全文获取类型
收费全文 | 3920篇 |
免费 | 740篇 |
国内免费 | 657篇 |
专业分类
化学 | 3098篇 |
晶体学 | 25篇 |
力学 | 188篇 |
综合类 | 35篇 |
数学 | 388篇 |
物理学 | 1583篇 |
出版年
2024年 | 7篇 |
2023年 | 86篇 |
2022年 | 123篇 |
2021年 | 101篇 |
2020年 | 151篇 |
2019年 | 144篇 |
2018年 | 125篇 |
2017年 | 124篇 |
2016年 | 177篇 |
2015年 | 170篇 |
2014年 | 247篇 |
2013年 | 326篇 |
2012年 | 402篇 |
2011年 | 446篇 |
2010年 | 298篇 |
2009年 | 254篇 |
2008年 | 323篇 |
2007年 | 275篇 |
2006年 | 229篇 |
2005年 | 180篇 |
2004年 | 145篇 |
2003年 | 105篇 |
2002年 | 100篇 |
2001年 | 91篇 |
2000年 | 76篇 |
1999年 | 75篇 |
1998年 | 77篇 |
1997年 | 67篇 |
1996年 | 67篇 |
1995年 | 81篇 |
1994年 | 42篇 |
1993年 | 28篇 |
1992年 | 39篇 |
1991年 | 31篇 |
1990年 | 17篇 |
1989年 | 17篇 |
1988年 | 16篇 |
1987年 | 7篇 |
1986年 | 8篇 |
1985年 | 10篇 |
1984年 | 5篇 |
1983年 | 3篇 |
1982年 | 6篇 |
1981年 | 7篇 |
1980年 | 1篇 |
1979年 | 4篇 |
1974年 | 1篇 |
1940年 | 1篇 |
1902年 | 1篇 |
1898年 | 1篇 |
排序方式: 共有5317条查询结果,搜索用时 93 毫秒
51.
J C Zhu C H Li Y Liu Z H Zhang A X Hou S S Qu 《Journal of Thermal Analysis and Calorimetry》2006,83(1):181-186
After the occurrence of 'Minamata disease' in 1950,
mercury aroused much more attention, and lots of studies concerned have been
made. The purpose of the present paper is to study the effect of mercuric
chloride on the mitochondria suspension isolated from the liver tissue of Cyprinus carpio from the direct viewpoint of energy
by using the microcalorimetric method. The metabolic thermogenic curves of
the mitochondria suspension at 25°C were obtained, and the mitochondria
metabolic thermokinetic equations were established, from which we obtained
the thermodynamic and thermokinetic parameters: thermogenic rate constant
(k), heat output (Q),
average heat power (Pav),
etc. Experimental results indicated that low concentration of mercuric chloride
(5 nmol Hg2+/(mg protein)) stimulates the thermogenesis
of mitochondria, suggesting a strong effect of uncoupling action, while high
concentration of mercuric chloride (20 nmol Hg2+/(mg
protein)) inhibits the metabolism of mitochondria completely, suggesting a
fatal effect on the phosphorylation system. The effect of Hg2+
on mitochondria is concentration-depended, from which the probable reaction
mechanism of Hg2+ to the mitochondria was proposed.
So the microcalorimetric method can be used in the toxicology research. 相似文献
52.
一种新的液晶高分子——丁酸壳聚糖的合成与表征 总被引:18,自引:2,他引:18
甲壳素几乎不溶于任何溶剂,由于其脱乙酰化产物壳聚糖含自由氨基,能被酸质子化而溶解,所以壳聚糖的应用领域远多于甲壳素.但是壳聚糖也仅能溶于酸性介质中,并不能溶于纯水和普通有机溶剂,因而人们对甲壳素或壳聚糖进行各种化学改性[1,2],寻求溶解性更好尤其能溶于水的衍生物,以扩大其应用范围.本文按文献[2~4]方法合成了O-丁酰化壳聚糖(简称丁酸壳聚糖),首次报道它具有溶致液晶性. 相似文献
53.
The contribution of the Institute for Reference Materials and Measurements to the certification of the B, Cd, Cu, Mg, and Pb content of a synthetic water sample used in Comparison 12 of the International Measurement Evaluation Programme (IMEP-12) is described. The aim of the IMEP programme is to demonstrate objectively the degree of equivalence and quality of chemical measurements of individual laboratories on the international scene by comparing them with reference ranges traceable to the SI (Système International d'Unités). IMEP is organized in support of European Union policies and helps to improve the traceability of values produced by field chemical measurement laboratories. The analytical procedure used to establish the reference values for the B, Cd, Cu, Mg, and Pb content of the IMEP-12 sample is based on inductively coupled plasma-isotope-dilution mass spectrometry (ICP-IDMS) applied as a primary method of measurement. The measurements performed for the IMEP-12 study are described in detail. Focus is on the element boron, which is particularly difficult to analyze by ICP-MS because of potential problems of low sensitivity, high mass discrimination, memory effects, and abundance sensitivity. For each of the certified amount contents presented here a total uncertainty budget was calculated using the method of propagation of uncertainties according to ISO (International Organization for Standardization) and Eurachem guidelines. For all investigated elements with concentrations in the low micro g kg(-1) and mg kg(-1) range (corresponding to pmol kg(-1) to the high micro mol kg(-1) level), SI-traceable reference values with relative expanded uncertainties ( k=2) of less than 2 % were obtained. 相似文献
54.
A new sensing method (BAW-TAL technique), which combined the bulk acoustic wave (BAW) technique with the gelation reaction of Tachypleus amebocyte lysate (TAL), was used for viscosity and density measurement and applied to the detection of Escherichia coliform (E. coli). This method depended on the fact that the viscosity and density of the mixture increased, and as a result, the resonance frequency decreased correspondingly after TAL was mixed with the heated E. coli solution that contained endotoxin. Results showed that the frequency shift was linearly related to the logarithm of E. coli concentration in the range of 2.7x10(4)-2.7x10(8) cells/ml. The correlation coefficient was 0.996. This BAW-TAL method was compared with the standard pour plate counts (PPC) method. The proposed method was much more rapid and simpler for detection of E. coli than the traditional methods. 相似文献
55.
细胞动力学研究VIII.Na2SeO3对黑根菌作用特征 总被引:1,自引:0,他引:1
The Characteristics of the action of Na2SeO3 on Rhizopus nigrocans has been studied by means of microcalorimetry, the relationship between growth rate constants and the concentration of Na2SeO3 is
k=0.03608exp[-0.003608(c+8.60)2]
It was found that Na2SeO3 of low concentration has promoting action on the growth of Rhizopus nigrocans cells, and high concentration of Na2SeO3 has inhibitory action. The study has provided a lot of information on the bioaffect of selenium and the research of toxicology. 相似文献
k=0.03608exp[-0.003608(c+8.60)2]
It was found that Na2SeO3 of low concentration has promoting action on the growth of Rhizopus nigrocans cells, and high concentration of Na2SeO3 has inhibitory action. The study has provided a lot of information on the bioaffect of selenium and the research of toxicology. 相似文献
56.
Annals of Global Analysis and Geometry - In this paper, we study a problem of finding compact hypersurfaces of prescribed mean curvature with free boundary in a ball. We transform the problem to an... 相似文献
57.
58.
钼钨铌磷杂多化合物的研究(Ⅰ):杂多酸的合成和表征 总被引:4,自引:0,他引:4
提出了分步酸化一分步加料合成[PNb_2Mo_xW_(10-x)O_(40)]~(5-)(x=0,2,4,6)系列杂多酸的方法,给出了最佳配料比和生成反应的pH值,并进行了红外、紫外、极谱、电位滴定及热稳定性研究。 相似文献
59.
60.