Spectroscopic Diagnostics of Atmospheric Argon Microwave Plasma Based on an Inductive Coupling Window-Rectangular Resonator

We present a novel microwave plasma source based on an inductive coupling window-rectangular resonator. A definite volume of atmospheric argon microwave plasma is excited in the source under the input of several kilowatts of microwave power operating at 2.45 0Hz. The excitation temperature and electron temperature of the argon plasma are separately researched by using Boltzmann plot and line-to continuum intensity ratio of Ar I spectral lines. Its electron density is inferred from the Stark broadening of the Hβ line at 486.13nm.     

ZSM-5催化丙烯芳构化反应构效关系及反应特性

甲醇两步制芳烃反应中低碳烯烃芳构化反应稳定性优异,为分析其内在机制,制备了不同硅铝比(n_SiO2/n_Al2O3)及Zn负载量的ZSM-5催化剂,以丙烯芳构化为模型反应,分析ZSM-5表面酸性对低碳烯烃芳构化反应性能的影响规律,并探究反应微观特性。发现当硅铝比由150降至75时,增加的酸密度促进了烯烃氢转移芳构化过程,使芳烃选择性由31.0%增至34.4%,但丙烯直接参与的氢转移过程也被强化,使丙烷产物选择性由28.2%增至36.0%。引入Zn助剂可将部分Br?nsted酸转变为ZnLewis酸,强化烯烃脱氢芳构化过程,使芳烃选择性进一步显著增加到62.4%。丙烯芳构化过程中芳烃烷基化深度比甲醇芳构化过程低,提升总芳烃选择性的同时,也明显抑制了难溶性积碳的形成,使反应稳定性明显提升。由此得出,甲醇两步制芳烃过程中甲醇制低碳烯烃过程对甲醇的预先消耗,抑制了低碳烯烃芳构化反应芳烃产物的深度烷基化,是该反应表现出优异稳定性的重要原因。     

催化褪色光度法测定微量锰（Ⅱ）的研究

本文研究在硫酸介质中，锰（Ⅱ）催化ＥＤＴＡ还原重铬酸银，而使之褪色的新指示反应。确定了催化褪色反应动力学条件，锰（Ⅱ）的浓度在０－０．４μｇ／ｍｌ范围内，工作曲线呈良好的线性关系，检测限为０．０１１μｇ／ｍＬ，该方法用于天然水及污水中锰的测定，获得满意结果。     

AuCl_3催化2-丙炔基-苯胺和丙炔反应机理的研究

采用密度泛函理论方法B3PW91研究了AuCl3催化剂作用下2-丙炔基-苯胺和丙炔环加成生成吲哚衍生物的反应机理。研究结果表明,吲哚衍生物的生成需要经过六个步骤,其中氢迁移过程具有最高的活化自由能为214.22 kJ/mol,是反应的速率控制步骤。整个反应是强放热的,AuCl3催化下反应能够顺利进行,而且AuCl3易于从产物上离去,所以,对于该反应AuCl3是一种有效的催化剂。     

Asymmetric Synthesis of Contact Sex Pheromone of Tetropium fuscum and Its Enantiomer

Tetropium fuscum is a harmful forest pest and attacks spruces. The contact sex pheromone of this pest, (S)-11-methyl-heptacosane, and its enantiomer were synthesized via Evans’ chiral auxiliaries. The key steps of this approach included acylation of carboxylic acid, diastereoselective methylation of oxazolidinone amide, and Wittig coupling of the aldehyde with chiral phosphonium salt. The synthetic pheromones would have potential utility in the control of this pest.     

飞秒强激光作用下Ar原子团簇离子能谱计算

研究了飞秒强激光与Ar原子团簇相互作用时的电离机制及库仑爆炸过程,建立了一个简化的模型计算相互作用产生的离子能谱,计算结果与实验结果较为吻合,可以较好地解释离子能谱高能端的主要特征。     

天文斑点成像技术中的噪声影响分析

为进一步说明天文像复原新方法-迭代位移叠加法的性质，对探测器的附加噪声在斑点干涉术、斑点掩模法和迭代位移叠加法中的影响分别进行了分析。结果表明：在斑点掩模法中，复杂的噪声高阶矩统计被引入了重谱的噪声偏差，因此对噪声极为敏感，使数据处理更加复杂化；与斑点掩模法相比，迭代位移叠加法仅涉及对噪声的一阶矩统计平均，所以此新方法的特点是对噪声不敏感，具有图像复原处理过程简单快捷的优越性。     

A highly selective fluorescent probe for pyrophosphate in aqueous solution

A new 4-amino-1,8-naphthalimide-based fluorescent chemosensor bearing a guanidiniocarbonyl pyrrole moiety has been synthesized. The sensor displays a selective fluorescent enhancement with pyrophosphate over ATP, ADP, AMP and other inorganic anions in aqueous solution.     

A weighted penalty finite element method for the analysis of power-law fluid flow problems

In this paper, a new finite element method for the flow analysis of the viscous incompressible power-law fluid is proposed by the use of penalty-hybrid/mixed finite element formulation and by the introduction of an alternative perturbation, which is weighted by viscosity, of the continuity equation. A numerical example is presented to exhibit the efficiency of the method.The Project Supported by the National Natural Science Foundation of China.     

THREE-DIMENSIONAL THERMOELASTIC ANALYSIS OF FUNCTIONALLY GRADED PLATE

Three-dimensional thermoelastic analysis is presented for an orthotropic functionally graded rectangular plate,which is simply supported and isothermal on its four lateral edges.With the assumption that material properties have arbitrary dependence on the thickness-coordinate,a Peano-Baker series solution is obtained for the thermoelastic fields of the functionally graded plate subjected to mechanical and thermal loads on its upper and lower surfaces by means of state space method.The correctness of the obtained series solution is validated through numerical examples.The influence of different material properties distributions on the structural response of the plate is also studied.