Å, and C—H⋯O = 164 and 134°]. These define a chain along b. 相似文献
62.
Andrs Vega Oscar Donoso‐Tauda Andres Ibaez Carlos A. Escobar 《Acta Crystallographica. Section C, Structural Chemistry》2008,64(4):o199-o204
A series of five compounds containing the bicyclo[3.3.0]octa‐2,6‐diene skeleton are described, namely tetramethyl cis,cis‐3,7‐dihydroxybicyclo[3.3.0]octa‐2,6‐diene‐2,4‐exo,6,8‐exo‐tetracarboxylate, C16H18O10, (I), tetramethyl cis,cis‐3,7‐dihydroxy‐1,5‐dimethylbicyclo[3.3.0]octa‐2,6‐diene‐2,4‐exo,6,8‐exo‐tetracarboxylate, C18H22O10, (II), tetramethyl cis,cis‐3,7‐dimethoxybicyclo[3.3.0]octa‐2,6‐diene‐2,4‐exo,6,8‐exo‐tetracarboxylate, C18H22O10, (III), tetramethyl cis,cis‐3,7‐dimethoxy‐1,5‐dimethylbicyclo[3.3.0]octa‐2,6‐diene‐2,4‐exo,6,8‐exo‐tetracarboxylate, C20H26O10, (IV), and tetramethyl cis,cis‐3,7‐diacetoxybicyclo[3.3.0]octa‐2,6‐diene‐2,4‐exo,6,8‐exo‐tetracarboxylate, C20H22O12, (V). The bicyclic core is substituted in all cases at positions 2, 4, 6 and 8 with methoxycarbonyl groups and additionally at positions 3 and 7 with hydroxy [in (I) and (II)], methoxy [in (III) and (IV)] or acetoxy [in (V)] groups. The conformations of the methoxycarbonyl groups at positions 2 and 4 are exo for all five compounds. Each C5 ring of the bicyclic skeleton is almost planar, but the rings are not coplanar, with dihedral angles of 54.93 (7), 69.85 (5), 64.07 (4), 80.74 (5) and 66.91 (7)° for (I)–(V), respectively, and the bicyclooctadiene system adopts a butterfly‐like conformation. Strong intramolecular hydrogen bonds exist between the –OH and C=O groups in (I) and (II), with O...O distances of 2.660 (2) and 2.672 (2) Å in (I), and 2.653 (2) and 2.635 (2) Å in (II). The molecular packing is stabilized by weaker C—H...O(=C) interactions, leading to dimers in (I)–(III) and to a chain structure in (V). The structure series presented in this article shows how the geometry of the cycloocta‐2,6‐diene skeleton changes upon substitution in different positions and, consequently, how the packing is modified, although the intermolecular interactions are basically the same across the series. 相似文献
63.
64.
The IR and Raman spectra of the oxyapatite Ca8La2(VO4)6O2 has been measured and discussed in comparison with those of related species. Data for Ca8La2(PO4)6O2 and for a solid solution of composition Ca8La2(PO4)6O2 are also reported. 相似文献
65.
Benito Alcaide Gerardo Escobar JoséL. González-Simó Carmen López-Mardomingo Rafael Pérez-Ossorio Joaquin Plumet 《Tetrahedron letters》1982,23(19):2033-2036
Total stereoselectivity is observed in the sodium borohydride reduction of α-aminodeoxybenzoins and their hydrochlorides in various hydroxylic solvents. RS - SR isomer (erythro) was the only aminoalcohol obtained. 相似文献
66.
Crystallographic data for the oxoapatites of general formula Ca8
Ln
2(PO4)6O2 withLn=La, Pr-Ho) have been obtained from X-ray powder data. The vibrational spectra, which are also discussed, allow to make a proposal about the location of the lanthanide cations present in these lattices. 相似文献
67.
Fabiola Angulo Gerard Olivar Gustavo A. Osorio Carlos M. Escobar Jocirei D. Ferreira Johan M. Redondo 《Communications in Nonlinear Science & Numerical Simulation》2012,17(12):4683-4689
Non-smooth systems (namely piecewise-smooth systems) have received much attention in the last decade. Many contributions in this area show that theory and applications (to electronic circuits, mechanical systems, …) are relevant to problems in science and engineering. Specially, new bifurcations have been reported in the literature, and this was the topic of this minisymposium. Thus both bifurcation theory and its applications were included. Several contributions from different fields show that non-smooth bifurcations are a hot topic in research. Thus in this paper the reader can find contributions from electronics, energy markets and population dynamics. Also, a carefully-written specific algebraic software tool is presented. 相似文献
68.
de Escobar Cícero Coelho Lansarin Marla Azário Santos João Henrique Zimnoch dos Brandestini Milena Duarte 《Journal of Sol-Gel Science and Technology》2018,88(1):220-226
Journal of Sol-Gel Science and Technology - In this work, a ZnO-based molecularly imprinted photocatalyst (MIP) bearing acid Lewis sites (Al) was evaluated for photocatalytic oxidation of glycerol.... 相似文献
69.
Reducing inconsistency measured by the geometric consistency index in the analytic hierarchy process
Juan Aguarón María Teresa Escobar José María Moreno-Jiménez 《European Journal of Operational Research》2021,288(2):576-583
This paper presents a theoretical framework and a procedure for revising the judgements and improving the inconsistency of an Analytic Hierarchy Process (AHP) pairwise comparison matrix when the Row Geometric Mean (RGM) is used as the prioritisation procedure and the Geometric Consistency Index (GCI) is the inconsistency measure. Inconsistency is improved by slightly modifying the judgements that further reduce the GCI. Both the judgements and the derived priority vector will be close to the initial values. A simulation study is utilised to analyse the performance of the algorithm. The proposed framework allows the specification of the procedure to particular interests. A numerical example illustrates the proposed procedure. 相似文献
70.
Abouzaid E Arenton M Barker AR Bellantoni L Blucher E Bock GJ Cheu E Coleman R Corcoran MD Cox B Erwin AR Escobar CO Glazov A Golossanov A Gomes RA Gouffon P Hsiung YB Jensen DA Kessler R Kotera K Ledovskoy A McBride PL Monnier E Nguyen H Niclasen R Phillips DG Ping H Ramberg EJ Ray RE Ronquest M Santos E Slater W Smith D Solomey N Swallow EC Toale PA Tschirhart R Velissaris C Wah YW Wang J White HB Whitmore J Wilking MJ Winston R Worcester ET Worcester M Yamanaka T Zimmerman ED 《Physical review letters》2011,107(20):201803
The KTeV E799 experiment has conducted a search for the rare decays, K(L)→π(0)π(0)μ(+)μ(-) and K(L)→π(0)π(0)X(0)→π(0)π(0)μ(+)μ(-), where the X(0) is a possible new neutral boson that was reported by the HyperCP experiment with a mass of (214.3 ± 0.5) MeV/c(2). We find no evidence for either decay. We obtain upper limits of Br(K(L)→π(0)π(0)X(0)→π(0)π(0)μ(+)μ(-)) < 1.0 × 10(-10) and Br(K(L)→π(0)π(0)μ(+)μ(-)) < 9.2 × 10(-11) at the 90% confidence level. This result rules out the pseudoscalar X(0) as an explanation of the HyperCP result under the scenario that the dsX(0) coupling is completely real. 相似文献