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排序方式: 共有198条查询结果,搜索用时 0 毫秒
51.
Zhang Xiaoguang Yu Zhongyuan Lin Ning Liu Xiumin 《Optical and Quantum Electronics》2001,33(11):1173-1180
Gain-switched distributed feedback laser diodes (GS-DFB-LD) with high repetition bit rate have large frequency chirp. Conventionally, the F–P spectrum filter and normal dispersion fiber were used to eliminate chirp in GS-DFB-LD pulse sources. In this paper, a new method for eliminating chirp of high repetition pulses generated from DFB laser diodes is proposed. The use of a linearly chirped fiber grating for chirp elimination is discussed theoretically and numerically. A new apodized coupling profile function for the grating, which we call it the inverse Gaussian, is given. Its characteristics are analyzed and compared with other profiles. The numerical results are in agreement with the theoretical analysis. 相似文献
52.
In this Letter, the plastic relaxation introduced by typical 60° mixed dislocation in zinc‐blende axial nanowire (NW) heterostructures is evaluated by numerical Peach–Koehler approach which reflects the interaction between coherent strain field and misfit dislocation. Cylindrical NW epilayers grown on NW and bulk substrate are separately modeled. We reveal that straight 60° dislocation with Burgers vector (a /2) 〈101〉 would always generate at NW center orienting [111], while aspect ratio dependent off‐center equilibrium position should be expected for NW epilayer along [001]. Moreover, the critical diameters, below which coherency is maintained, are predicted based on energy balance criterion for axial NW heterostructures along predominating growth direction [111]. The results are compared with existing theory and experimental observations. Our work provides a necessary quantitative complement to the understanding of plastic relaxation and coherency limit in axial NW heteroepitaxy. (© 2014 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim) 相似文献
53.
Zhao Z Xu B Zhou XF Wang LM Wen B He J Liu Z Wang HT Tian Y 《Physical review letters》2011,107(21):215502
A novel carbon allotrope of C-centered orthorhombic C(8) (Cco-C(8)) is predicted by using a recently developed particle-swarm optimization method on structural search. Cco-C(8) adopts a sp(3) three-dimensional bonding network that can be viewed as interconnected (2,2) carbon nanotubes through 4- and 6-member rings and is energetically more favorable than earlier proposed carbon polymorphs (e.g., M carbon, bct-C(4), W carbon, and chiral C(6)) over a wide range of pressures studied (0-100 GPa). The simulated x-ray diffraction pattern, density, and bulk modulus of Cco-C(8) are in good accordance with the experimental data on structurally undetermined superhard carbon recovered from cold compression of carbon nanotube bundles. The simulated hardness of Cco-C(8) can reach a remarkably high value of 95.1 GPa, such that it is capable of cracking diamond. 相似文献
54.
Zhennan Wu Dr. Yanchun Li Jiale Liu Prof. Zhongyuan Lu Prof. Hao Zhang Prof. Bai Yang 《Angewandte Chemie (International ed. in English)》2014,53(45):12196-12200
Metal nanoclusters (NCs) with diameter below 2 nm are promising catalysts in oxygen reduction reactions (ORR). However, the high surface energy of ultra‐small clusters leads to structural instability, shedding doubt on practical applications. Herein, we demonstrate a self‐assembly method to improve the durability of catalytic metal NCs, employing copper NCs capped by 1‐dodecanethiol (DT) to form free‐standing ribbons in colloidal solution. By tuning the cooperation between the dipolar attraction between Cu NCs and the van der Waals attraction between DT, the thickness of ribbons is adjusted to a single NC scale. Such free‐standing ribbons exhibit excellent catalytic activity and durability in ORR. 相似文献
55.
Shuyun Zhu Xian-en Zhao Wei Zhang Zhongyuan Liu Wenjing Qi Saima Anjum Guobao Xu 《Analytica chimica acta》2013
Fluorescent silver nanoclusters stabilized by DNA (DNA-AgNCs) exhibit distinct response rates to thiol and disulfide. Glutathione reductase can catalyze the reduction of the oxidized glutathione (GSSG) quickly to reduced glutathione (GSH) in the presence of β-nicotinamide adenine dinucleotide 2′-phosphate reduced tetrasodium salt hydrate (NADPH). Consequently, DNA-AgNCs can serve as a new fluorescent platform for assaying the glutathione reductase (GR) activity. This newly proposed assay has a high sensitivity and a good selectivity toward GR. The GR activity can be detected in the range of 0.2–2.0 mU mL−1 with a minimum detectable concentration of 0.2 mU mL−1. Pepsin, lysozyme, trypsin, avidin, thrombin, myoglobin, and BSA have little effect on the fluorescence intensity of DNA-AgNCs. The GR activity assay is successfully used to monitor the inhibition of GR activity by a typical inhibitor 1,3-bis(2-chloroethyl)-1-nitrosourea. 相似文献
56.
57.
讨论了原子参数的精度对复合泵浦激光增益系数的影响,同时对复合泵浦激光研究中常用的各种原子数据进行了评价。 相似文献
58.
Hongyan Wang Renguo Lv Zhongyuan Huang Pei Liu Peihong Cong 《Journal of Macromolecular Science: Physics》2016,55(1):85-98
Fluorine atoms were introduced into the molecular chain of a phenolic resin (PR) by a two-step acid synthesis process to improve its thermal and hydrophobic properties. The successful synthesis of a fluorinated phenolic resin/phenolic resin blend (F-PR/PR) was proven by Fourier transform infrared spectroscopy (FTIR) and nuclear magnetic resonance 19F (19F-NMR). The thermal properties of F-PR/PR were analyzed by differential scanning calorimetry (DSC) and thermo gravimetric analysis (TGA) and the results indicate that the F-PR/PR had good thermal stability. The hydrophobic properties of PR were effectively modified as demonstrated by the water drop contact angles. The flexural and tribological properties of F-PR/PR were also investigated. The fluorine atom, by virtue of its electronegativity, size and bond strength with carbon, can be used to create composites from F-PR/PR with remarkable properties. For comparison, two other resin blends were also synthesized. 相似文献
59.
Glutamic acid cation based ionic liquids: microwave synthesis, characterization, and theoretical study 总被引:2,自引:0,他引:2
Some new members of amino acid ionic liquids (ILs) with glutamic acid (Glu) cation were studied. GluBF4, GluCl, GluNO3, and Glu2SO4 were synthesized using the one-step microwave synthesis method, and their physicochemical properties, including the IR spectrum, melting point, conductivity, solubility, and thermostability, were investigated in detail experimentally. Systematic theoretical study on the series molecules were also performed by quantum chemistry calculation. Geometry optimization on the single molecule was carried out with the B3LYP/6-311++G** level of theory, and the vibration frequencies of each optimized molecule were analyzed at the same level. The binding energies were calculated, and the basis set superposition error (BSSE) was corrected by the counterpoise method (CP). A close relation between the experimental melting points and the intramolecular interaction was found: the smaller the absolute value of the biding energy between ions is, the lower the melting point would be. This conclusion shows the probability of designing ILs with the help of theoretical way in the future exploitation. 相似文献
60.
We introduce a reaction model for use in coarse-grained simulations to study the chemical reactions in polymer systems at
mesoscopic level. In this model, we employ an idea of reaction probability in control of the whole process of chemical reactions.
This model has been successfully applied to the studies of surface initiated polymerization process and the network structure
formation of typical epoxy resin systems. It can be further modified to study different kinds of chemical reactions at mesoscopic
scale. 相似文献