XRF法在密闭鼓风炉粗锌分析中的应用

本文研究了用X－射线荧光光谱法测定密闭鼓风炉粗锌中铅、锌、铁和镉等元素,样品从炉前取出后铸成一定形状,被测表面经抛光后直接测定,不经化学处理。用经验系数法校正基体效应。用人工模拟制备标准,其浓度与X－射线强度的线性相关系数均在0．98以上,标准偏差小于0．0056;相对标准偏差小于2．41％。测定结果与化学结果相符。     

Yb∶Y_3Al_5O_(12)晶体晶格振动光谱的研究

采用提拉法生长Y3Al5O12(YAG)晶体和Yb3 掺杂原子数分数分别为5%,10%,15%,20%,25%,50%和100%的Yb∶Y3Al5O12(Yb∶YAG)晶体。系统表征和分析了Yb3 掺杂浓度对拉曼光谱的影响。随着Yb3 掺杂浓度的增加,晶体的振动模式没有明显的变化,晶体结构没有改变;在370 cm-1和785 cm-1附近,振动吸收峰的半峰全宽逐渐增大。分析得出,Yb3 掺杂浓度对晶体的晶格、对称性、荧光寿命均有影响,从而可能影响到晶体的光谱和激光性能。     

Propagation of optical vortex solitons due to the Gouy phase in strongly nonlocal nonlinear media

In this paper,we present a study on the propagation of the symmetrical optical vortices formed by two collinear Laguerre-Gauss solitons in strongly nonlocal nonlinear media.The optical vortices,which move along the beam axis as the light propagates,result in a rotation of the beam’s transverse profile.This physical reason of the rotation is the Gouy phase acquired by the component beams.     

Signal beating elimination using single-mode fiber to multimode fiber coupling

We experimentally demonstrate an all-passive fiber-based approach to prevent undesired beating during signal merging and detection. Beating occurs when optical signals of very close or the same wavelength are combined at a coupler and detected using a photodetector. Our approach is based on signal coupling from several single-mode fibers to a single piece of multimode fiber without interference, such that different signals propagate in different modes with different spatial positions inside the multimode fiber. We have investigated signal beating when the signals are coherent, partially coherent, or incoherent with each other. The measured results for single-mode to multimode coupling show signal beating is substantially reduced, resulting in widely opened eye diagrams and error-free bit error rate performance.     

拟可微函数优化的Lagrange乘子与一阶最优性条件

本文给出了拟可微优化的Fritz John必须条件与Shapiro最优性必要条件的等价性质以及两个最优性充分条件.     

Readily available phosphine-phosphoramidite ligands for highly efficient Rh-catalyzed enantioselective hydrogenations

A new family of air- and moisture-stable phosphine-phosphoramidite ligands (PEAPhos) has been prepared from commercially available and inexpensive (S)-alpha-phenylethylamine through a two- or three-step transformation and successfully applied in the rhodium-catalyzed enantioselective hydrogenations of a variety of substrates, in which up to 99.9% ee was obtained for all of these kinds of substrates.     

多壁碳纳米管-Nafion复合膜修饰玻碳电极测定硝苯地平的研究

研制了以Nafion分散羧基化多壁碳纳米管的化学修饰电极(Nafion-MWCNTs/GC),研究了硝苯地平(NIF)在修饰电极上的电化学行为和测定方法。实验结果表明,在0.1mol/LNH3-NH4Cl(pH9.6)溶液中,Nafion-MWCNTs/GC,对NIF具有明显的催化和增敏作用,还原峰电位由-0.85V(裸电极)正移到-0.75V(vs.AgCl/Ag)(修饰电极),灵敏度增加约7倍。对各种实验条件进行了优化。定量测定的线性范围为2.5×10-7~4.5×10-5mol/L,r为0.9974;检出限为8.0×10-8mol/L。探讨了NIF在Nafion-MWCNTs/GC上的电极过程和反应机理,测得在本体系中参与反应的质子数和电子转移数均为4,电子转移系数α为0.41。对NIF药片进行了测定,回收率为94.5%~101.0%。     

Self‐Healable Electrically Conducting Wires for Wearable Microelectronics

Electrically conducting wires play a critical role in the advancement of modern electronics and in particular are an important key to the development of next‐generation wearable microelectronics. However, the thin conducting wires can easily break during use, and the whole device fails to function as a result. Herein, a new family of high‐performance conducting wires that can self‐heal after breaking has been developed by wrapping sheets of aligned carbon nanotubes around polymer fibers. The aligned carbon nanotubes offer an effective strategy for the self‐healing of the electric conductivity, whereas the polymer fiber recovers its mechanical strength. A self‐healable wire‐shaped supercapacitor fabricated from a wire electrode of this type maintained a high capacitance after breaking and self‐healing.     

X光二极管实验平台初步设计

采用Marx发生器结合水介质同轴线设计了高压脉冲功率源,在X射线二极管负载上可产生数 MV高压输出。通过电压波过程分析,给出了在负载上获得最大电压输出条件下的形成线、传输线的阻抗设计原则。通过集中参数电路模型分析,给出了一定预脉冲幅值下形成线、传输线电长度及中储设计原则。结合水介质正极性耐压Martin经验公式进行绝缘设计,二极管采用径向均压绝缘堆结构,给出了整个装置初步方案设计。基于Pspice的全系统电路模拟表明：当中储运行电压为2.6 MV时,对3 形成线充电电压为3.3 MV,并最终在40 负载上获得4 MV电压输出,且充电过程中负载脉冲幅值约为形成线充电电压的1.2%,在现有条件下,该平台设计指标能够满足实验预期。