Vertical assembly of carbon nanotubes for via interconnects

The via interconnects are key components in ultra-large scale integrated circuits(ULSI).This paper deals with a new method to create single-walled carbon nanotubes(SWNTs) via interconnects using alternating dielectrophoresis(DEP).Carbon nanotubes are vertically assembled in the microscale via-holes successfully at room temperature under ambient condition.The electrical evaluation of the SWNT vias reveals that our DEP assembly technique is highly reliable and the success rate of assembly can be as high as 90%.We also propose and test possible approaches to reducing the contact resistance between CNT vias and metal electrodes.     

Hierarchical nanowires for high-performance electrochemical energy storage

Nanowires are promising candidates for energy storage devices such as lithium-ion batteries, su- per（：apa.citors and lithium-air batteries. However, simple-structured nanowires have some limitations hence the strategies to make improvements need to be explored and investigated. Hierarchical nanowires with enhanced periormanee have been considered as an ideal candidate for energy storage due to the novel structures and/or synergistic properties. This review describes some of the recent progresses in the hierarchical nanowire merits, classification, synthesis and performance in energy storage applieat, ions. Herein we discuss the hierarchical nanowires based on their structural design from three major categories, including exterior design, interior design and aligned nanowire assembly. This review also briefly outlines the prospects of hierarchical nanowires in morphology control, property enhancement and application versatility.     

理论研究B2分子X3Σg-和A3Πu态的光谱性质

采用Davidson修正的内收缩多参考组态相互作用方法及Dunning等的相关一致基aug-cc-pV6Z计算了B₂分子X³∑_g^-和A³Π_u电子态的势能曲线.利用总能量外推公式,将两个电子态的总能量分别外推至完全基组极限.对势能曲线进行核价相关修正及相对论修正计算,得到了同时考虑两种效应修正的外推势能曲线.通过同位素质量识别,得到了主要的同位素分子¹¹B¹¹B和¹⁰B¹¹B的X³Σ_g^-和A³Ⅱ_u电子态的光谱常数T_e,R_e,ω_e,ω_ex_e,ω_ey_e,B_e,β_e和γ_e.求解双原子分子核运动的径向Schr（o|¨）dinger方程,找到了无转动的同位素分子¹¹B₂（X³Σ_g^-,A³Π_u）和¹⁰B¹¹B（X³∑_g^-,A³Π_u）的全部振动态.针对每一同位素分子的每一振动态,分别计算了其振动能级和惯性转动常数等分子常数,它们均与已有的实验结果较为一致.其中,¹⁰B¹¹B（A^Π_u）分子的光谱常数和分子常数属首次报道.     

72Ge40的低激发态能级研究

用低本底反康谱仪(HpGe–NaI)和HpGe–HpGe的三参数符合γ–γ–T系统,对72Ga的衰变γ单谱、符合谱进行了研究,实验共获得2.3×10⁷个符合事件.根据实验结果建立了含有26个能级、87条γ射线的72Ga的衰变能级纲图,其中包含首次测到7条γ射线225.92、826.97、1349.71、1475.32、1667.91、2105.28、2247.39keV和4个能级3248.01、3396.27、3806.10、3864.56keVS并为2939.83keV能级和112.59、937.97、2402.25、2939.95keV4条γ射线的存在提供了证据;实验没有发现113.5、1155.7、1192.4keVγ射线和能级3307.1keV存在的证据。并把317.72keVγ射线的跃迁,由原来的能级3757.26keV跃迁到3439.51keV能级,改为3565.85keV到3248.01keV能级跃迁.     

一种改进的夜间数字能见度测量方法

为降低背景光噪声对数字摄像法夜间能见度测量的不确定性影响,对双光源法能见度测量系统进行改进。该系统利用避光筒限制CCD相机视场角,拍摄2个位于不同距离的LED背光源,然后对摄取到的图像进行处理得到光源图像的灰度值,再根据阿拉德定律求得大气消光系数,计算出大气能见度值。通过在无背景光、有背景光未加避光筒和加避光筒3种条件下的比对实验,分析光源图像的灰度信息,并将实验结果进行处理,得出有避光筒和无避光筒时测得的能见度值与无背景光下测量结果的相关系数分别是0.911 3和0.322 7,均方根相对偏差分别是6.87% 和23.38%。结果表明:系统抑制背景光噪声的能力明显增强,能较准确地测量夜间能见度。     

Chiral selective tunneling induced graphene nanoribbon switch

An armchair graphene nanoribbon switch has been designed based on the principle of the Klein paradox. The resulting switch displays an excellent on-off ratio performance. An anomalous tunneling phenomenon, in which electrons do not pass through the graphene nanoribbon junction even when the conventional resonance condition is satisfied, is observed in our numerical simulations. A selective tunneling rule is proposed to explain this interesting transport behavior based on our analytical results. Based on this selective rule, our switch design can also achieve the confinement of an electron to form a quantum qubit.      

全无机钙钛矿太阳电池的制备及稳定性

全无机钙钛矿太阳电池因其热稳定性好、载流子迁移率高,可用于制备叠层电池等优点备受关注.随着人们对全无机钙钛矿太阳电池的深入研究和制备工艺的持续优化,全无机钙钛矿太阳电池的光电转换效率已经突破19％.然而,全无机钙钛矿材料相稳定性较差,这使得实现全无机钙钛矿太阳电池在空气环境下制备和长期使用面临巨大挑战.众多科研工作者通...     

Monoterpenoid Indole Alkaloids with Promoting Neurite Growth from Tabernaemontana divaricata

Main observation and conclusion Phytochemical investigations on Tabernaemontana divaricata led to the isolation of seven undescribed monoterpenoid indole alka-l...     

微腔内气体抽离的多尺度模拟与分析

基于适用于整个克努森数范围的流动理论,建立了去除惯性约束聚变实验中靶丸内空气的理论模型,并设计实验验证了此模型的可靠性。物理实验要求靶丸内空气浓度低于10×10⁻⁶,数值模拟了去除靶丸内空气的过程,重点分析了靶丸内空气浓度、压力与除气时间的关系。计算并比较了单管路一次抽气法、单管路循环抽气法与双管路流洗法三种去除靶丸内空气方法的时间成本。数值计算结果表明：单管路一次抽气法中,靶丸上的微通道的存在对去除靶丸内空气所需时间的影响不可忽略,在考虑靶丸上微通道与充气管的情况下,需要1961.77 h才能使靶丸内的空气浓度达到标准。单管路循环抽气法中,抽气次数与单次抽气程度会影响去除靶丸内空气所需总时间,在单次抽气程度值取最优的情况下,采用充三次,抽四次的方案可使达标总时间减少至1 h左右,此方案下单次充气和抽气时间分别为6 min和10 min。而采用双管路流洗法则仅需11 min便可使靶丸内空气浓度达标。