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981.
在AZ91D镁合金中添加稀土元素Ce和Y,研究了Ce,Y元素在铸态AZ91D镁合金中的存在形式以及对合金组织和性能的影响。结果表明,铸态AZ91D镁合金中加入的Ce,Y大部分形成Al4Ce和Al2Y化合物,少量剩余的Ce,Y部分取代Mg元素的位置,以代位固溶的形式固溶在α-Mg固溶体和β-Mg17Al12金属间化合物中;Ce,Y能够细化镁合金铸态组织的晶粒,使Mg17Al12相发生"断网"并减少其在组织中的相对比例;适量添加Ce,Y能够提高AZ91D镁合金铸态机械性能,其主要原因是Ce,Y的细晶作用、固溶强化作用、Al-RE相的第二相强化作用以及对Mg17Al12相强化作用的改善。 相似文献
982.
The stability of the disordered structure in liquid or glass states could be characterized by the glass-forming ability (GFA) and thermal stability (TS), respectively. The two quantities are often, but not always, positively correlated. Here we show that the discrepancy between GFA and TS originates from the competition between entropy and enthalpy which fairly much relies on local structural characteristics. This inherent interaction and competition determines hierarchy of phase stability against temperature. As a result, the time susceptibility of GFA and temperature susceptibility of TS were derived from the time-temperature-transformation diagram, which are coincided with the above mentioned entropy-enthalpy competition perspective. Thus, the interrelationship among entropy, enthalpy and local cluster feature provides a potential resolution to design and optimize glass formers, and have implications for better understanding the nature of glass transition. 相似文献
983.
Guang-xiang Zhong Hong-dan Hu Chun-nian Xia Jian-song Jiang Ting-ting Chen 《Journal of chemical crystallography》2010,40(9):735-739
Graphical abstract
The title compounds, 2′,4′-difluoro-4-[(4-methylbenzoyl)oxy]-N-[4-nitro-3-(trifluoromethyl)phenyl]-[1,1′-biphenyl]-3-carboxamide 2a and 2′,4′-difluoro-4-[(4-chlorobenzoyl)oxy]-N-[4-nitro-3-(trifluoromethyl) phenyl]-[1,1′-biphenyl]-3-carboxamide 2b, synthesized from diflunisal, a registered anti-inflammatory drug, via amidation of carboxlic acid and esterification of phenolic hydroxy group, were confirmed by single- crystal X-ray diffraction showing their packing are stabilized by intermolecular hydrogen bonds 相似文献984.
利用荧光光谱法研究了α-萘乙酸(NAA)与DNA之间的相互作用。结果表明,DNA能使NAA的荧光强度猝灭,根据荧光强度变化和荧光猝灭公式求得NAA与DNA的荧光猝灭常数。荧光寿命实验结果表明,荧光猝灭是由形成复合物的静态猝灭过程所致。黏度实验、离子强度实验等多种实验结果表明,NAA与DNA间的结合作用为部分插入式和沟槽式相结合。 相似文献
985.
986.
Solid-state dye samples based on modified polymethyl methacrylate with methanol (MPMMA) doped with pyrromethene 567 (PM567)
were first prepared. The effects of volume percentage of methanol on the laser performances of the samples, including spectra
properties, slope efficiency and photostability were studied. The highest slope efficiency 66.39% was obtained in the sample
(MMA:methanol = 16:4). Pumping the samples at a repetition rate of 5 Hz with a pulse energy as high as 100 mJ (the fluence
was 0.26 J/cm2), the output energy dropped to half of its initial value after approximate 156720 shots and the corresponding normalized
photostability reached 101.86 GJ/mol in the sample (MMA:methanol = 17:3). Our results indicate that it can obtain a high slope
efficiency and good photostability for a solid-state dye laser using MPMMA as solid hosts. 相似文献
987.
W. Liang X. H. Zhang J. Xia G. Y. Jin L. J. Xu G. C. Sun Z. M. Zhao 《Laser Physics》2011,21(5):861-863
A high-power diode -pumped Nd3+:YAl3(BO3)4 (Nd:YAB) laser emitting at 1338 nm is described. At the incident pump power of 9.8 W, as high as 734 mW of continuous-wave
(CW) output power at 1338 nm is achieved. The slope efficiency with respect to the incident pump power was 9.0%. To the best
of our knowledge, this is the first demonstration of such a laser system. The output power stability over 60 min is better
than 2.6%. The laser beam quality M
2 factor is 1.21. 相似文献
988.
Synthesis and luminescence properties of novel 4-(N-carbazole methyl) benzoyl hydrazone Schiff bases
4-(N-carbazole methyl) benzoyl hydrazine was synthesized on the basis of carbazole, and then nine novel carbazolyl acylhydrazone Schiff bases were synthesized by the condensation reaction between 4-(N-carbazole methyl) benzoyl hydrazine and the substituted benzaldehydes. The relationships between the substituted group types and the UV fluorescence spectral properties, as well as the fluorescence quantum yields of the title Schiff bases were also investigated. The results show that the introduction of both the donating and accepting electron groups causes various grade redshifts of the fluorescence characteristic emission peak of the title Schiff bases to occur.The fluorescence quantum yields of the title Schiff bases with the donating group are increased, and the highest fluorescence quantum yield is up to 0.703. 相似文献
989.
Qinglin Sai Changtai Xia Han Rao Xiaodong Xu Peng Xu 《Journal of luminescence》2011,131(11):2359-2364
The Mn-, Cr-doped and Mn, Cr-co-doped MgAl2O4 powders have been synthesized via a gel-solid reaction method. Energy transfer from Mn2+ to Cr3+ has been observed for the first time in the co-doped MgAl2O4 phosphors. When excited with blue light with a wavelength of 450 nm at room temperature, both green emission from Mn2+ around 520 nm and red emission from Cr3+ around 675and 693 nm were generated. Moreover, the color of the emission can be modified by controlling the doping concentrations of Mn2+ and Cr3+. Therefore, MgAl2O4: Mn2+, Cr3+ could be used as a single-phased phosphor for white LED with a blue LED chip. The energy transfer in terms of Mn2+ to Cr3+ is determined by means of radiation and reabsorption. 相似文献
990.
Long Zheng Xia Zhang Xiaomin Ren Jing Gao Lei Shi Xiaolong Liu Qi Wang Yongqing Huang 《Optics & Laser Technology》2011,43(5):960-964
Surface plasmon resonance sensors based on Ag-metalized nanolayer in microstructured optical fibers are theoretically analyzed by using finite element method (FEM). In our simulations we use Drude-Lorentz model to describe the metal dielectric constant. The numerical results show that the sensitivity of Ag-metalized SPR sensor could reach 1167 nm/RIU and corresponding resolution is 8.57×10−5 RIU. Compared to conventional Au-metalized SPR sensors the performance of our device is obviously better. 相似文献