全文获取类型
收费全文 | 14498篇 |
免费 | 2302篇 |
国内免费 | 2448篇 |
专业分类
化学 | 11647篇 |
晶体学 | 199篇 |
力学 | 783篇 |
综合类 | 256篇 |
数学 | 1573篇 |
物理学 | 4790篇 |
出版年
2024年 | 40篇 |
2023年 | 205篇 |
2022年 | 431篇 |
2021年 | 443篇 |
2020年 | 523篇 |
2019年 | 623篇 |
2018年 | 455篇 |
2017年 | 479篇 |
2016年 | 703篇 |
2015年 | 778篇 |
2014年 | 843篇 |
2013年 | 1125篇 |
2012年 | 1223篇 |
2011年 | 1133篇 |
2010年 | 1044篇 |
2009年 | 897篇 |
2008年 | 1113篇 |
2007年 | 955篇 |
2006年 | 868篇 |
2005年 | 795篇 |
2004年 | 652篇 |
2003年 | 627篇 |
2002年 | 733篇 |
2001年 | 662篇 |
2000年 | 455篇 |
1999年 | 309篇 |
1998年 | 206篇 |
1997年 | 134篇 |
1996年 | 119篇 |
1995年 | 99篇 |
1994年 | 74篇 |
1993年 | 73篇 |
1992年 | 81篇 |
1991年 | 81篇 |
1990年 | 56篇 |
1989年 | 31篇 |
1988年 | 30篇 |
1987年 | 20篇 |
1986年 | 22篇 |
1985年 | 28篇 |
1984年 | 16篇 |
1983年 | 15篇 |
1982年 | 8篇 |
1981年 | 3篇 |
1979年 | 7篇 |
1975年 | 3篇 |
1974年 | 4篇 |
1973年 | 2篇 |
1936年 | 3篇 |
1935年 | 2篇 |
排序方式: 共有10000条查询结果,搜索用时 15 毫秒
51.
We evaluate the practical relevance of two measures of conic convex problem complexity as applied to second-order cone problems solved using the homogeneous self-dual (HSD) embedding model in the software SeDuMi. The first measure we evaluate is Renegar's data-based condition measure C(d), and the second measure is a combined measure of the optimal solution size and the initial infeasibility/optimality residuals denoted by S (where the solution size is measured in a norm that is naturally associated with the HSD model). We constructed a set of 144 second-order cone test problems with widely distributed values of C(d) and S and solved these problems using SeDuMi. For each problem instance in the test set, we also computed estimates of C(d) (using Peña’s method) and computed S directly. Our computational experience indicates that SeDuMi iteration counts and log (C(d)) are fairly highly correlated (sample correlation R = 0.675), whereas SeDuMi iteration counts are not quite as highly correlated with S (R = 0.600). Furthermore, the experimental evidence indicates that the average rate of convergence of SeDuMi iterations is affected by the condition number C(d) of the problem instance, a phenomenon that makes some intuitive sense yet is not directly implied by existing theory. 相似文献
52.
X.T Zhang Y.C LiuZ.Z Zhi J.Y ZhangY.M Lu D.Z ShenW Xu X.W FanX.G Kong 《Journal of luminescence》2002,99(2):149-154
The properties of the excitonic luminescence for nanocrystalline ZnO thin films are investigated by using the dependence of excitonic photoluminescence (PL) spectra on temperature. The ZnO thin films are prepared by thermal oxidation of ZnS films prepared by low-pressure metalorganic chemical vapor deposition (LP-MOCVD) technique. The X-ray diffraction (XRD) indicates that ZnO thin films have a polycrystalline hexagonal wurtzite structure with a preferred (0 0 2) orientation. A strong ultraviolet (UV) emission peak at 3.26 eV is observed, while the deep-level emission band is barely observable at room temperature. The strength of the exciton-longitudinal-optical (LO) phonon coupling is deduced from the temperature dependence of the full-width at half-maximum (FWHM) of the fundamental excitonic peak, decrease in exciton-longitudinal-optical (LO) phonon coupling strength is due to the quantum confinement effect. 相似文献
53.
用600keV的Kr~ 离子轰击Al/Cr双层薄膜样品进行界面原子反应及相互混合的研究。实验样品是在单晶硅上蒸镀约500nm厚的铝膜,相继再蒸上所需厚度的铬膜而制成的。轰击剂量为2.0×10~(15)-2.5×10~(16)Kr~ /cm~2。用2.0MeVa粒子对轰击前后的样品进行了卢瑟福背散射(RBS)分析,发现界面处有明显的原子混合存在;当轰击剂量≥1.0×10~(16)Kr~ /cm~2时,RBS谱出现有明显的坪台,经拟合计算和x射线衍射(XRD)测量证实确有化合物Al_(13)Cr_2存在;还分别得到了原子混合量及混合效率与轰击剂量的关系;最后对界面处的原子混合机制进行了讨论。 相似文献
54.
本文用ab initio计算方法,采用STO-3G基组,对二硝基卤代甲烷CH_2(NO_2)_3(1),CF_2(NO_2)_2(2);CCl_2(NO_2)_2(3)等分子作了单点计算,研究其旋转势能.全构型优化研究了五个具有对称性构型的结构和稳定性,并作了理论分析和探讨. 相似文献
55.
基于cDNA宏阵列的系统聚类分析猪发育阶段的基因表达谱 总被引:3,自引:0,他引:3
取杜洛克猪胚胎第33,45,55,65.75天的背最长肌样本.用cDNA Macroarray分析方法和聚类分析技术分析了327个EST在骨骼肌内不同发育阶段的基因表达谱.结果表明有98条EST在不同发育时期显著差异表达.第33天和第45天两阶段基因表达状态相似.第55天和第65天基因表达状态相似.而第75天的基因表达与第55天和第65天两个阶段的基因表达具有相近的聚类关系.表达状态相近,基因功能相似的基因大都被聚类在一起. 相似文献
56.
57.
A Novel and Efficient Catalytic System for Aerobic Oxidative Coupling of 2-Naphthol Derivatives 总被引:2,自引:0,他引:2
LiCHEN JingBoLAN ZhiHuaMAO XiaoQiYU RuGangXIE 《中国化学快报》2004,15(8):903-906
The paper reported a novel and efficient aerobic oxidative coupling reaction of 2-naphthol derivatives catalyzed by CuCu (Ⅰ or Ⅱ)N-alkylimidazole complexes in excellent yields. The crystal structure of CuCu(Ⅱ)N-methylimidazole complex to be determined by X-Ray. 相似文献
58.
Zhi‐Yong Huang Jin‐Can Shen Zhi‐Xia Zhuang Xiao‐Ru Wang Frank S. C. Lee 《应用有机金属化学》2004,18(6):255-261
Cinnabar, as one of the most widely used mineral drugs in traditional Chinese medicines, has been proven to have prominent curative effects in clinical use for more than 2000 years. But the safety and toxicity of the drug has been under constant debate in clinic usage. Metallothionein (MT) contains about 30% of cysteine in the molecule, and plays an important detoxification role against heavy metals. In this study, it was used as a biomarker to assess mercurial accumulation in rats fed orally with cinnabar. After feeding rats with cinnabar by gastric gavage at different dosages and at different times, the distribution of heavy metals (including mercury, copper and zinc) and MT was investigated among rat tissues, including liver, kidney, heart, brain, testis and blood. Metals and MT determinations were carried out using inductively coupled plasma mass spectrometry (ICP‐MS) and a modified mercury saturation assay technique respectively. The results indicated that mercury was easily accumulated in the tissues of rats exposed to cinnabar, especially in kidney. For example: at a feeding dosage of 5 g kg?1 (bw) for 4 weeks, the mercury concentrations in kidney were 13, 8.7, 21.6 and 26 times those in liver, testis, brain and heart respectively; and at 2.5 g kg?1 (bw) for 2 weeks, the mercury concentrations in kidney were 21, 2.1, 3 and 21 times those in liver, testis, brain and heart respectively. In addition, mercury in kidney and liver of all cinnabar groups was significantly higher than that of the control group (P < 0.01). A high positive correlation observed between MT concentrations and mercury levels in both liver and kidney (R2 = 0.9299, P < 0.02 for liver; R2 = 0.9923, P < 0.0008 for kidney) indicated that MT could be used as a biomarker for mercury in tissues. Copyright © 2004 John Wiley & Sons, Ltd. 相似文献
59.
The classes ofL
1-matrices,L
2-matrices,L
3-matrices andW-matrices are introduced to study solvability of a linear complementarity problem via solving a linear program. Three sufficient
conditions are presented to guarantee that a linear complementarity problem is solvable via a linear program. The new sufficient
conditions are weaker than the ones introduced by Mangasarian. This fact is also illustrated by an example.
Partially supported by NSFC.
This author is also with College of Business Administration of Human University as a Lotus chair professor. 相似文献
60.
The terminology ‘ID frequency’(w ID) is proposed after analyzing the 1D active photonic crystal based on the transfer matrix method. The relationship between wID and the structure parameters of the photonic crystal is investigated. 相似文献