全文获取类型
收费全文 | 18984篇 |
免费 | 3147篇 |
国内免费 | 2490篇 |
专业分类
化学 | 13734篇 |
晶体学 | 163篇 |
力学 | 1321篇 |
综合类 | 171篇 |
数学 | 2174篇 |
物理学 | 7058篇 |
出版年
2024年 | 67篇 |
2023年 | 433篇 |
2022年 | 589篇 |
2021年 | 714篇 |
2020年 | 791篇 |
2019年 | 722篇 |
2018年 | 572篇 |
2017年 | 545篇 |
2016年 | 921篇 |
2015年 | 812篇 |
2014年 | 983篇 |
2013年 | 1380篇 |
2012年 | 1687篇 |
2011年 | 1636篇 |
2010年 | 1184篇 |
2009年 | 1093篇 |
2008年 | 1222篇 |
2007年 | 1057篇 |
2006年 | 972篇 |
2005年 | 887篇 |
2004年 | 721篇 |
2003年 | 652篇 |
2002年 | 656篇 |
2001年 | 561篇 |
2000年 | 452篇 |
1999年 | 499篇 |
1998年 | 400篇 |
1997年 | 359篇 |
1996年 | 384篇 |
1995年 | 313篇 |
1994年 | 266篇 |
1993年 | 219篇 |
1992年 | 171篇 |
1991年 | 142篇 |
1990年 | 127篇 |
1989年 | 80篇 |
1988年 | 83篇 |
1987年 | 61篇 |
1986年 | 57篇 |
1985年 | 48篇 |
1984年 | 23篇 |
1983年 | 22篇 |
1982年 | 22篇 |
1981年 | 17篇 |
1980年 | 9篇 |
1979年 | 4篇 |
1974年 | 1篇 |
1957年 | 4篇 |
1936年 | 1篇 |
排序方式: 共有10000条查询结果,搜索用时 15 毫秒
51.
52.
Xiu‐Li Wang Ke‐Ke Yang Yu‐Zhong Wang Zhi‐Xuan Zhou Yong‐Dong Jin 《Journal of polymer science. Part A, Polymer chemistry》2004,42(14):3417-3422
A new biodegradable starch graft copolymer, starch‐g‐poly(1,4‐dioxan‐2‐one), was synthesized through the ring‐opening graft polymerization of 1,4‐dioxan‐2‐one onto a starch backbone. The grafting reactions were conducted with various 1,4‐dioxan‐2‐one/starch feed ratios to obtain starch‐g‐poly(1,4‐dioxan‐2‐one) copolymers with various poly(1,4‐dioxan‐2‐one) graft structures. The microstructure of starch‐g‐poly(1,4‐dioxan‐2‐one) was characterized in detail with one‐ and two‐dimensional NMR spectroscopy. The effect of the feed composition on the resulting microstructure of starch‐g‐poly(1,4‐dioxan‐2‐one) was investigated. © 2004 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 42: 3417–3422, 2004 相似文献
53.
本文得到了正定Hermitian阵的Hadamard积的Schur补的一些不等式,进而,给出了他们的一些应用,这些改进了近期的一些结束. 相似文献
54.
原子吸收法在有机分析中的应用(Ⅵ)香烟中氢氰酸的分析 总被引:3,自引:0,他引:3
原子吸收法在有机分析中的应用(Ⅵ)香烟中氢氰酸的分析谢志海,郎惠云,高云(西北大学化学系,西安,710069)关键词:氢氰酸,测定,原子吸收光谱香烟中的尼古丁,烟焦油等含氮有机物燃烧后将产生氢氰酸,吸入人体后极为有害。国外在这方面的研究始于七十年代,... 相似文献
55.
Measurement of small-signal and large-signal responses of packaged laser modules at high temperature
Ning Hua Zhu Ji Min Wen Hai Peng Song Shang Jian Zhang Liang Xie 《Optical and Quantum Electronics》2006,38(15):1245-1257
In this paper, the pulsed injection method is extended to measure the chip temperature of various packaged laser modules,
such as the DFB laser modules, the FP laser modules, and the EML laser modules. An optimal injection condition is obtained
by investigating the dependence of the lasing wavelength on the width and period of the injection pulse in a relatively wide
temperature range. The small-signal frequency responses and large-signal performances of packaged laser modules at different
chip temperature are measured. The adiabatic small-signal modulation characteristics of packaged LD are first extracted. In
the large-signal measurement, the effects of chip temperature, bias current and driving signal on the performances of the
laser modules are discussed. It has been found that the large-signal performances of the EML modules depend on the different
red-shift speeds of the DFB and EAM sections as chip temperature varying, and the optimal characteristics may be achieved
at higher temperature. 相似文献
56.
Peng Xu Haitao Wang Rui Lv Qiangguo Du Wei Zhong Yuliang Yang 《Journal of polymer science. Part A, Polymer chemistry》2006,44(12):3911-3920
A novel microphase‐inversion method was proposed for the preparation of TiO2–SiO2/poly(methyl methacrylate) core–shell nanocomposite particles. The inorganic–polymer nanocomposites were first synthesized via a free‐radical copolymerization in a tetrahydrofuran solution, and the poor solvent was added slowly to induce the microphase separation of the nanocomposite and result in the formation of nanoparticles. The average particle sizes of the microspheres ranged from 70 to 1000 nm, depending on the reaction conditions. Transmission electron microscopy and scanning electron microscopy indicated a core–shell morphology for the obtained microspheres. Thermogravimetric analysis and X‐ray photoelectron spectroscopy measurements confirmed that the surface of the nanocomposite microspheres was polymer‐rich, and this was consistent with the core–shell morphology. The influence of the synthetic conditions, such as the inorganic composition and the content of the crosslinking monomer, on the particle properties was studied in detail. © 2006 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 44: 3911–3920, 2006 相似文献
57.
Activated carbon fiber (ACF) as extraction fiber for solid-phase microextraction (SPME) and its application for the analysis of banned organochlorine pesticides (OCPs) were investigated. Firstly, ACF was activated by different concentration of zinc chloride, which indicated that ACF activated by 60% zinc chloride had a reasonable specific surface area, pore volume and pore distribution. Secondly, the parameters for the ACF-SPME procedure, the adsorption and desorption conditions, were also optimized when coupled with gas chromatography-mass spectrometry (GC-MS). Thirdly, the ACF-SPME was used to analyze 17 kinds of OCPs in water. The linearity of most pesticides was found to be between 0.2 and 50 microg/l with GC-MS under the selected ion monitoring (SIM) acquisition mode. The limits of detection (LOD) at the sub microg/l were obtained. The work demonstrated here shows that ACF is a promising alternative for the SPME procedure. 相似文献
58.
This article will combine the finite element method, the interpolated coefftcient finite element method, the eigenfunction expansion method, and the search-extension method to obtain the multiple solutions for semilinear elliptic equations. This strategy not only grently reduces the expensive computation, but also is successfully implemented to obtain multiple solutions for a class of semilinear elliptic boundary value problems with non-odd nonlinearity on some convex or nonconvex domains. Numerical solutions illustrated by their graphics for visualization will show the efficiency of the approach. 相似文献
59.
X.L. Zhong 《Applied Surface Science》2006,253(2):417-420
Bi3.25La0.75Ti3O12 (BLT) thin films were fabricated on Pt/Ti/SiO2/Si(1 0 0) substrates by chemical solution deposition (CSD), and the dependence of ferroelectric and dielectric properties of the as-deposited BLT thin films on excess Bi content in precursor sols was studied. It is found that the prepared BLT thin film shows the best polarization-electric field, capacitance-voltage and dielectric constant (?r)-frequency characteristics, when the value of excess Bi content in precursor sols is 10%. In detail, its remnant polarization (2Pr) value is 40 μC/cm2, the capacitance tunability is 21% measured at room temperature under conditions of an applied voltage of 8 V and measurement frequency of 10 kHz, and the ?r is 696 at 100 kHz frequency. 相似文献
60.
A three-body system of identical particles is considered in order to demonstrate that the quantum-mechanical symmetry plays
a decisive role in determining microscopic structures.
Received March 14, 1994; revised July 29, 1994; accepted for publication October 19, 1994 相似文献