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901.
This paper presents the absorption spectra, excited spectra and fluorescence spectra of Nd: YAP, Ce: YAP and Nd, Ce: YAP. It is believed that there is an energy transfer from Ce3+ to Nd3+ and it is possible to improve the laser efficiency of Nd: YAP sensitized by Ce3+. 相似文献
902.
903.
微滴喷射增材制造技术中沉积微滴的大小与均匀性是影响成型件质量的关键因素.本文设计了一种用于生成均匀微滴的压电驱动式微滴喷射装置,通过压电材料带动柔性膜片振动,将液体从喷嘴中喷出生成微滴,采用数值模拟和实验相结合的方法,研究了不同控制参数下膜片振幅及其对生成微滴尺寸和均匀性的影响.研究结果表明:膜片振幅大小受到驱动电压和压电频率的共同影响,压电频率是导致膜片中心点振幅实验测量值小于理论计算值的主要原因,膜片振动会导致喷嘴内部压力发生变化从而影响微滴生成尺寸.在相同驱动电压条件下,压电频率为10 Hz时存在压电膜片振幅最大值.随着膜片振幅的增大,喷孔处液体速度和液柱长度增大到临界值时可以生成微滴,当喷孔处的液柱长度超过临界值时,会形成卫星液滴. 当膜片振幅区间在30 $\mu$m$\sim $42 $\mu $m可以稳定生成微滴,生成最小微滴尺寸为339.8$\mu$m,直径最大变化率为0.29%,相邻两微滴间距最大变化率为2.67%,生成微滴的尺寸及均匀性较好.研究结果有助于提高压电式微滴喷射装置的液滴生成质量. 相似文献
904.
Meccanica - A flow mixing nozzle can produce satisfactory atomization for heavy oil. However, the study of the internal flow pattern of this nozzle, along with the spray morphology and its... 相似文献
905.
YANG Liming GUO Lixin YU Hao WANG Guan SUN Jiangman ZHANG Pengfei GU Xinggui TANG Ben Zhong 《高等学校化学研究》2021,37(1):129-136
The development of fluorescent nanocrystals based on organic small molecules is of great importance in bioimaging due to the merits of easy modification,high brightness and excellent photostability,however suffering from the emission-detrimental aggregation-caused quenching(ACQ)effect.Herein,we successfully designed and synthesized an AIE-active di(N,N-dimethylaniline)-dibenzofulvene(named as NFTPE),which exhibits the crystallization-induced emission enhancement(CIEE)effect.Interestingly,two types of yellow-and orange-emissive crystals for NFTPE were obtained,exhibiting aggregation microenvironment-dependent emission tuning in the solid state.Single-crystal analysis and density functional theory(DFT)calculations reveal that different aggregation microenvironments result in the distinct molecular conformation for various emission.Excitingly,the crystallization of NFTPE in an aqueous solution under the assistance of amphiphilic PEG polymer matrices could be monitored in situ by the fluorescence changes,facilitating the preparation of NFTPE nanocrystals(NFTPE-NCs)by adjusting the aggregation microenvironment.The obtained NFTPE-NCs exhibit the superior performance in cell imaging in respect to high brightness,photostability,and biocompatibility,thus demonstrating the potential in bioimaging applications. 相似文献
906.
Chao-Shen Zhang Bei-Bei Zhang Liang Zhong Xiang-Yu Chen Zhi-Xiang Wang 《Chemical science》2022,13(13):3728
A DFT study has been conducted to understand the asymmetric alkyl–alkyl bond formation through nickel-catalysed reductive coupling of racemic alkyl bromide with olefin in the presence of hydrosilane and K3PO4. The key findings of the study include: (i) under the reductive experimental conditions, the Ni(ii) precursor is easily activated/reduced to Ni(0) species which can serve as an active species to start a Ni(0)/Ni(ii) catalytic cycle. (ii) Alternatively, the reaction may proceed via a Ni(i)/Ni(ii)/Ni(iii) catalytic cycle starting with a Ni(i) species such as Ni(i)–Br. The generation of a Ni(i) active species via comproportionation of Ni(ii) and Ni(0) species is highly unlikely, because the necessary Ni(0) species is strongly stabilized by olefin. Alternatively, a cage effect enabled generation of a Ni(i) active catalyst from the Ni(ii) species involved in the Ni(0)/Ni(ii) cycle was proposed to be a viable mechanism. (iii) In both catalytic cycles, K3PO4 greatly facilitates the hydrosilane hydride transfer for reducing olefin to an alkyl coupling partner. The reduction proceeds by converting a Ni–Br bond to a Ni–H bond via hydrosilane hydride transfer to a Ni–alkyl bond via olefin insertion. On the basis of two catalytic cycles, the origins for enantioconvergence and enantioselectivity control were discussed.The enantioconvergent alkyl–alkyl coupling involves two competitive catalytic cycles with nickel(0) and nickel(i) active catalysts, respectively. K3PO4 plays a crucial role to enable the hydride transfer from hydrosilane to nickel–bromine species. 相似文献
907.
908.
SHEN Qifei XU Ruohan WANG Zhi ZHAO Tianyu ZHOU Yu XU Yanzi YANG Zhiwei LEI Ming MENG Lingjie DANG Dongfeng 《高等学校化学研究》2021,37(1):143-149
Aggregation-induced emission(AIE)luminogens(AIEgens)with high brightness in aggregates exhibit great potentials in biological imaging,but these AIEgens are seldom applied in super-resolution biological imaging,especially in the imaging by using the structural illumination microscope(SIM).Based on this consideration,we synthesized the donor-acceptor typed AIEgen of DTPA-BTN,which not only owns high brightness in the near-infrared(NIR)emission region from 600 nm to 1000 nm(photoluminescence quantum yield,PLQYs=11.35%),but also displays excellent photo-stability.In addition,AIE nanoparticles based on 4,7-ditriphenylamine-[1,2,5]-thiadiazolo[3,4-c]pyridine(DTPA-BTN)were also prepared with highly emissive features and excellent biocompatibility.Finally,the developed DTPA-BTN-based AIE nanoparticles were applied in the super-resolution cellular imaging via SIM,where much smaller full width at half-maximum values and high signal to noise ratios were obtained,indicating the superior imaging resolution.The results here imply that highly emissive AIEgens or AIE nanoparticles can be promising imaging agents for super-resolution imaging via SIM. 相似文献
909.
聚酰亚胺/SiO2杂化膜的制备、表征和气体渗透性能 总被引:1,自引:0,他引:1
采用溶胶凝胶法,在以TiO2为过渡层的硅藻土-莫来石陶瓷膜管基底上,制备了组分不同的聚酰亚胺/SiO2杂化膜。聚酰亚胺是利用4,4′-六氟亚异丙基邻苯二甲酸酐、2,4,6-三甲基-1,3-苯二胺和3,5-二氨基苯甲酸在溶液中进行亚胺化完成的。采用FT-IR、TG/DTA、DSC、SEM、BET和气体渗透测定对膜进行了表征和测试。结果表明,聚酰亚胺通过支链上的羧酸基和SiO2相键连织构成了具有规则孔道的空间网状结构,并且随着SiO2含量的增加孔径逐渐减小;杂化膜具有较高的热稳定性和有机无机兼容性;相对于聚酰亚胺膜,杂化膜对H2、CO2和H2O与N2相比较具有较高的分离性,SiO2含量为25(wt)%的杂化膜对H2/N2、CO2/N2和H2O/N2的分离因子分别达到55.9、31.1和42.8。 相似文献
910.