全文获取类型
收费全文 | 17372篇 |
免费 | 2780篇 |
国内免费 | 1936篇 |
专业分类
化学 | 12597篇 |
晶体学 | 186篇 |
力学 | 1198篇 |
综合类 | 137篇 |
数学 | 2028篇 |
物理学 | 5942篇 |
出版年
2024年 | 54篇 |
2023年 | 333篇 |
2022年 | 540篇 |
2021年 | 572篇 |
2020年 | 631篇 |
2019年 | 665篇 |
2018年 | 534篇 |
2017年 | 540篇 |
2016年 | 763篇 |
2015年 | 766篇 |
2014年 | 955篇 |
2013年 | 1173篇 |
2012年 | 1530篇 |
2011年 | 1546篇 |
2010年 | 1057篇 |
2009年 | 938篇 |
2008年 | 1084篇 |
2007年 | 977篇 |
2006年 | 978篇 |
2005年 | 793篇 |
2004年 | 602篇 |
2003年 | 546篇 |
2002年 | 546篇 |
2001年 | 462篇 |
2000年 | 350篇 |
1999年 | 364篇 |
1998年 | 291篇 |
1997年 | 270篇 |
1996年 | 303篇 |
1995年 | 237篇 |
1994年 | 205篇 |
1993年 | 160篇 |
1992年 | 172篇 |
1991年 | 175篇 |
1990年 | 132篇 |
1989年 | 123篇 |
1988年 | 81篇 |
1987年 | 70篇 |
1986年 | 80篇 |
1985年 | 60篇 |
1984年 | 54篇 |
1983年 | 45篇 |
1982年 | 32篇 |
1981年 | 31篇 |
1980年 | 29篇 |
1978年 | 24篇 |
1977年 | 25篇 |
1976年 | 23篇 |
1974年 | 20篇 |
1973年 | 26篇 |
排序方式: 共有10000条查询结果,搜索用时 453 毫秒
41.
根据有限元法单元划分的思想,提出了一种新颖的模拟光腔模式及光束传输的特征向量法. 该方法的关键之处在于基于衍射积分理论构造了一种新的光束传输矩阵,通过求解特征矩阵方程可一次性得到谐振腔的一系列特征向量,每一列特征向量即代表了腔镜上光场的一个确定模式的振幅及相位分布. 并可采用该方法模拟光场传输到腔内或腔外任意地方的场分布. 该方法将传统方法中大量的迭代过程转化成为本征积分方程特征向量的求解过程,并与初值取值无关,且可一次性求得多个模式分布,从而可方便地分析谐振腔的模式鉴别能力. 特征向量法对圆形镜共焦
关键词:
谐振腔
特征向量法
模式分布 相似文献
42.
基于Gross-Pitaevskii方程,运用有效化学势概念,研究了囚禁在组合势(由磁阱和三维光 晶格组成)中玻色凝聚气体在三维光晶格中的分布规律,并由此得到玻色凝聚气体的归 一化基态波函数.在取消组合势和仅取消光晶格而保留磁阱的两种情况下,运用传播子方 法求解出玻色凝聚气体密度分布的解析表达式.取消组合势后,理论计算所得到的玻色凝聚 气体聚随时间的演化规律与Greiner等的实验结果相一致.仅取消光晶格而保留磁阱时,研 究表明玻色凝聚气体的干涉模式呈现周期性的振荡行为.此外,在磁阱为各向异性的情况下 ,
关键词:
玻色凝聚气体
磁阱
光晶格
干涉模式 相似文献
43.
XiaoMinSUN DaChengFENG ZhengTingCAI 《中国化学快报》2004,15(6):749-752
For the Na I2 collision system, theoretical study is performed on the QCISD(T) level by using ab initio method. The ab initio potential energy surfaces are got and on them the long-lived complexes are found and optimized. These results verify the crossed molecule beam experimental phenomenon and the detailed geometry structures are given for the first time. The role of the complexes in the reaction path is also described in detail. 相似文献
44.
Ri Cheng XUAN* Wei Xiao HU Zhong Yu YANG Ya Ping LU College of Pharmaceutical Sciences Zhejiang University of Technology Hangzhou 《中国化学快报》2004,(2)
2-Chloro-5-methylpyridine is an important intermediate for the preparation of biological active compounds, especially insecticides1, e.g. imidacloprid2, and is usually manufac- tured from 3-methylpyridine N-oxide. However, the manufacturing process also forms the by-products: 3-methylpyridine and its isomer 2-chloro-3-methylpyridine3. The pro- perties of the isomers are similar, it is difficult to separate by ordinary methods, such as distillation. Scheme 1 79.4%13.6%5.2%NClCH3NCH3ClNC… 相似文献
45.
FengSHI HongYangLI XiaoJunPENG RongZHANG XiaoQiangCHEN JiangLiFAN LiChengSUN 《中国化学快报》2004,15(12):1407-1410
As photosensitizer for solar cell, a new ruthenium (Ⅱ) complex with four ester groups had been synthesized, in which a phenol substituted by {[(2-hydroxy-5-tert-butylbenzyl)(pyridyl-2-methyl)amino]methyl} is covalently linked to ruthenium (Ⅱ) tris-bipyridine. The structures of the new compounds were confirmed by NMR and ESI-MS spectra. The electrochemical and photochemical properties were also studied. 相似文献
46.
JingXiaWANG ChengYouKAN DeShanLIU 《中国化学快报》2004,15(10):1161-1163
Two novel polymerizable dyes with anthraquinone residue have been prepared, and their structures were characterized by FTIR, ^1HNMR and EA. 相似文献
47.
本文通过研究匹配问题的实例空间,匈牙利算法和解空间三者之间的关系,指出S实例空间的数目与问题复杂度之间的关系既不是充分也不是必要的,而如何对问题的解空间进行合理的分解才能是问题的关键。 相似文献
48.
Paul阱内的压缩效应与量子跃迁 总被引:1,自引:1,他引:0
处理一个一维Paul阱系统中的压缩现象与量子跃迁现象,对于阱内的最强压缩态和共振跃迁(一种极不稳定状态)之间的关系作了阐述,并对利用压缩性质在阱内进行精密测量的可能性作了讨论 相似文献
49.
本文在A.Blanco等人的算法的基础上,提出了max-min神经网络的一种改进了的反馈学习算法,严格证明了该算法的迭代收敛性,理论分析及实例计算结果均表明,本文算法具有算法简单,收敛速度快,输出误差小等显著特点。 相似文献
50.
Benjamin S. Hsiao Rong-Ming Ho Stephen Z. D. Cheng 《Journal of Polymer Science.Polymer Physics》1995,33(17):2439-2447
Unique crystallization and melting behavior in poly(aryl ether ketone ketone) containing alternated terephthalic and isophthalic moieties were studied by time-resolved synchrotron x-ray methods. Recently, this material has been shown to exhibit three polymorphs (forms I, II, and III). In this work, we further investigated their distinctive thermal properties and found that form I is the dominating and the most thermally stable phase while form II is favored by fast nucleation conditions and is the least stable phase. On the other hand, form III represents a minor intermediate phase that usually coexists with form I and can be transferred from form II and to form I. Structural and morphological changes in form I have been followed by simultaneous wide-angle x-ray diffraction (WAXD)/small-angle x-ray scattering (SAXS) measurements during cold- or melt-crystallization and subsequent melting. In all cases, a larger dimensional change was found in the crystallographic a-axis than the b-axis during heating and cooling. This may be due to the greater lateral stress variation with respect to temperature along the a direction of the primary lamellae which is induced by either the formation of secondary lamellae or the preferential chain-folding direction in poly(aryl ether ketone ketone)s. During the phase transitions of form II ← III in the cold-crystallized specimen and form III ← I in the melt-crystallized samples, lamellar variables (long period, lamellar thickness, and invariant) obtained from SAXS remain almost constant. This indicates that the density distribution in the long spacing is independent of the melting in form II or III. For melt-crystallization, the corresponding changes in unit-cell dimensions and lamellar morphology during the annealing-induced low endotherm are most consistent with the argument that these changes are due to the melting of thin lamellar population. © 1995 John Wiley & Sons, Inc. 相似文献