Frustrated Total Internal Reflection: Resonant and Negative Goos–Hänchen Shifts in Microwave Regime

It is well-known that the variations of Goos–Hänchen shifts (GHSs) are closely associated with the energy flux provided by evanescent states in the case of total internal reflection. However, when the frustrated total internal reflection (FTIR) is realized with double-prism system operated in the microwave frequency, we observe that the GHSs for the reflected beam show periodic, resembling the phenomenon for transmitted beams reported in the literatures, versus either the operating frequency or the air layer thickness, which is different from the variation of the corresponding reflected energy. Moreover, in another FTIR based system fabricated by a composite absorptive material slab with a two-dimensional top layer of frequency selective surface (FSS), the GHSs for reflected beam are discovered as not only resonant but also negative with the incidence of transverse electric that is TE polarized, just as predicted theoretically in the literatures.     

海藻酸钠粘结剂用于钠离子电池红磷-碳负极

通过球磨法制备了红磷-碳(P-C)复合材料,并考察了海藻酸钠(SA)粘结剂用于钠离子电池P-C负极的电化学性能。结果表明,相对于聚偏氟乙烯(PVDF)粘结剂,SA粘结剂使P-C电极展示了较高的可逆容量(在0.1 A·g~(-1)的电流密度下循环20圈后的容量为2 126 m Ah·g~(-1))。使用SA作粘接剂的P-C复合材料优越的电化学性能,归因于SA粘结剂与活性物质之间可能存在的化学作用力,有效缓解了红磷脱嵌钠过程中的体积变化,保持了电极的稳定性。     

常压催化加氢合成邻氨基苯酚的研究

用硅溶胶改性的漆原镍催化剂，在常压液相催化条件下，氢化邻硝基苯酚制备邻氨基苯酚的反应过程，可分为诱导期、恒速吸氢阶段、吸氢衰减期３个反应阶段．恒速吸氢阶段的吸氢速率为５×１０２ｍｏｌ／（ｋｇ·ｍｉｎ）且与体系的温度无关，诱导期随温度的增加而变短，吸氢衰减期的长短随溶剂量的变化而变化．实验结果表明，邻氨基苯酚的收率在９５％左右．     

纳米固体超强酸SO42-/Fe2O3的制备及其催化合成乙酸乙酯

将Fe₂O₃纳米粉体经一定浓度的H₂SO₄浸泡活化后制成纳米固体超强酸SO₄^2-/Fe₂O₃,将其用于催化合成乙酸乙酯以考察其活性。利用均匀设计分析了超强酸制备过程及酯化反应过程中各因素的影响,研究结果表明较好的制备条件是:H₂SO₄浓度:2.5mol·L^-1;浸泡时间:1h;活化温度:167℃;活化时间:1h,此时获得的固体超强酸SO₄^2-/Fe₂O₃的粒径小于50nm。当催化剂用量为冰乙酸质量的5%,n(乙醇)∶n(冰乙酸)为3∶1,反应3.5h后乙酸的转化率高于80%。该催化剂经H₂SO₄溶液浸泡、活化再生后可重新使用,推断出其酸强度H₀<-14.5。     

细胞动力学研究Ⅴ.细胞连续增长热动力学

用微量热法测定了布鲁氏菌Ｍ５（５５０１０）和８３－９８１在２７℃和４０℃时的生长发热功率曲线．由这些生长发热功率曲线，建立了细胞有限条件下连续增长热动力学方程：ｌｎ（Ｐｍ／Ｐｔ－１）＝ｌｎ（Ｐｍ／Ｐ０－１）－ｋｔ从而求出了细菌的生长常数ｋ．这个方程非常适合“Ｓ”型的生长发热功率曲线     

Multiple singular manifold method and extended direct method: Application to the burgers equation

This paper considers the relationship between the multiple singular manifold method (MSMM) and the extended direct method (EDM) for studying partial differential equations. It is shown that the similarity reductions using EDM can be obtained by MSMM. The prototype example for illustrating the approach is the Burgers equation, which is the simplest evolution equation to embody nonlinearity and dissipation. As a conclusion of the MSMM, we obtain a set of Bäcklund transformations of the Burgers equation.