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31.
Selective Hydroarylation of 1,3‐Diynes Using a Dimeric Manganese Catalyst: Modular Synthesis of Z‐Enynes
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Zhongfei Yan Prof. Dr. Xiang‐Ai Yuan Dr. Yue Zhao Prof. Dr. Chengjian Zhu Prof. Dr. Jin Xie 《Angewandte Chemie (International ed. in English)》2018,57(39):12906-12910
The transition‐metal‐catalyzed selective hydroarylation of unsymmetrical alkynes represents the state‐of‐art in organic chemistry, and still mainly relies on the use of precious late‐transition‐metal catalysts. Reported herein is an unprecedented MnI‐catalyzed hydroarylation of unsymmetrical 1,3‐diyne alcohols with commercially available arylboronic acids with predictive selectivity. This method addresses the challenges in regio‐, stereo‐, and chemoselectivity. It offers a general, convenient and practical strategy for the modular synthesis of multisubstituted Z‐configurated conjugated enynes. This protocol is distinguished by its operational simplicity, complete selectivity, excellent functional‐group compatibility, and gram‐scale potential. A dimeric MnI species, Mn2(CO)8Br2, was proven to be a much more efficient catalyst precursor than Mn(CO)5Br. 相似文献
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This paper solves an optimal portfolio selection problem in the discrete‐time setting where the states of the financial market cannot be completely observed, which breaks the common assumption that the states of the financial market are fully observable. The dynamics of the unobservable market state is formulated by a hidden Markov chain, and the return of the risky asset is modulated by the unobservable market state. Based on the observed information up to the decision moment, an investor wants to find the optimal multi‐period investment strategy to maximize the mean‐variance utility of the terminal wealth. By adopting a sufficient statistic, the portfolio optimization problem with incompletely observable information is converted into the one with completely observable information. The optimal investment strategy is derived by using the dynamic programming approach and the embedding technique, and the efficient frontier is also presented. Compared with the case when the market state can be completely observed, we find that the unobservable market state does decrease the investment value on the risky asset in average. Finally, numerical results illustrate the impact of the unobservable market state on the efficient frontier, the optimal investment strategy and the Sharpe ratio. Copyright © 2016 John Wiley & Sons, Ltd. 相似文献
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Yue Sun Zhongfei Gao Chunhua Wang Guige Hou 《Acta Crystallographica. Section C, Structural Chemistry》2019,75(8):1157-1165
Two fluorine‐substituted 1,4,5,6‐tetrahydrobenzo[h]quinazolin‐2‐amine (BQA) derivatives, namely 2‐amino‐4‐(2‐fluorophenyl)‐9‐methoxy‐1,4,5,6‐tetrahydrobenzo[h]quinazolin‐3‐ium chloride, ( 8 ), and 2‐amino‐4‐(4‐fluorophenyl)‐9‐methoxy‐1,4,5,6‐tetrahydrobenzo[h]quinazolin‐3‐ium chloride, ( 9 ), both C19H19FN3O+·Cl?, were generated by Michael addition reactions between guanidine hydrochloride and the α,β‐unsaturated ketones (E)‐2‐(2‐fluorobenzylidene)‐7‐methoxy‐3,4‐dihydronaphthalen‐1(2H)‐one, C18H15FO2, ( 6 ), and (E)‐2‐(4‐fluorobenzylidene)‐7‐methoxy‐3,4‐dihydronaphthalen‐1(2H)‐one, ( 7 ). Because both sides of α,β‐unsaturated ketones ( 6 ) or ( 7 ) can be attacked by guanidine, we obtained a pair of isomers in ( 8 ) and ( 9 ). Single‐crystal X‐ray diffraction indicates that each isomer has a chiral C atom and both ( 8 ) and ( 9 ) crystallize in the achiral space group P21/c. The chloride ion, as a hydrogen‐bond acceptor, plays an important role in the formation of multiple hydrogen bonds. Thus, adjacent molecules are connected through intermolecular hydrogen bonds to generate a banded structure. Furthermore, these bands are linked into an interesting 3D network via hydrogen bonds and π–π interactions. Fortunately, the solubilities of ( 8 ) and ( 9 ) were distinctly improved and can exceed 50 mg ml?1 in water or PBS buffer system (pH 7.4) at room temperature. In addition, the results of an investigation of anti‐inflammatory activity show that ( 8 ) and ( 9 ), with o‐ and p‐fluoro substituents, respectively, display more potential for inhibitory effects on LPS‐induced NO secretion than starting ketones ( 6 ) and ( 7 ). 相似文献
35.
Guifang Ju Yihua Hu Li Chen Xiaojuan Wang Zhongfei Mu Haoyi Wu Fengwen Kang 《Journal of luminescence》2012,132(8):1853-1859
The spectroscopic characterization of yttria, singly and doubly doped with Ln3+ (Ln=Sm, Eu, Dy, Er, Ho) and Bi3+ ions, is performed through excitation spectra, emission spectra and decay time measurements. The obtained spectroscopic data clearly indicate that energy transfer takes place from Bi3+ to Ln3+ ions. The energy transfer efficiency of Bi3+→Ln3+ and quantum efficiency of Ln3+ were calculated. Upon excitation of 370 nm (Bi3+ excitation band), the quantum efficiency of Ln3+ varies from ~4% to ~44%. The energy transfer efficiency increases continuously with increasing Ln3+ concentrations, whereas the variation of the quantum efficiency of Ln3+ is complicated. The quantum efficiency of Ln3+ is discussed in terms of electron transfer and cross relaxation. 相似文献
36.
This paper proposes a unified framework to solve distributionally robust mean-risk optimization problem that simultaneously uses variance, value-at-risk (VaR) and conditional value-at-risk (CVaR) as a triple-risk measure. It provides investors with more flexibility to find portfolios in the sense that it allows investors to optimize a return-risk profile in the presence of estimation error. We derive a closed-form expression for the optimal portfolio strategy to the robust mean-multiple risk portfolio selection model under distribution and mean return ambiguity (RMP). Specially, the robust mean-variance, robust maximum return, robust minimum VaR and robust minimum CVaR efficient portfolios are all special instances of RMP portfolios. We analytically and numerically show that the resulting portfolio weight converges to the minimum variance portfolio when the level of ambiguity aversion is in a high value. Using numerical experiment with simulated data, we demonstrate that our robust portfolios under ambiguity are more stable over time than the non-robust portfolios. 相似文献
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现实中,保险公司的投资行为会受到《保险法》及其自身风险管理条例的约束; 另外,保险公司必须提存一定数量的准备金以满足监管规定.鉴于此,本文将保险公司盈余首达最低准备金水平的时刻定义为``破产”时刻,以最小化``破产”概率为目标, 假设保险公司的盈余过程服从扩散模型,其可投资无风险资产与一种风险资产且投资受线性约束.我们通过求解相应的HJB方程得到了值函数与最优投资策略的解析式并给出了经济解释与数值算例. 相似文献
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In the present paper, phosphors with the composition Y3−x−yAl5O12:Bi3+x, Dy3+y were synthesized with solid state reactions. The luminescence properties of Bi3+ and Dy3+ in Y3Al5O12(YAG) and the energy transfer from Bi3+ to Dy3+ were investigated in detail. Bi3+ in YAG emits one broad band peaking at 304 nm which can be ascribed to the transition from excited states 3P0, 1 to ground state 1S0. Dy3+ in YAG emits two groups of peaks around 484 and 583 nm, respectively, which can be ascribed to the transitions from excited state 4F9/2 to ground states 6H15/2 and 6H13/2. The co-doping of Bi3+ enhances the luminescent intensity of Dy3+ by ∼7 times because Bi3+ can transfer the absorbed energy to Dy3+ efficiently. The mechanism of energy transfer was also discussed. 相似文献
39.
Zhongfei Mu Yihua Hu Haoyi WuChujun Fu Fengwen Kang 《Physica B: Condensed Matter》2011,406(4):864-868
A series of phosphors with the composition Y3MnxAl5−2xSixO12 (x=0, 0.05, 0.1, 0.15, 0.2, 0.3, 0.4, 0.5, 0.6) was prepared through solid state reactions. X-ray powder diffraction analysis of samples shows that when co-doping content does not exceed 16% of Al3+, equimolar co-doping of Mn2+ and Si4+ does not change the garnet structure of phosphors, but makes the interplanar distance to decrease a certain extent. However, if the co-doping content exceeds 16%, new phases will form in the samples. The excitation and emission spectra of samples show that Mn2+ in Y3MnxAl5−2xSixO12 emits broadband orange light (peak wavelength varies from 586 to 593 nm). With an increment in co-doping content, the emission intensity of the phosphors increases when the value of x is lower than 0.1 while it decreases when it is higher than 0.1 and the emission peak moves to a longer wavelength. 相似文献