光栅不理想特性对不同调制码型的光传输系统的影响

分析了光纤光栅不理想特性的产生机理，对以啁啾光纤光栅为色散补偿器的10Gb/s光传输系统中，啁啾光纤光栅的不理想特性包括群时延纹波、反射纹波及光栅通带带宽对采用归零码(RZ)、非归零码(NRZ)以及载波抑制归零码(CSRZ)三种调制格式传输系统性能的影响进行了详细的数值分析和比较. 同时进行了基于光纤光栅色散补偿的1500km无误码传输实验，通过对啁啾光纤光栅由于不理想特性的差别而导致对实际传输系统不同信道性能影响的比较，进一步验证了仿真分析的正确性. 关键词： 光传输 啁啾光纤光栅 不理想特性 调制码型     

β-环糊精与N,N′-二(4-吡啶基甲基)-1,6-己二胺自组装包结行为的研究

以4-吡啶甲醛和1,6-己二胺为原料,合成了含吡啶基的还原双席夫碱客体N,N′-二(4-吡啶基甲基)-1.6-己二胺(C6N4),通过核磁共振技术研究了β-环糊精与C6N4的自组装包结作用,测定了包结比和稳定常数．结果表明,β-环糊精与客体C6N4在水溶液中形成1∶1的包结配合物,其稳定常数的平均值为1．7×102dm3·mol-1．     

冷热联供的空气制冷不可逆循环分析

本文分析了压气机排气余热利用的冷热联供回热空气制冷不可逆循环,并建立了仅忽略系统内所有换热器流动阻力损失的循环工作性能系数(COP)计算方程式。用该方程分析研究了透平膨胀机与压气机等熵效率、压缩机排气余热度、降温比、传热温差、压比等参数对系统COP值的影响,发现膨胀透平等熵效率提高对COP值的贡献远大于压气机效率同样提高的功效;在其它参数确定时,存在最佳压比,可使系统工作性能系数在该条件下达极值。在优化参数配置下,用于空气调节的冷热联供回热空气制冷不可逆循环的COP值可达2左右。     

Growth, Antimony Incorporation Behaviour and Beryllium Doping of GaAs1-ySby Grown on GaAs by Molecular Beam Epitaxy

A series of GaAs1-ySby epilayers are grown on GaAs substrates under antimony compositions of samples with beryllium doping are obtained different growth conditions. Different A non-equilibrium thermodynamics model is used to calibrate and fit the Sb composition. Activation energy of 0.37 eV for the dissociation process of Sb4 molecules is obtained. Carrier mobility and concentration of samples are influenced by the Sb composition. Quasi-qualitative analysis of mobility is used to explain the relations among Sb composition, carrier mobility and concentration. High resolution x-ray diffraction （HRXRD） rocking curves and Hall effects measurements are used to determine the crystal quality, carrier mobility and concentration.     

氢氟烃二元混合工质的组分分析

气相色谱法是最常用的混合工质组元浓度分析方法。针对氢氟烃二元混合物的特点,本文搭建了气相色谱法混合工质组分分析实验台,测定了9种氢氟烃二元混合物组元质量分数与峰面积百分比的对应关系。讨论了气相色谱法混合工质组分分析的理论方法,比较了2种标准曲线函数模型对实验数据的再现精度,本文提出的校正因子为变量的模型对实验数据的再现性较好,平均绝对偏差小于±0.25%,满足热物性研究对混合物组元成分分析的实验要求。     

反式十氢萘类液晶的合成

以6-烷基-2-十氢萘酮为原料, 经格氏试剂与羰基的加成、脱水、还原及异构化合成系列反式十氢萘类单体液晶 1～12, 产率9.9%～80.8%, 2, 3的产率高于文献值. 结构经过IR, ¹³C NMR, MS鉴定, 并探讨了化合物的相变行为特点和碱催化条件下十氢萘构象异构化的历程.     

长链烷氧取代金属卟啉的合成及催化性能研究

本文报道了一类长链烷氧取代金属卟啉化合物3的合成。研究了由化合物3与表面活性剂:十二烷基三甲基溴化铵所形成的混合胶柬体系作为仿细胞色素P-450加氧酶模拟物对苯乙烯环氧化的催化活性。结果表明:在胶束体系中长链烷氧取代金属卟啉的催化效率优于简单对称四甲苯基金属卟啉,由此证实:混合胶束中,疏水内核提供的模拟酶的疏水微环境,在苯乙烯环氧化反应中起着重要作用。     

Synthesis,crystal structure,and ESR study of a novel phosphorylated lipophilic spin trap

In this article, the synthesis of a novel alpha-phosphorus-containing spin trap DEPPEPO [2-(diethoxyphosphoryl)-2-phenethyl-3,4-dihydro-2H-pyrrole-1-oxide] and the evaluation of its ability to spin-trap radicals, especially superoxide and hydroxyl radicals, are described. Single crystal X-ray structure analysis reveals that there exist a lot of intramolecular nonbonded attractive interactions in the molecule. The phenethyl group is located away from the diethoxyphosphoryl group and the nitronyl plane, and only one face of the nitronyl plane is sterically hindered by the oxygen attached to the phosphorus with a double bond. The latter feature is responsible for the stereoselection of the free radical additions on the nitronyl moiety. The ability of DEPPEPO to trap the active superoxide anion radical generated in the HX/XO system and the stability of their spin adduct were investigated with that for DEPMPO. The half-life of DEPPEPO is about 13.4 min, and as a result, the DEPPEPO seems to be a promising lipophilic spin trap, perhaps in both in vitro and in vivo ESR investigation. Because DEPPEPO is a solid compound, it is quite easy to purify by recrystallization and to store the compound even at room temperature. In addition, an obvious increase in lipophilicity for DEPPEPO was found as a contribution of 2-substituted phenethyl.     

取代苄基瞵酸脂与取代苯甲醛反应的动力学研究

本文报导几种中等活性的瞵酸脂与各种取代苯甲醛反应的动力学研究, 并考查了中等活性的瞵酸脂组分及中等活性的醛组分上不同取代对反应速度的影响。     

Arm effects of mononuclear armed cyclen copper complexes on DNA cleavage

Novel cyclen copper(II) complexes appending different side arms were synthesized as DNA cleavage agents. Both the intermediates and mononuclear complexes were characterized by ¹H NMR, ESI-HRMS, Elemental analyses and IR, and their catalytic activities for DNA cleavage and DNA binding abilities were investigated. The results indicate that the copper(II) complexes could catalyze the cleavage of supercoiled DNA (pUC 19 plasmid DNA) under physiological conditions to produce nicked DNA with high yields (nearly 100%) via an oxidative mechanism in the absence of exogenous agents; The copper complex bearing an 9-anthryl group gave superior DNA interactions to those bearing phenyl or methyl groups.