在溴代十六烷基吡啶存在下5-Br-PADAP分光光度法测定水中微量铁的研究

研究了显色剂2-(5-溴-2-吡啶偶氮)-5-二乙氨基酚(简称为5-Br-PADAP)与铁(Ⅱ)显色反应条件,在pH=6.0的醋酸-醋酸钠缓冲体系中,采用阳离子表面活性剂溴代十六烷基吡啶增溶增敏。铁(Ⅱ)与显色剂形成的配合物组成为Fe(Ⅱ)∶R=1∶2,络合物具有两个吸收峰,分别位于λ1=556nm与λ2=748nm。选择748nm进行测定,其摩尔吸光系数为ε748=3.3×104L·mol-1·cm-1。铁含量在0—30μg/25mL范围内服从比耳定律。此法用于水样中微量铁的测定,结果准确可靠。     

直接荧光法和流动注射荧光法测定微量氨的研究

在碱性介质中 ,基于氨与邻苯二甲醛及 2 巯基乙醇反应生成强荧光性吲哚取代衍生物的体系建立测定水溶液中微量氨的直接荧光法和流动注射荧光法。曲通X 10 0 (TritonX 10 0 )对该体系具有良好的增稳作用。在λex=4 15nm ,λem=4 86nm下 ,用直接荧光法测定NH3含量在 0 2～ 1 0 μg·mL- 1 范围内 ,工作曲线的回归方程为ΔI =2 2 2 86 785 71cNH3(μg·mL- 1 ) (I即为Intensity) ,r=0 9995 ;NH3含量在 0 0 2～ 0 10 μg·mL- 1 范围内 ,工作曲线的回归方程为ΔI=- 2 7 4 2 9 2 371 4cNH3(μg·mL- 1 ) ,r=0 996 5。用流动注射法测定的工作曲线的回归方程为ΔI=1188cNH3(μg·mL- 1 ) ,r=0 9998,线性范围为 0～ 0 7μg·mL- 1 ,并对反应机理进行初步探讨。     

A simple pathway to ordered silica nanopattern from self-assembling of block copolymer containing organic silicon block

Self-assembly of block copolymer is an effective strategy to prepare periodic structures at nanoscale. In this paper an unique and very simple method to prepare inorganic silica nanopattern is demonstrated from self-assembling of poly(styrene-block-dimethylsiloxane) (PS-b-PDMS) on the surface of silicon wafer. To simplify the patterning process, at first we obtain highly ordered PDMS microdomains, which are covered with PS layer by controlling solvent vapor annealing conditions. Following exposure to UV/O₃ irradiation, nanopatterned surface consisting of silicon oxide is fabricated directly via selectively etching PS phase and converting PDMS phase into silicon oxide. As tuning the composition of the block copolymer, hexagonally packing dot and straight stripe pattern can be obtained. Finally, the time evolution from spheres morphology to aligned long cylinders is discussed. These results hold promise for nanolithography and the fabrication of nanodevices.     

Room temperature operation of 2-μm microchip Tm,Ho:Lu2SiO5 laser

Room temperature operation of a c-cut microchip Tm,Ho:Lu₂SiO₅ laser end-pumping by a fibercoupled laser-diode is reported. A 4.03 W incident pump power is used to generate a maximum laser output of 98 mW, representing 2.43% optical-to-optical conversion efficiency and a 4.38% slope efficiency corresponding to incident power. In the experiment, the oscillating wavelengths shifting from 2.084 to 2.089 μm has been observed and approximately 10 mW single 2.087 μm wavelength oscillation has been obtained by changing the pump power to 1.43 W and the position of the pump focus.     

最大似然法在HL-2A汤姆逊散射中的初步应用

介绍了一种处理HL-2A汤姆逊散射原始实验数据的新方法--最大似然法。该方法用数理统计的手段,通过使理论推导出的数据与实际采集到的散射数据最大可能的一致,得到了较准确的等离子体电子温度T_e和密度n_e。将计算所得的结果与现在汤姆逊散射系统所用的比值法得到的结果相比较,验证了该方法的可适用性,并能够克服比值法的一些缺陷。     

基于GEANT4的CsI(T1)闪烁体探测器的Monte Carlo模拟

对闪烁光在晶体内的传输以及光电子倍增过程进行了建模,基于GEANT4软件包对CsI(T1)闪烁体探测器进行了蒙特卡罗模拟,得到了不同形状、尺寸和包装的CsI(T1)晶体测量γ射线的能谱.对比模拟和测试结果,两者得到了很好的符合,从而验证了模拟参数的合理性和可靠性.该模拟程序的建立为闪烁体探测器的设计提供了更精确的开发工具.     

Pecularities of change transfer mechanism and dielectric properties of glasses Ag-Sb-S-I

Temperature dependence of electronic and ionic components of electric conductivity and dielectric permittivity of amorphic compounds Ag_0.25Sb_0.25S_0.5, (AgSbS₂)_0.95· (SbSI)_0.05 and (AgSbS₂)_0.9·(SbSI)_0.1 in the temperature range of 290–380 K have been investigated. The experimental data show that glasses investigated are solid electrolytes. Ionic conductivity as well as dielectric permittivity of the glasses Ag-Sb-S may be changed by introduction of SbSI.     

基于红外波段光谱吸收的小型化湿度探测系统

 探测系统的光源选择为垂直腔面发射激光器,选定水汽在1.854 μm的吸收峰。系统自动在直接测量法与谐波测量法之间切换,能够适应高低湿度环境。在低湿度环境检测中,利用二次谐波与一次谐波的比值来定标湿度,有效去除了光源不稳定对测量带来的影响;过采样的A/D转换结合数字锁相放大（DLIA）技术,提高了检测精度。系统通过以太网接口,可以实现远程数据采集。     

Kerr介质中耦合全同∧型三能级原子与真空场相互作用过程中场熵的演化特性

利用量子理论,研究了真空场与耦合全同∧型三能级原子相互作用过程中场熵的演化特性.讨论了系统初始状态、失谐量、原子间偶极相互作用和Kerr系数对场熵演化特性的影响.数值计算结果表明:场熵呈现出周期性振荡,其振荡频率和幅度强烈地依赖于系统的初始状态;失谐量、原子间耦合强度、Kerr系数的增大,都会使场熵振荡的幅度减小.     

锥型热声谐振管内非线性声场的数值模拟研究

从声学角度出发,考虑粘性耗散、非线性效应及管型结构变化的影响,利用伽辽金法,对锥型热声谐振管内的一维声场进行了数值模拟研究,对谐振管结构参数对声场的影响进行了分析,给出了锥型管内压比随谐振管结构参数变化的规律,通过与圆柱型直管的比较,揭示了锥型管在抑制谐波及提高压比等方面的优越性。