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51.
In this article, we deal with the global existence and nonexistence of solutions to the non-Newtonian polytropic filtration equations coupled with nonlinear boundary conditions. By constructing various kinds of sub- and super-solutions and using the basic properties of M-matrix, we give the necessary and sufficient conditions for global existence of nonnegative solutions. The critical curve of Fujita type is conjectured with the aid of some new results, which extend the recent results of Zheng, Song, and Jiang [Critical Fujita exponents for degenerate parabolic equations coupled via nonlinear boundary flux, J. Math. Anal. Appl. 298 (2004), pp. 308–324], Zhou and Mu [Critical curve for a non-Newtonian polytropic filtration system coupled via nonlinear boundary flux, Nonlinear Anal. 68 (2008), pp. 1–11], and Zhou and Mu [Algebraic criteria for global existence or blow-up for a boundary coupled system of nonlinear diffusion equations, Appl. Anal. 86 (2007), pp. 1185–1197] to more general equations. 相似文献
52.
This article deals with the critical curve of a fast diffusive polytropic filtration system coupled at the boundary condition. By constructing the self-similar supersolution and subsolution, we obtain the critical global existence curve. The critical curve of Fujita type is conjectured with the aid of some new results. 相似文献
53.
Dr. Adrian Ortiz Dr. Tamas Benkovics Dr. Gregory L. Beutner Dr. Zhongping Shi Dr. Michael Bultman Dr. Jeffrey Nye Dr. Chris Sfouggatakis Dr. David R. Kronenthal 《Angewandte Chemie (International ed. in English)》2015,54(24):7185-7188
Described herein is the synthesis of BMS‐986001 by employing two novel organocatalytic transformations: 1) a highly selective pyranose to furanose ring tautomerization to access an advanced intermediate, and 2) an unprecedented small‐molecule‐mediated dynamic kinetic resolution to access a variety of enantiopure pyranones, one of which served as a versatile building block for the multigram, stereoselective, and chromatography‐free synthesis of BMS‐986001. The synthesis required five chemical transformations and resulted in a 44 % overall yield. 相似文献
54.
Shang S Tan Z Dong S Danishefsky SJ 《Journal of the American Chemical Society》2011,133(28):10784-10786
Native chemical ligation (NCL) is widely applicable for building proteins in the laboratory. Since the discovery of this method, many strategies have been developed to enhance its capability and efficiency. Because of the poor reactivity of proline thioesters, ligation at a C-terminal proline site is not readily accomplished. Here, we demonstrate that ligation at an N-terminal protein is feasible using the combined logic of NCL and metal-free dethiylation (MFD). 相似文献
55.
56.
Zhongping Huang Chengzhu Ni Fengli Wang Zuoyi Zhu Qamar Subhani Muhua Wang Yan Zhu 《Journal of separation science》2014,37(3):198-203
The application of ion chromatography with the column‐switching technique for the simultaneous analysis of peroxydisulfate and conventional inorganic anions in a single run is described. With this method, conventional inorganic anions were separated by consecutive elution through both the guard column and separation column, but peroxydisulfate that only passed through the guard column had a good peak shape and short retention time. A series of standard solutions consisting of target anions of various concentrations from 0.01 to 75 mg/L were analyzed, with a correlation coefficient (r) ≥ 0.9990. The limits of detection were in the range of 0.49–9.84 μg/L based on the S/N of 3 and a 25 μL injection volume. RSDs for retention time, peak area, and peak height were all <1.77%. A spiking study was performed with satisfactory recoveries between 97.6 and 103.4% for all anions. The quantitative determination of peroxydisulfate and conventional inorganic anions in surface waters was accomplished within 18 min by this column‐switching technique. 相似文献
57.
This review discussed recent advancements related to therapeutic peptide engineering. 相似文献
58.
制备出一种新型抑制电导检测阴离子色谱固定相,通过对色谱条件的选择,成功实现了多种含磷阴离子的分离。选用KOH溶液作为流动相,成功分离并测定正磷酸根、焦磷酸根、三偏磷酸根和三聚磷酸根,且线性良好,方法的加标回收率达到90%～106%。用于实际样品分析,结果满意。 相似文献
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