基于移动agent的WSN低能耗数据融合策略设计

为了解决无线传感器网络中LEACH协议中传感器节点需要耗费大量能量,导致节点过早死亡,在LEACH协议的基础上,将移动agent引入到数据融合策略中,提出了一种基于移动agent和LEACH协议的数据融合策略;首先,改进簇头选举机制,考虑剩余能量和与基站的距离等因素;其次,为了避免访问冗余节点而耗费能量,确定了访问节点集合,并通过改进的遗传算法来获得访问节点序列;最后,通过仿真实验并与LEACH协议、AF-LEACH协议进行比较,文中方法节点死亡时间在470s才出现,延迟了节点死亡时间,从而延长了网络的生命周期。     

Effect of heat treatment on morphology, crystalline structure and photocatalysis properties of TiO2 nanotubes on Ti substrate and freestanding membrane

Highly ordered titanium oxide (TiO₂) nanotubes were prepared by electrolytic anodization of titanium electrodes. Morphological evolution and phase transformations of TiO₂ nanotubes on a Ti substrate and that of freestanding TiO₂ membranes during the calcinations process were studied by scanning electron microscopy, transmission electron microscopy, and X-ray diffraction microscopy. The detailed results and mechanisms on the morphology and crystalline structure were presented. Our results show that a compact layer exists between the tubular layer and Ti substrate at 600 °C, and the length of the nanotubes shortens dramatically at 750 °C. The freestanding membranes have many particles on their tubes during calcinations from 450 to 900 °C. The TiO₂ nanotubes on the Ti substrate transform to rutile crystals at 600 °C, while the freestanding TiO₂ membranes retain an anatase crystal with increasing temperature to 800 °C. The photocatalytic activity of TiO₂ nanotubes on a Ti substrate annealed at different temperatures was investigated by the degradation of methyl orange in aqueous solution under UV light irradiation. Due to the anatase crystals in the tubular layer and rutile crystals in the compact layer, TiO₂ nanotubes annealed at 450 °C with pure anatase crystals have a better photocatalytic activity than those annealed at 600 °C or 750 °C.     

Compact double-layer subwavelength binary blazed grating 1×4 splitter based on silicon-on-insulator

We describe a compact double-layer waveguide grating splitter that not only achieves efficient coupling between single mode fiber and a silicon-on-insulator optical waveguide but also realizes effective splitting. By appropriate choice of waveguide/grating parameters, including thicknesses, periods, height, and fill factor to optimize the mode matching, coupling efficiency is improved and the value of power difference of each output port is also significantly decreased. The maximum of power difference between four output ports is about 6.2%; however, the minimum value is only 0.6% or so. Moreover, the average power difference of four output ports is lower than 10% for TE polarization light over the 10?nm wavelength bandwidth centered at 1.54?μm. In addition, the splitter structure has the best tolerance for grating fabrication with deviations of grating depth 90?nm.     

一种新型X射线象增强器光电阴极

我们研制了一种X射线象增强器透射式光电阴极,即高低密度夹芯结构的CsIX射线光电阴极,它的量子效率是高密层CsI的1～10倍.该技术应用于X射线象增强器,探测效率可以提高一个量级,使增益较低的MCP都可以作为产品使用.     

乙丙橡胶共聚物的13C-NMR研究

用溶剂CCl₄,在室温(22℃)条件下,对三种乙丙橡胶共聚物进行¹³C-NMR测定,得到分辨率较高的图谱,标识了各种类型C原子,确定了共聚单体组成和序列分布。结果表明,样品A、B具有嵌段丙烯和嵌段乙烯序列结构可能性较大,样品C具有交替丙烯-乙烯-丙烯序列的倾向较大。用两种统计模型对三个样品的三元组分布进行处理来推测聚合反应机理。     

不完全信息下的区间直觉模糊数的多属性决策方法

针对属性权重信息不完全的区间直觉模糊的多属性决策问题,提出灰色关联分析的决策方法.该方法首先确定各属性下的最佳和最劣方案,确定各方案与理想方案的灰色关联系数,然后在属性权重信息不完全的情况下,建立基于理想点的最优决策模型,求出属性权重,进而根据与理想方案的相对贴近度对各方案进行排序,最后用实例对该方法进行了说明,理论分析和数据结果表明了方法的可行性和有效性.     

Reaction of oxazirconacycloheptenes with aldehydes mediated by CuCl: one-pot synthesis of tetrahydrofuran derivatives from four different components involving two molecules of the same or different aldehydes, an ethylene and an alkyne

Reaction of zirconacyclopentenes with 2 equiv. of the same aldehydes in the presence of 1 equiv. of CuCl from −78 °C to room temperature afforded tetrahydrofuran derivatives in good isolated yields upon hydrolysis with aqueous 3 N HCl. Oxazirconacycloheptenes, generated in situ from zirconacyclopentenes with one aldehyde was found to be the reactive intermediate. When treated with a second aldehyde and CuCl, an oxazirconacycloheptene gave a tetrahydrofuran derivative comprised of four different components involving an alkyne, an ethylene and two different aldehydes, thus providing the first one-pot synthesis of important tetrahydrofuran derivatives from four components. When bulky aldehydes were used, hydrolysis of the above reaction mixtures afforded 2-hexen-1,6-diols, which could be quantitatively transformed to their corresponding tetrahydrofuran derivatives when treated with stronger aqueous acid (12 N HCl).     

单耗分析案例

单耗分析案例宋之平,李洪涛（华北电力大学研究生部北京１０００８５）关键词能量系统,节能降耗,经济学１概述“单耗分析”以单耗为主要指标,以科学而直观的方式展示燃料单耗和成本的构成、分布和变化的图景以及影响因素,以便对改善设计、优化运行、促进管理科学化、...     

CuBr-catalyzed efficient alkynylation of sp3 C-H bonds adjacent to a nitrogen atom

A simple and effective catalytic method to construct propargylamine was developed by using copper bromide and tert-BuOOH via a combination of sp3 C-H bond and sp C-H bond activations followed by C-C bond formation.     

Zeolite nanocrystals inside mesoporous TUD-1: a high-performance catalytic composite

A hierarchically structured composite material with interconnecting meso- and micropores has been developed with the aim to optimize zeolite performance. A general synthetic method has been developed that, in a controlled manner, allows for various types of nanosized zeolite to be incorporated into a three-dimensional mesoporous matrix. Nanosized zeolite Beta was used to exemplify this new approach, resulting in a system in which zeolite Beta shows a higher cracking activity per gram of zeolite than pure nanosized zeolite Beta for the model feed n-hexane. Additionally, FTIR studies of CO and NH3 adsorption revealed that the nature of the acid sites in the nanozeolite has been partially modified due to the interactions with the mesoporous matrix, TUD-1.