3‐Formyl‐BODIPY Phenylhydrazone as a Chromo‐Fluorogenic Probe for Selective Detection of NO2 (g)

A new colorimetric and fluorogenic probe, based on a 3‐formyl boron dipyrromethene (BODIPY) phenylhydrazone, for the sensitive and selective detection NO₂ (g) has been prepared. The probe in solution experiences a remarkable hypsochromic shift of its absorption and fluorescence emission bands in the presence gaseous NO₂ (g), leading to limits of detection of few ppb. The probe also works in the solid phase, adsorbed on filter paper strips, or chemically immobilized on the surface of silica nanoparticles, with limits of detection to the naked eye of about 0.5 ppm.     

Formation of Hybrid Perovskite Tin Iodide Single Crystals by Top‐Seeded Solution Growth

Hybrid perovskites have generated a great deal of interest because of their potential in photovoltaic applications. However, the toxicity of lead means that there is interest in finding a nontoxic substitute. Bulk single crystals of both cubic CH₃NH₃SnI₃ and CH(NH₂)₂SnI₃ were obtained by using the top‐seeded solution growth method under an ambient atmosphere. Structural refinement, band gap, thermal properties, and XPS measurements of CH₃NH₃SnI₃ and CH(NH₂)₂SnI₃ single crystals are also reported in detail. These results should pave the way for further applications of CH₃NH₃SnI₃ and CH(NH₂)₂SnI₃.     

强激光远场光束质量参数的测试

 提出漫射红外成像-多点标校测量方法,用于测量强激光远场光束质量参数。在激光远场距离处设置漫反射靶板,用成像探测器摄取经靶面漫射的脉冲强激光光斑图像;在靶面中心处挖小孔,孔后放置能量探测器实时测量激光脉宽和峰值功率。同时对整个激光光斑图像进行能量定标,进而得出远场脉冲强激光的实际空间能量/功率分布、总能量,以及相应的光束质量参数。应用该测量方法,对高能TEA CO₂激光进行测量研究,测得其远场光束截面半径为80.2 mm,发散角为1.55 mrad。     

基于光参量放大的高速实时光取样技术

提出了一种基于光参量放大的高速实时光取样方案. 利用色散介质对光纤锁模激光器产生的窄脉冲源进行色散展宽,从而产生线性啁啾光信号. 将该信号和被取样信号同时送入高非线性光纤,利用高非线性光纤中的参量放大效应,将被取样信号的强度信息调制到线性啁啾光信号上. 在接收端利用不同中心波长的滤波器即可滤出不同时间点的取样信号,从而在光域同时完成了高速实时光取样和取样信号的串-并转换. 是实现高速实时取样技术的一种极具竞争力的实现方案. 实验中,实现了对10 Gb/s非归零码OOK信号的40 GS/s的高速实时取样系统,并转换为4路10 GS/s取样信号输出. 在接收端成功根据4路取样信号恢复出被取样信号波形,验证了该实时光取样方案的可行性. 关键词： 光信号处理 光取样 参量放大 高非线性光纤     

脉冲时滞抛物型方程解的振动性

本文研究了两类边界条件下有振动系数的脉冲时滞抛物型方程解的振动性,得到了若干解振动的判别准则。其结果即使用于有固定符号系数的方程,也显著地改进了已有的结果。     

Influence of Gas Components on the Formation of Carbonyl Sulfide over Water-Gas Shift Catalyst B303Q

Water-gas shift reaction catalyst at lower temperature (200—400℃) may improve the conversion of carbon monoxide. But carbonyl sulfide was found to be present over the sulfided cobalt-molybdenum/alumina catalyst for water-gas shift reaction. The influences of temperature, space velocity, and gas components on the formation of carbonyl sulfide over sulfided cobalt-molybdenum/alumina catalyst B303Q at 200—400℃were studied in a tubular fixed-bed quartz-glass reactor under simulated water-gas shift conditions. The experimental results showed that the yield of carbonyl sulfide over B303Q catalyst reached a maximum at 220℃with the increase in temperature, sharply decreased with the increase in space velocity and the content of water vapor, increased with the increase in the content of carbon monoxide and carbon dioxide, and its yield increased and then reached a stable value with the increase in the content of hydrogen and hydrogen sulfide. The formation mechanism of carbonyl sulfide over B303Q catalyst at 200—400℃was discussed on the basis of how these factors influence the formation of COS. The yield of carbonyl sulfide over B303Q catalyst at 200-400℃was the combined result of two reactions, that is, COS was first produced by the reaction of carbon monoxide with hydrogen sulfide, and then the as-produced COS was converted to hydrogen sulfide and carbon dioxide by hydrolysis. The mechanism of COS formation is assumed as follows: sulfur atoms in the Co9S8-MOS2/Al2O3 crystal lattice were easily removed and formed carbonyl sulfide with CO, and then hydrogen sulfide in the water-gas shift gas reacted with the crystal lattice oxygen atoms in CoO-MoO3/Al2O3 to form Co9S8-MoS2/Al2O3. This mechanism for the formation of COS over water-gas shift catalyst B303Q is in accordance with the Mars-Van Krevelen's redox mechanism over metal sulfide.     

非锁相Lorenz-Haken方程动力学研究

考虑原子的相干性和经典注入光场，利用随机微分方程给出非锁相条件下的Lorenz-Haken方程，研究失谐量、注入经典光场和原子相干性对非锁相Lorenz-Haken方程动力学特性的影响．在激光运转情形，失谐量造成光场位相的混沌，系统在不同条件下，出现四吸引子、双吸引子及单吸引子混沌状态，且体系的分数维维数较锁相条件下增加．光场失谐量、注入光场和原子相干性可抑制混沌．在双稳态运转下，光场位相为π的偶数倍或奇数倍，使光场稳定于正值和负值，故体系出现对称双稳态对，但无混沌状态． 关键词： 非锁相Lorenz-Haken方程 混沌 原子相干性 注入光场     

Synthesis of substituted quinoline via copper-catalyzed one-pot cascade reactions of 2-bromobenzaldehydes with aryl methyl ketones and aqueous ammonia

In this Letter, a new version of the Friedländer synthesis of quinoline derivatives starting from 2-bromobenzaldehydes, aryl methyl ketones, and aqueous ammonia with copper-catalyzed amination as a key step is presented. Remarkable advantages of this new quinoline synthesis include commercially available and economical starting materials, simple operational process, and excellent efficiency.