表面膨胀粘度的测定研究

用不同浓度的NaCl和表面活性剂直链的十二烷基苯磺酸钠(LAS)、稳定剂聚丙烯酰胺和水所组成的泡沫体系为研究对象,通过表面压松弛的方法,利用计算机数据拟合,得到了计算表面膨胀粘度的方法。     

胶束溶液中高氯酸二水(四胺)合钴(Ⅲ)配合物催化磷酸二酯水解的研究

本文合成了疏水性高氯酸二水（四胺）合钴（Ⅲ）配合物，研究了它与非离子表面活性剂Brij35形成的金属2胶束催化二（对硝基苯酚）磷酸二酯水解的动力学及其机理。结果表明此金属胶束对磷酸二酯水解的速率大约提高10^4倍，这主要是由于表面活性剂胶束的pH效应和浓聚效应所致，暗示着顺式二水类配合物形成的金属胶束是一个潜在的磷酸二酯水解剪切的催化剂。     

液芯光纤光度法在乙醇水溶液中测定铂(Ⅱ)、钛(Ⅳ)

采用氟塑料长光纤管，以４２％乙醇水溶液作液芯，组成液芯光纤，基于铂与氯化亚锡、钛与过氧化氢形成黄色络合物在乙醇水溶液中很稳定，拟定了测定铂、钛的液芯光纤光度法。该法灵敏度高，用 １ｍ长光纤作吸收池，铂的灵敏度为 ４． ８４５ Ａ／ｍｇ· Ｌ－１，钛的灵敏度为１．４１Ａ／ｍｇ· Ｌ－１（Ａ为吸光度），与常规法（１ｃｍ）比色皿相比灵敏度提高了 １００倍。该法测定了催化剂中铂，煤灰粉中钛，结果与推荐值相符。     

Single Atom Alloy Preparation and Applications in Heterogeneous Catalysis

There have been remarkable progresses in manipulating heterogeneous catalysts' nanostructures in the past decade. The concept of single atom alloy (SAA) was firstly proposed in 2012 when researchers successfully stabilized single Pd atoms on the Cu(111) surface. However, earlier work in 2009, which focused on replacing one Au atom with a Pd atom in thiolate protected Au₂₅ nanoclusters, could also be considered as the pioneer work of single atom alloy. Both kinds of single atom alloys exhibited the potential of maximum utilization of scarce elements and attractive catalytic performances. The well‐defined structures of SAA catalysts make accurate modeling possible, which further realizes the rational design of single atom alloy catalysts. In this review, we summarize the research trajectory of single atom alloys as well as recent achievements in this field. We also introduce several commonly adopted characterization methods for SAA catalysts such as scanning tunneling microscopy (STM), temperature programmed reaction (TPR), extended X‐ray absorption fine structure (EXAFS) spectra, matrix assisted laser desorption/ionization mass spectrum (MALDI‐MS) and differential pulse voltammetry (DPV). Through discussing recent progresses in SAA catalysts, we propose that future researches in this filed should be focused on exploring new kinds of metal nanocrystals and controlling the nanostructure of SAA even more precisely.     

足球分子及有关碳笼的电子结构

本文评述了激光气化产生的碳原子簇的电子结构和活性。足球分子具有球面芳香性。我们用INDO/2和INDO/CI系列方法。研究了足球分子及其异构体的电子结构和UV谱。足球分子的计算结果是只有一条低频带(366.4nm),与实验结果(386.0nm)符合得很好。     

锂电池Li／KIBr2—非水体系的研究

本非水电池体系由Ｌｉ负极、多孔石墨电极和电解质溶液组成；电解质溶液由无机溶剂ＰＯＣｌ＿３（或有机溶剂硝基苯）和溶解在该溶剂中的活性物质（ＫＩＢｒ＿２）及支持电解质构成。该电池体系的开路电压为８．５０伏左右，放电性能良好，可望在实际中得到应用。此外，对电池体系的反应机理也作了初步的探讨。     

基于交叉共轭结构的功能材料

近年来,人们对交叉共轭体系的制备、性能以及理论研究方面产生了极大的兴趣。本文综述了近期国内外在交叉共轭体系研究方面取得的一些最新进展,重点介绍了其在自组装、有机电致发光和离子检测等方面的最新发展动态。最后还对本课题组在交叉型p-n双嵌段寡聚物方面的研究作了详细的介绍,并对一些热点问题作了展望。     

从蓖麻油制取10-羟基癸酸的研究

本文报道了从蓖麻油制取10-羟基癸酸的研究,发现了从蓖麻油制取10-羟基癸酸的新的工艺路线和最佳的工艺条件,用氢氧化钠用量、2-辛醇量、反应时间和反应温度四因子三水平L_9(3~4)进行了正交试验,发现最佳工艺条件是:氢氧化钠(g)/蓖麻油(g):1.25:2-辛醇量(g)/蓖麻油(g):2:反应时间:6h;反应温度:180℃。在这一新的工艺路线和最佳工艺条件下,10-羟基癸酸产率可达75％。     

Decomposition of Transformer Oil Under Ultrasonic Irradiation During Degassing Process

In the degassing process of transformer oil with ultrasonic waves ,decompostition of the oil was observed.Light hydrocarbons,including methane,ethane,ethylene ,aceylene,propane etc,were found to be released continuously from the oil into headspace within a closed vial placed in an ultrasonic field ,The gases came from decomposition of hydrocarbon molecules under cavitation effect.     

无水醋酸镍与水杨醛肟固相配位反应的热化学研究

用新型的具有恒定温度环境的反应热量计，以６ｍｏｌ·ｄｍ－３ＨＣｌ溶液为量热溶剂，分别测定了ＨＳＡＯ，Ｎｉ（Ａｃ）２和Ｎｉ（ＳＡＯ）２，ＨＡｃ先后溶于该溶剂的溶解焓．设计了一个新的热化学循环，计算得到该配位反应的反应焓ΔｒＨ＝－８６．０７５ｋＪ·ｍｏｌ－１，并估算出了ΔｆＨ［Ｎｉ（ＳＡＯ）２，２９８Ｋ］＝－４０１．３３６ｋＪ·ｍｏｌ－１．